# Chemical

General Desc:
Diacetone alcohol is a clear colorless liquid with a pleasant odor.  It has a flash point of less than 141 deg. F.  It is lighter than water and is soluble in water.  Its vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  125¦ F (cc)
142¦ F (oc) (USCG, 1999)

Lower Exp Limit:  1.8 % (USCG, 1999)

Upper Exp Limit:  6.9 % (USCG, 1999)

Auto Igtn Temp:  1118¦ F (USCG, 1999)

Melting Point:  -45.0¦ F (USCG, 1999)

Vapor Pressure:  3.62 mm (USCG, 1999)

Specific Gravity:  0.94 (NIOSH, 1997)

Boiling Point:  328¦ F at 760 mm (USCG, 1999)

Molecular Weight:  116.16 (USCG, 1999)

IDLH:  1800 ppm (NIOSH, 1997)

TLV TWA:  50 ppm  For pure Diacetone Alcohol. (¬ACGIH, 1999)

Water Solubility:  Miscible (NIOSH, 1997)

First Aid:
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical.  Skin: If this chemical contacts the skin, flush the contaminated skin with water promptly. If this chemical penetrates the clothing, immediately remove the clothing and flush the skin with water promptly. If irritation persists after washing, get medical attention.  Breathing: If a person breathes large amounts of this chemical, move the exposed  person to fresh air at once. If breathing has stopped, perform mouth-to-mouth  resuscitation. Keep the affected person warm and at rest. Get medical  attention as soon as possible.  Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 1997)

Firefighting:
CAUTION:  All these products have a very low flash point:  Use of water spray when fighting fire may be inefficient.  SMALL FIRES:  Dry chemical, CO2, water spray or alcohol-resistant foam.  Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane.  LARGE FIRES:  Water spray, fog or alcohol-resistant foam.  Do not use straight streams.  Move containers from fire area if you can do it without risk.  FIRE INVOLVING TANKS OR CAR/TRAILER LOADS:  Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.  Cool containers with flooding quantities of water until well after fire is out.  Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.  ALWAYS stay away from the ends of tanks.  For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (DOT, 1996)

Reactivity:
CHEMICAL PROFILE:  Acetyl bromide reacts violently with alcohols or water, Merck 11th ed., 1989.  Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, Chem. Eng. News 45(43):73(1967); J, Org. Chem. 28:1893(1963). Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous-carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites, NFPA 491 M, 1991. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence, Wischmeyer(1969). (REACTIVITY, 1999)

Symptoms:
eye, nose, throat, skin irritation; corneal tissue damage; narcosis; in animals: liver damage

Health Effects:
irritation-eye, nose, throat, skin---moderate; cumulative kidney damage

Physical Description:
Colorless liquid with a faint, minty odor.

Exposure Symptoms:
Irrit eyes, skin, nose, throat; corn damage; in animals: narco, liver damage


General Desc:
Physical State Shipped: Liquid

Odor: Mild, choking alcohol odor

Color: Colorless

Characteristics in Water: Floats and mixes with water.  Irritating vapor is produced. (USCG, 1999)

Properties:
Flash Point:  114¦ F (oc) (USCG, 1999)

Lower Exp Limit:  1.2 %  (212¦F) (USCG, 1999)

Upper Exp Limit:  9.0 %  (212¦F) (USCG, 1999)

Auto Igtn Temp:  662¦ F (USCG, 1999)

Melting Point:  -179¦ F (NIOSH, 1997)

Vapor Pressure:  28 mm (NIOSH, 1997)

Specific Gravity:  0.81 at 57 ¦F (NIOSH, 1997)

Boiling Point:  270¦ F at 760 mm (USCG, 1999)

Molecular Weight:  88.15 (USCG, 1999)

IDLH:  500 ppm (NIOSH, 1997)

TLV TWA:  100 ppm (¬ACGIH, 1999)

TLV STEL:  125 ppm (¬ACGIH, 1999)

Water Solubility:  Sol(57¦F): 2% (NIOSH, 1997)

Firefighting:
Fire Extinguishing Agents: Water spray, dry chemical, alcohol foam, or carbon dioxide. (USCG, 1999)

Reactivity:
CHEMICAL PROFILE:  Attacks plastics. REF (Handling Chemicals Safely, 1980. p. 236. Acetyl bromide reacts violently with alcohols or water, Merck 11th ed., 1989.  Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, Chem. Eng. News 45(43):73(1967); J, Org. Chem. 28:1893(1963). Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous-carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites, NFPA 491 M, 1991. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence, Wischmeyer(1969). (REACTIVITY, 1999)

Symptoms:
eye, nose, throat irritation; narcosis; headaches, dizziness; dyspnea; nausea, vomiting, diarrhea; skin cracking

Synonyms:
Fermentation amyl alcohol, Fusel oil, Isobutyl carbinol, Isopentyl alcohol, 3-Methyl-1-butanol, Primary isoamyl alcohol

Physical Description:
Colorless liquid with a disagreeable odor.

Exposure Symptoms:
Irrit eyes, skin, nose, throat; head, dizz; cough, dysp, nau, vomit, diarr; skin cracking; in animals: narco


General Desc:
Endosulfan is a brown or colorless crystalline solid with a pungent odor.  It is heavier than, and practically insoluble in water.  It is toxic by inhalation, skin absorption, and/or ingestion.  It is used as a pesticide, fungicide or herbicide. (¬ AAR, 1999)

Properties:
Melting Point:  158 to 212¦ F Range of values given is for a mixture of isomers (a isomer 228.7F; b isomer 415.9F). (EPA, 1998)

Vapor Pressure:  1e-05 mm at 77¦ F (EPA, 1998)

Specific Gravity:  1.745 at 68¦ F (NTP, 1992)

Boiling Point:  Decomposes (NIOSH, 1997)

Molecular Weight:  406.95 (EPA, 1998)

TLV TWA:  0.1 mg/m3  Skin. (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 73¦ F (NTP, 1992)

First Aid:
Signs and Symptoms of Acute Endosulfan Exposure: Ingestion of endosulfan may result in nausea, vomiting, and diarrhea.  Dizziness, agitation, nervousness, tremor, incoordination, and convulsions may also occur.  Central nervous system depression may terminate in respiratory failure.  Contact with endosulfan may irritate or burn the skin, eyes, and mucous membranes. Emergency Life-Support Procedures: Acute exposure to endosulfan may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to endosulfan. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to endosulfan. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas three times.  An initial soap and water wash should be followed by an alcohol wash.  The third wash should again be with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 3.  Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of endosulfan is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.Ipecac should not be administered to children under 6 months of age. Warning: Ingestion of endosulfan may result in sudden onset of seizures or loss of consciousness.  Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4. The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  Transport to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash or cement powder.    Water spill:  If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount.  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Firefighting:
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Ventilate closed spaces before entering them. Wear positive pressure breathing apparatus and special protective clothing. Remove and isolate contaminated clothing at the site.Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog. Use alcohol foam, carbon dioxide or dry chemical. (EPA, 1998)

Reactivity:
AIR AND WATER REACTIONS:  Slowly hydrolyses to form sulfur dioxide, Hydrolyses more rapidly under alkaline conditions. (REACTIVITY, 1999)

Symptoms:
irritation skin; nausea, confusion, agitation, flushing, dry mouth, tremor, convulsions, headache; in animals: kidney, liver injury; decreased testis weight

Health Effects:
acute central nervous system toxin; cumulative kidney damage; LD50 (oral,rat) 18-43 mg/kg

Target Organ:
skin, central nervous system, liver, kidneys, reproductive system

Physical Description:
Brown crystals with a slight, sulfur dioxide odor.

Notes 2:
[insecticide] [Note: Technical product is a tan, waxy, isomer mixture.]

Exposure Symptoms:
Irrit skin; nau, conf, agitation, flushing, dry mouth, tremor, convuls, head; in animals: kidney, liver inj; decr testis weight


Properties:
Auto Igtn Temp:  842¦ F (USCG, 1999)

Melting Point:  502¦ F (USCG, 1999)

Vapor Pressure:  0.00000008 mm (NIOSH, 1997)

Specific Gravity:  1.38 (NIOSH, 1997)

Boiling Point:  Sublimes (NIOSH, 1997)

Molecular Weight:  136.2 (USCG, 1999)

TLV TWA:  10 mg/m3 (¬ACGIH, 1999)

Water Solubility:  Sol(59¦F): 6% (NIOSH, 1997)

First Aid:
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical. Skin: If this chemical contacts the skin, wash the contaminated skin with water. Breathing: If a person breaths large amounts of this chemical, move the exposed person to fresh air at once. Other measures are usually unnecessary. Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 1997)

Firefighting:
Fire Extinguishing Agents: Water, dry chemical, carbon dioxide (USCG, 1999)

Reactivity:
This compound is incompatible with the following:Organic acids, oxidizers [Note: Explosive compound is formed when a mixture of PE & thiophosphoryl chloride is heated.] (NIOSH, 1997)

Synonyms:
2,2-bis(Hydroxymethyl)-1,3-propanediol; Methane tetramethylol; Monopentaerythritol; PE; Tetrahydroxymethylolmethane; Tetramethylolmethane

Physical Description:
Colorless to white, crystalline, odorless powder.

Notes 2:
[Note: Technical grade is 88% monopentaerythritol & 12% dipentaerythritol.]


General Desc:
Bromochloromethane is a clear, colorless liquid with a sweet, chloroform-like odor.  It's vapors may cause illness from inhalation.  It is nonflammable.  When it is exposed to high temperatures it may emit toxic fumes.  It is used as a fire extinguishing agent. (¬ AAR, 1999)

Properties:
Melting Point:  -126¦ F (NTP, 1992)

Vapor Pressure:  117 mm Hg at 68¦ F (NTP, 1992)

Vapor Density:  4.46 (NTP, 1992)

Specific Gravity:  1.930 at 77¦ F (NTP, 1992)

Boiling Point:  154.0¦ F (NTP, 1992)

Molecular Weight:  129.39 (NTP, 1992)

IDLH:  2000 ppm (NIOSH, 1997)

TLV TWA:  200 ppm (¬ACGIH, 1999)

TLV STEL:  250 ppm (¬ACGIH, 1999)

Water Solubility:  1-5 mg/mL at 68¦ F (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN:  IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop.  IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION:  DO NOT INDUCE VOMITING.  Corrosive chemicals will destroy the membranes of the mouth, throat, and esophagus and volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting.  Thus, the risk of increasing the medical problems by inducing vomiting of a volatile corrosive chemical is very high.  If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.  IMMEDIATELY transport the victim to a hospital.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body.  DO NOT INDUCE VOMITING.  IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Firefighting:
Cool all affected containers with flooding quantities of water.  Use water in flooding quantities as fog.  Extinguish fire using agent suitable for type of surrounding fire.  (Material itself does not burn or burns with difficulty.)  Apply water from as far a distance as possible.  Keep run-off water out of sewers and water sources. ( AAR, 1999)

Reactivity:
STABILITY:  This chemical is sensitive to light (may discolor).  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical is incompatible with strong bases and strong oxidizing agents.  It is also incompatible with active metals, calcium, aluminum, magnesium, zinc and their alloys.  This chemical will attack some forms of plastics, rubber and coatings. (NTP, 1992)

Symptoms:
disorientation, dizziness; irritated eyes, throat, skin; pulmonary edema

Health Effects:
cumulative liver damage; narcosis; irritation-eyes, throat---mild

Synonyms:
Bromochloromethane, CB, CBM, Fluorocarbon 1011, Halon®1011, Methyl chlorobromide

Physical Description:
Colorless to pale-yellow liquid with a chloroform-like odor.

Notes 2:
[Note: May be used as a fire extinguishing agent.]

Exposure Symptoms:
Irrit eyes, skin, throat; conf, dizz, CNS depres; pulm edema


General Desc:
2,2-Dichloropropionic acid is a colorless liquid.  It is soluble in water.  It is corrosive to metals and tissue.  It weighs 11.6 lbs./gal.  It is used as a herbicide. (¬ AAR, 1999)

Properties:
Melting Point:  46¦ F (USCG, 1999)

Vapor Pressure:  5.07 mm at 160¦ F (USCG, 1999)

Vapor Density (air = 1):  4.9 (USCG, 1999)

Specific Gravity:  1.39 (¬ AAR, 1999)

Boiling Point:  374¦ F at 760 mm (USCG, 1999)

Molecular Weight:  143 (USCG, 1999)

TLV TWA:  5 mg/m3 (¬ACGIH, 1999)

Water Solubility:  50% (NIOSH, 1997)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Use water spray to knock-down vapors.  Neutralize spilled material with crushed limestone, soda ash, or lime.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.    Water spill:  Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom.  If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount.  Remove trapped material with suction hoses.  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Firefighting:
Extinguish fire using agent suitable for type of surrounding fire.  (Material itself does not burn or burns with difficulty.)  Cool all affected containers with flooding quantities of water.  Apply water from as far a distance as possible.  Use water spray to knock-down vapors. ( AAR, 1999)

Reactivity:
This compound is incompatible with the following:  Metals [Note: Very corrosive to aluminum & copper alloys. Reacts slowly in water to form hydrochloric & pyruvic acids.] (NIOSH, 1997)

Symptoms:
irritation eyes, skin, upper respiratory system; skin burns; lassitude (weakness, exhaustion), loss of appetite, diarrhea, vomiting, slowing of pulse; central nervous system depressant/depression

Synonyms:
Dalapon; 2,2-Dichloropropanoic acid; à,à-Dichloropropionic acid

Notes 2:
[herbicide] [Note: A white to tan powder below 46ºF. The sodium salt, a white powder, is often used.]

Exposure Symptoms:
Irrit eyes, skin, upper resp sys; skin burns; lass, loss of appetite, diarr, vomit, slowing of pulse; CNS depres


General Desc:
Lithium hydride is a greyish white granular powder.  It reacts with water to form lithium hydroxide, a corrosive material, and hydrogen, a flammable gas.  The heat of this reaction may be sufficient to ignite the hydrogen.  It may react violently with heat or oxidizing materials. (¬ AAR, 1999)

Properties:
Lower Exp Limit:  Flammable solid. (EPA, 1998)

Upper Exp Limit:  Flammable solid. (EPA, 1998)

Auto Igtn Temp:  392¦ F (USCG, 1999)

Melting Point:  1256¦ F (EPA, 1998)

Vapor Pressure:  0 mm at 68¦ F (EPA, 1998)

Specific Gravity:  0.78 (NIOSH, 1997)

Boiling Point:  Decomposes (NIOSH, 1997)

Molecular Weight:  7.95 (EPA, 1998)

IDLH:  0.5 mg/m3 (NIOSH, 1997)

TLV TWA:  0.025 mg/m3 (¬ACGIH, 1999)

ERPG-1:  25 micrograms/m3 (AIHA, 1999)

ERPG-2:  100 micrograms/m3 (AIHA, 1999)

ERPG-3:  500 micrograms/m3 (AIHA, 1999)

Water Solubility:  Reacts (NIOSH, 1997)

First Aid:
Warning: Lithium hydride is an alkaline-corrosive agent.  Contact with eyes may result in severe damage to the cornea, conjunctiva, and blood vessels.  Caution is advised. Signs and Symptoms of Acute Lithium Hydride Exposure: Acute exposure to lithium hydride may result in irritation and burning of the skin, eyes, and mucous membranes.  Increased salivation, dysphagia (difficulty swallowing), abdominal pain, and spontaneous vomiting may occur.  Stridor (high-pitched, noisy respirations), dyspnea (shortness of breath), and pulmonary edema are also common.  Apathy and mental confusion may develop, with progression to coma and death. Emergency Life Support Procedures: Acute exposure to lithium hydride may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to lithium hydride. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to lithium hydride. 2. Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 30 minutes. 5.  Wash exposed skin areas for at least 15 minutes with water. 6. Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7. Transport to a health care facility. Ingestion Exposure: 1. Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2. DO NOT induce vomiting or attempt to neutralize!  3. Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Activated charcoal is of no value. 5.  Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup).  Water or milk should be given only if victims are conscious and alert. 6. Transport to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Do not use water.  Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Keep material dry. ( AAR, 1999)

Firefighting:
Wear protective goggles or face shield, rubberized gloves, flame-proof outer clothing, respirator, and high boots or shoes. Large fires: withdraw from area and let fire burn, as lithium hydride may continue to re-ignite. A fire, once started, cannot be extinguished by ordinary methods.Do not use water, carbon dioxide, dry chemical, or halogenated extinguishing agents such as carbon tetrachloride. Use dry graphite; or ground dolomite-based dry chemical extinguishers such as "Lith-X". Fires may be smothered by inverting a can over them. (EPA, 1998)

Reactivity:
AIR AND WATER REACTIONS:  The powdered material burns readily in air, with water or air of high humidity it reacts rapidly to form caustic Lithium hydroxide and hydrogen (Bretherick 1979 p. 107).CHEMICAL PROFILE:  A white solid, upon contact with moisture it forms caustic lithium hydroxide and hydrogen gas. It may ignite spontaneously in moist air, mixture with liquid oxygen is explosive. It ignites on contact with dinitrogen oxide [Mellor, 1967, vol. 8, suppl. 2.2, p. 214]. (REACTIVITY, 1999)

Symptoms:
eye, skin burns; mouth and esophageal burns if injested; nausea; muscle twitches; mental confusion; blurred vision

Health Effects:
irritation-eye, nose, throat, skin---marked; lung damage; central nervous system effects

Physical Description:
Odorless, off-white to gray, translucent, crystalline mass or white powder.

Exposure Symptoms:
Irrit eyes, skin; eye, skin burns; mouth, esophagus burns (if ingested); nau; musc twitches; mental conf; blurred vision


General Desc:
Vinyl bromide, inhibited boils at 60 deg. F.  and could exist as a liquid at low ambient temperatures.  It is highly flammable and has a specific gravity of 1.51.  It is a suspected carcinogen.  Exposure of the container to prolonged fire or intense heat may cause it to rupture violently and rocket. (¬ AAR, 1999)

Properties:
Flash Point:  <18¦ F (NTP, 1992)

Lower Exp Limit:  9% (NTP, 1992)

Upper Exp Limit:  15% (NTP, 1992)

Auto Igtn Temp:  882¦ F (NTP, 1992)

Melting Point:  -219.1¦ F (NTP, 1992)

Vapor Pressure:  895 mm Hg at 68¦ F (NTP, 1992)

Vapor Density:  3.7 (NTP, 1992)

Specific Gravity:  1.49 at 68¦ F (NTP, 1992)

Boiling Point:  60.4¦ F (NTP, 1992)

Molecular Weight:  106.96 (NTP, 1992)

TLV TWA:  5 ppm  Suspected human carcinogen. (¬ACGIH, 1999)

Water Solubility:  Insoluble (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN:  CAUTION: Exposure of skin to compressed gases may result in freezing of the skin.  Treatment for frostbite may be necessary.  Remove the victim from the source of contamination.  IMMEDIATELY wash affected areas gently with COLD water (and soap, if necessary) while removing and isolating all contaminated clothing.  Dry carefully with clean, soft towels.  Call a hospital or poison control center IMMEDIATELY even if no symptoms (such as inflammation or irritation) develop.  Be prepared to transport the victim to a hospital for treatment after washing the affected area if advised to do so by a physician. INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION:  This compound is a gas, therefore inhalation is the first route of exposure. OTHER:  Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring.  Recommendations from the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure. (NTP, 1992)

Firefighting:
Do not extinguish fire unless flow can be stopped.  Use water in flooding quantities as fog.  Use "alcohol" foam, dry chemical or carbon dioxide.  Cool all affected containers with flooding quantities of water.  Apply water from as far a distance as possible. ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Light sensitive, peroxidizable monomer may initiate exothermic polymerization of the bulk material (Handling Chemicals Safely 1980.. p. 958) (REACTIVITY, 1999)

REL NOTES:
CARCINOGEN (Ca); REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION (LOQ 0.2 ppm)

Symptoms:
irritation eyes, skin; dizziness, confusion, incoordination, narcosis, nausea, vomiting; liquid: frostbite [potential occupational carcinogen]

Health Effects:
cumulative bromide intoxication (central nervous system effects); mutagen;

Target Organ:
eyes, skin, central nervous system, liver; in animals: liver and lymph node tumors

Synonyms:
Bromoethene, Bromoethylene, Monobromoethylene, Vinyl bromide, inhibited

Physical Description:
Colorless gas or liquid (below 60ºF) with a pleasant odor.

Notes 2:
[Note: Shipped as a liquefied compressed gas with 0.1% phenol added to prevent polymerization.]

Exposure Symptoms:
Irrit eyes, skin; dizz, conf, inco, narco, nau, vomit; liquid: frostbite; [carc]


General Desc:
PHYSICAL DESCRIPTION:  Fine beige crystals; white powder.

PHYSICAL DATA:  Chlorine-like odor. (NTP, 1992)

Properties:
Melting Point:  392¦ F (decomposes) (NTP, 1992)

Vapor Pressure:  0.000000616 mm Hg at 95¦ F (NTP, 1992)

Boiling Point:  Decomposes (NIOSH, 1997)

Molecular Weight:  241.46 (NTP, 1992)

Water Solubility:  <0.1 mg/mL at 68¦ F (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container.  Use absorbent paper dampened with water to pick up any remaining material.  Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal.  Wash all contaminated surfaces with a soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should protect this material from exposure to light, and store it under ambient temperatures. (NTP, 1992)

Reactivity:
STABILITY:  This chemical may be sensitive to prolonged exposure to light.  Aqueous solutions may be decomposed by light.REACTIVITY:  This chemical is incompatible with strong oxidizing agents, strong acids, acid chlorides and acid anhydrides. (NTP, 1992)

Symptoms:
irritation eyes, skin, respiratory system; nausea; in animals: liver, kidney changes

Health Effects:
mutagen/suspect carcinogen; LD50 (oral, rat) 3.75 mg/kg

Synonyms:
4-Amino-3,5,6-trichloropicolinic acid; 4-Amino-3,5,6-trichloro-2-picolinic acid; ATCP; Tordon®

Physical Description:
Colorless to white crystals with a chlorine-like odor.

Exposure Symptoms:
Irrit eyes, skin, resp sys; nau; in animals: liver, kidney changes


General Desc:
Diborane is a colorless gas with an offensive odor.  It is toxic by inhalation.  Diborane is decomposed by water giving off hydrogen, another flammable gas and boric acid a non-regulated material.  Its vapors are heavier than air.  Long term exposure to low concentrations or short term exposure to high concentrations can result in adverse health effects from inhalatiom.  It is used in electronics. (¬ AAR, 1999)

Properties:
Flash Point:  -130¦ F (unspc) (EPA, 1998)

Lower Exp Limit:  0.9% (NTP, 1992)

Upper Exp Limit:  98% (NTP, 1992)

Auto Igtn Temp:  100-126¦ F (NTP, 1992)

Melting Point:  -265¦ F (EPA, 1998)

Vapor Pressure:  224 mm at -169.6¦ F (EPA, 1998)

Vapor Density:  <1.0 (NTP, 1992)

Specific Gravity:  0.447 at -297¦ F (NTP, 1992)

Boiling Point:  -135¦ F at 760 mm (EPA, 1998)

Molecular Weight:  27.69 (EPA, 1998)

IDLH:  15 ppm (NIOSH, 1997)

TLV TWA:  0.1 ppm (¬ACGIH, 1999)

ERPG-1:  not appropriate (AIHA, 1999)

ERPG-2:  1 ppm (AIHA, 1999)

ERPG-3:  3 ppm (AIHA, 1999)

Water Solubility:  Decomposes (NTP, 1992)

First Aid:
Warning: Effects may be delayed up to 24 hours.  Caution is advised. Signs and Symptoms of Acute Diborane Exposure: Signs and symptoms of acute exposure to diborane may include tightness in the chest, dyspnea (shortness of breath), cough, and wheezing.  Nausea and pulmonary edema may also occur.  Other possible effects of acute exposure include dizziness, headache, weakness, lack of coordination, muscle spasms, tremor, and seizures.  Exposure to diborane may irritate or burn the skin, eyes, and mucous membranes. Emergency Life-Support Procedures: Acute exposure to diborane may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to diborane. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to diborane. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas at least twice with large amounts of cool water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: No information is available. (EPA, 1998)

Firefighting:
Firefighting should be done from an explosion-resistant location. Use water from unmanned monitors or hose holders to keep fire-exposed containers cool. If it is necessary to stop flow of gas, use water spray to protect personnel effecting shut-off. Personnel should be evacuated immediately. Self-contained breathing apparatus and full protective clothing should be worn.  Isolate for 1/2 mile in all directions if tank car or truck is involved in fire.Inert gas substances such as liquid nitrogen are recommended as fire extinguishing agents. (EPA, 1998)

Reactivity:
AIR AND WATER REACTIONS:  Ignites spontaneously in moist air(forms hydrogen and boric acid), Haz. Chem. Data(1966). Oxygen and diborane form spontaneously explosive mixtures, J. Am. Chem. Soc. 76, 1997(1954).CHEMICAL PROFILE:  It is a colorless, air and moisture-sensitive gas, highly toxic. It ignites in air. It is very explosive when exposed to heat or flame, on contact with moisture it produces hydrogen gas. Explosive reaction with benzene vapor, chlorine, nitric acid and tetravinyllead [Bretherick, 5th ed., 1995, p. 77]. Explosive reaction with dimethyl sulfoxide (Shriver, 1969, p. 209), violent reaction with halocarbon liquids used as fire extinguishants (e.g., carbon tetrachloride). Reaction with Al or Li produces complex hydrides that may ignite spontaneously in air [Haz. Chem. Data, 1975, p. 114]. (REACTIVITY, 1999)

Symptoms:
tightness chest, precordial pain, shortness of breathing, nonproductive cough; nausea; headaches; lightheadedness, vertigo; chills, fever; fatigue, weakness; tremors, muscle fasciculation.  in animals:  liver, kidney damage; pulmonary edema; hemorrhage

Health Effects:
acute respiratory damage; nervous system damage; irritation-eye---marked

Target Organ:
respiratory system, central nervous system, liver, kidneys

Synonyms:
Boroethane, Boron hydride, Diboron hexahydride

Physical Description:
Colorless gas with a repulsive, sweet odor.

Notes 2:
[Note: Usually shipped in pressurized cylinders diluted with hydrogen, argon, nitrogen, or helium.]

Exposure Symptoms:
Chest tight, precordial pain, short breath, nonproductive cough, nau; head, li-head, verti, chills, fever, ftg, weak, tremor, musc fasc; in animals: liver, kidney damage; pulm edema; hemorr


General Desc:
Vinylidene chloride is a clear colorless liquid with a chloroform-like odor.  It has a flash point of 0 deg. F.  and a boiling point of 99 deg. F.  If subject to heat, it may polymerize.  If the polymerization takes place in a container the container may violently rupture.  Vinylidene chloride is heavier than water and insoluble in water.  Its vapors are heavier than air.  It weighs 10.1 lbs./gal. (¬ AAR, 1999)

Properties:
Flash Point:  14¦ F (NTP, 1992)

Lower Exp Limit:  7.3% (NTP, 1992)

Upper Exp Limit:  16.0% (NTP, 1992)

Auto Igtn Temp:  1058¦ F (USCG, 1999)

Melting Point:  -188.5¦ F (NTP, 1992)

Vapor Pressure:  500 mm Hg at 68¦ F; 591 mm Hg at 77¦ F (NTP, 1992)

Vapor Density:  3.25 (NTP, 1992)

Specific Gravity:  1.218 at 68¦ F (NTP, 1992)

Boiling Point:  89.1¦ F at 760 mm Hg (NTP, 1992)

Molecular Weight:  96.94 (NTP, 1992)

TLV TWA:  5 ppm (¬ACGIH, 1999)

TLV STEL:  20 ppm (¬ACGIH, 1999)

Water Solubility:  5-10 mg/mL at 70¦ F (NTP, 1992)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.    Combustion products include corrosive or toxic vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.  Apply approriate foam to diminish vapor and fire hazard.    Water spill:  Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom.  Inject "universal" gelling agent to solidify encircled spill and increase effectiveness of booms.  Remove trapped material with suction hoses.  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Peroxidizable monomer may initiate exothermic polymerization of the bulk material (Bretherick 1979.  p. 160, 187). Mixing vinylidene chloride in equal molar portions in a closed container with any of the following substances  caused the temperature and pressure to increase:chlorosulfonic acid, nitric acid, or oleum (NFPA 1991). (REACTIVITY, 1999)

REL NOTES:
CARCINOGEN (Ca); REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION (LOQ 0.4 ppm)

Carcinogen:
IARC-3, NIOSH-Ca, TLV-A4, EPA-I;S* *S=INHALATION; I=ORAL

Symptoms:
irritation eyes, skin, throat; dizziness, headache, nausea, dyspnea (breathing difficulty); liver, kidney dysfunction; pneumonitis; potential occupational carcinogen

Target Organ:
eyes, skin, respiratory system, central nervous system, liver, kidneys; in animals: liver and kidney tumors

Synonyms:
1,1-DCE; 1,1-Dichloroethene; 1,1-Dichloroethylene; VDC; Vinylidene chloride monomer; Vinylidene chloride, inhibited; Vinylidene dichloride

Physical Description:
Colorless liquid or gas (above 89ºF) with a mild, sweet, chloroform-like odor.

Exposure Symptoms:
Irrit eyes, skin, throat; dizz, head, nau, dysp; liver, kidney dysfunc; pneuitis; [carc]


General Desc:
Chloropicrin is a slightly oily, colorless to yellow liquid with a strong odor.  It is slightly soluble in water and is non-combustible.  It is heavier than water.  It has an irritating odor.  The chloropicrin vapors are poisonous if inhaled and causes irritation of eyes, nose, and throat. (¬ AAR, 1999)

Properties:
Melting Point:  -92.6¦ F (NTP, 1992)

Vapor Pressure:  16.9 mm Hg at 68¦ F; 40 mm Hg at 92.8¦ F (NTP, 1992)

Vapor Density:  5.7 (NTP, 1992)

Specific Gravity:  1.6558 at 68¦ F (NTP, 1992)

Boiling Point:  234¦ F (NTP, 1992)

Molecular Weight:  164.37 (NTP, 1992)

IDLH:  2 ppm (NIOSH, 1997)

TLV TWA:  0.1 ppm (¬ACGIH, 1999)

TLV STEL:  0.3 ppm (¬ACGIH, 1999)

ERPG-1:  0.1 ppm (AIHA, 1999)

ERPG-2:  0.3 ppm (AIHA, 1999)

ERPG-3:  1.5 ppm (AIHA, 1999)

Water Solubility:  1-5 mg/mL at 72¦ F (NTP, 1992)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Use water spray to knock-down vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.    Water spill:  Use natural barriers or oil spill control booms to limit spill travel.  Remove trapped material with suction hoses. ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Powerful irritant affecting all body surfaces, more toxic then chlorine. It can be shocked into detonation. When heated to decomposition, it emits highly toxic fumes of chlorine gas and nitrogen oxides [Sax, 9th ed., 1996, p. 821]. It produces a violent reaction with aniline [Jackson, K. E., Chem. Rev., 1934, 14, p. 269] or strong bases in the presence of alcohols (alkoxides) [ Ramsey, B. G., et al., J. Am. Chem. Soc., 1966, 88, p. 3059]. (REACTIVITY, 1999)

Symptoms:
eye irritation, lacrimation; coughing, pulmonary edema; nausea, vomiting; skin irritation

Health Effects:
irritation-eye, nose, throat, skin---marked; acute lung damage/edema

Physical Description:
Colorless to faint-yellow, oily liquid with an intensely irritating odor.

Exposure Symptoms:
Irrit eyes, skin, resp sys; lac; cough, pulm edema; nau, vomit


General Desc:
Physical State Shipped: Solid

Color: Colorless to yellow

Characteristics in Water: Sinks and slowly mixes with water. (USCG, 1999)

Properties:
Flash Point:  302¦ F (cc) (USCG, 1999)

Melting Point:  244.4¦ F (USCG, 1999)

Specific Gravity:  1.57 (NIOSH, 1997)

Boiling Point:  606¦ F at 760 mm (USCG, 1999)

Molecular Weight:  168.11 (USCG, 1999)

IDLH:  50 mg/m3 (NIOSH, 1997)

TLV TWA:  0.15 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  0.05% (NIOSH, 1997)

Firefighting:
Fire Extinguishing Agents: Water, CO 2 , or dry chemical. (USCG, 1999)


General Desc:
Physical State Shipped: Solid Odor: Mild Odor Color: Yellow Characteristics in Water: Sinks in water. (USCG, 1999)

Properties:
Flash Point:  390¦ F (NTP, 1992) Melting Point:  298¦ F (NTP, 1992)

Vapor Pressure:  0.0015 mm Hg at 68¦ F; 0.007 mm Hg at 86¦ F (NTP, 1992)

Vapor Density:  4.77 (NTP, 1992)

Specific Gravity:  1.437 at 68¦ F (NTP, 1992)

Boiling Point:  637¦ F (NTP, 1992)

Molecular Weight:  138.14 (NTP, 1992)

IDLH:  300 mg/m3 (NIOSH, 1997)

TLV TWA:  3 mg/m3  Skin. (¬ACGIH, 1999)

Water Solubility:  <0.1 mg/mL at 70¦ F (NTP, 1992)

Firefighting:
Fire Extinguishing Agents: Water, foam, dry chemical or carbon dioxide (USCG, 1999)

Reactivity:
STABILITY:  This chemical is sensitive to moisture.  It may be sensitive to prolonged exposure to air and light.REACTIVITY:  This chemical may react vigorously with sulfuric acid above 392 F.  It may also react with sodium hydroxide at 266 F.  Under pressure, it may produce an explosive compound.  It is incompatible with strong oxidizers and strong reducing agents.  It is capable of explosive decomposition with strong initiators.  It will attack some forms of plastics, rubber and coatings. (NTP, 1992)

Symptoms:
cyanosis; ataxia; tachycardia; tachypnea, dyspnea; irritability; vomiting, diarrhea; convulsions; respiratory arrest; anemia, methemoglobinemia

Health Effects:
methemoglobinemia; chronic cumulative liver damage

Synonyms:
para-Aminonitrobenzene, 4-Nitroaniline, 4-Nitrobenzenamine, p-Nitrophenylamine, PNA

Physical Description:
Bright yellow, crystalline powder with a slight ammonia-like odor.

Exposure Symptoms:
Irrit nose, throat; cyan, ataxia; tacar, tachypnea; dysp; irrity; vomit, diarr; convuls; resp arrest; anemia; methemo; jaundice


General Desc:
Nitrobenzene is a pale yellow to dark brown liquid.  It has a flash point of 190 deg. F.  It is very slightly soluble in water.  It is toxic by inhalation and by skin absorption.  Toxic oxides of nitrogen are produced during combustion of this material.  It weighs 10.0 lbs./gallon. (¬ AAR, 1999)

Properties:
Flash Point:  190.4¦ F (cc) (EPA, 1998)

Lower Exp Limit:  1.8 % (EPA, 1998)

Upper Exp Limit:  1.8 % (USCG, 1999)

Auto Igtn Temp:  924¦ F (USCG, 1999)

Melting Point:  42¦ F (EPA, 1998)

Vapor Pressure:  1 mm at 111.92¦ F (EPA, 1998)

Vapor Density:  4.3 (EPA, 1998)

Specific Gravity:  1.203 at 68¦ F (NTP, 1992)

Boiling Point:  411.4¦ F at 760 mm (EPA, 1998)

Molecular Weight:  123.11 (EPA, 1998)

IDLH:  200 ppm (NIOSH, 1997)

TLV TWA:  1 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  Insoluble (<1 mg/mL at 75¦ F) (NTP, 1992)

First Aid:
Warning: Effects may be delayed.  Caution is advised.  Prior alcohol consumption aggravates the effects of nitrobenzene poisoning. Note: Absorption of nitrobenzene through the skin is rapid. Signs and Symptoms of Acute Nitrobenzene Exposure: Signs and symptoms of acute exposure to nitrobenzene may be severe and include cyanosis (blue tint to the skin and mucous membranes), tachycardia (rapid heart rate), hypotension (low blood pressure), and cardiac arrhythmias.  Respiratory depression and respiratory failure may also occur.  Headache, lethargy, weakness, vertigo (dizziness), severe depression, and coma may be noted.  Gastrointestinal symptoms include nausea and vomiting.  Urine and vomitus may have the odor of bitter almonds. Emergency Life-Support Procedures: Acute exposure to nitrobenzene may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to nitrobenzene. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  RUSH to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to nitrobenzene. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas THOROUGHLY with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  RUSH to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 3.  Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of nitrobenzene is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.Ipecac should not be administered to children under 6 months of age. Warning: Ingestion of nitrobenzene may result in sudden onset of seizures or loss of consciousness.  Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4. The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  RUSH to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash or cement powder.    Water spill:  Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom.  If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount.  Remove trapped material with suction hoses.  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Firefighting:
Move container from fire area if you can do it without risk. Fight fire from maximum distance. Dike fire control water for later disposal; do not scatter the material. Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Ventilate closed spaces before entering them. Wear positive pressure breathing apparatus and special protective clothing. Remove and isolate contaminated clothing at the site.Use water spray, dry chemical, foam, or carbon dioxide. (EPA, 1998)

Reactivity:
CHEMICAL PROFILE:   Aluminum chloride added to nitrobenzene containing about 5% phenol caused a violent explosion (Chem. Eng. News 31:4915. 1953). (REACTIVITY, 1999)

Symptoms:
anoxia; eye irritation; dermatitis; anemia; in animals:  liver, kidney damage

Health Effects:
methemoglobinemia; anemias; central nervous system effects; hematologic (blood) disturbances---anemias

Target Organ:
eyes, skin, blood, liver, kidneys, cardiovascular system, reproductive system

Synonyms:
Essence of mirbane, Nitrobenzol, Oil of mirbane

Physical Description:
Yellow, oily liquid with a pungent odor like paste shoe polish.

Exposure Symptoms:
Irrit eyes, skin; anoxia; derm; anemia; methemo; in animals: liver, kidney damage; testicular effects


Properties:
Flash Point:  260¦ F (NTP, 1992)

Melting Point:  156-160¦ F (NTP, 1992)

Vapor Pressure:  0.01 mm (NIOSH, 1997)

Specific Gravity:  1.048 at 68¦ F (NTP, 1992)

Boiling Point:  509¦ F at 760 mm Hg (NTP, 1992)

Molecular Weight:  220.36 (NTP, 1992)

Water Solubility:  <1 mg/mL at 68¦ F (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  Should a spill occur while you are handling this chemical, you should dampen the solid spill material with alcohol, then transfer the dampened material to a suitable container.  Use absorbent paper dampened with alcohol to pick up any remaining material.  Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal.  Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution.  Do not reenter the contaminate area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should store this chemical under refrigerated temperatures and keep it away from all oxidizing materials. (NTP, 1992)

Reactivity:
STABILITY:  The neat material is stable under normal laboratory conditions.REACTIVITY:  This compound may react with oxidizing materials. (NTP, 1992)

TLV NOTES:
VAPOR AND AEROSOL;MEASURED AS INHALABLE FRACTION AND VAPOR

Symptoms:
irritation eyes, skin; in animals: decreased growth rate, increase(d) liver weight

Health Effects:
explosives, flammable (no adverse effects when good housekeeping prrocedures

Synonyms:
2,6-Di-tert-butyl-p-cresol, BHT; Butylated hydroxytoluene; Dibutylated hydroxytoluene; 4-Methyl-2,6-di-tert-butyl phenol

Physical Description:
White to pale-yellow, crystalline solid with a slight, phenolic odor.

Exposure Symptoms:
Irrit eyes, skin; in animals: decr growth rate, incr liver weight


General Desc:
Aniline is a yellowish to brownish, oily liquid with a aromatic, amine-like or musty, fishy odor.  It has a flash point of 158 deg. F.  It can react with toluene diisocyanate with the reaction leading to possible ignition.  It is heavier than water and slightly soluble in water and its vapors are heavier than air.  It is toxic by skin absorption and inhalation.  Toxic oxides of nitrogen are produced during combustion of this material.  It weighs 8.5 lbs./gal.  It is used to manufacture other chemicals, especially dyes, photographic chemicals, agricultural chemicals and others. (¬ AAR, 1999)

Properties:
Flash Point:  158¦ F (cc) (EPA, 1998)

Lower Exp Limit:  1.3 % (EPA, 1998)

Upper Exp Limit:  20 to 25 % (EPA, 1998)

Auto Igtn Temp:  1139¦ F (USCG, 1999)

Melting Point:  21¦ F (EPA, 1998)

Vapor Pressure:  0.67 mm at 77¦ F (EPA, 1998)

Vapor Density:  3.22 (EPA, 1998)

Specific Gravity:  1.022 at 68¦ F (NTP, 1992)

Boiling Point:  363 to 367¦ F at 760 mm (EPA, 1998)

Molecular Weight:  93.12 (EPA, 1998)

IDLH:  100 ppm; Not applicable for Aniline (and homologs), a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  2 ppm  For Aniline.  Skin. (¬ACGIH, 1999)

Water Solubility:  10-50 mg/mL at 73¦ F (NTP, 1992)

First Aid:
Signs and Symptoms of Acute Aniline Exposure: Signs and symptoms of acute exposure to aniline may be severe and include dyspnea (shortness of breath), respiratory paralysis, cardiac arrhythmias, and cardiovascular collapse.  Victims may experience headache, irritability, disorientation, lethargy, weakness, incoordination, dizziness, and drowsiness.  Delerium, shock, convulsions, and coma may also be observed.  Gastrointestinal effects include dryness of throat, nausea, and vomiting.  Painful urination, oliguria (scanty urination), and hematuria (bloody urine) may occur.  Aniline may irritate the skin, eyes, and mucous membranes; cyanosis (blue tint to skin and mucous membranes) is a common finding. Note: Victims at special risk include individuals with glucose-6-phosphate-dehydrogenase deficiency, those with liver and kidney disorders, blood diseases, or a history of alcoholism. Emergency Life-Support Procedures: Acute exposure to aniline may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to aniline. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  RUSH to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to aniline. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas twice with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  RUSH to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 3.  Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of aniline is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.Ipecac should not be administered to children under 6 months of age. Warning: Ingestion of aniline may result in sudden onset of seizures or loss of consciousness.  Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4. The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  RUSH to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.    Combustion products include corrosive or toxic vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash or cement powder.  Apply "universal" gelling agent to immobilize spill.    Water spill:  Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom.  If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount.  Remove trapped material with suction hoses.  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Firefighting:
Fight fire from maximum distance. Dike fire control water for later disposal and do not scatter material.  If a leak or spill has not ignited, use water spray to control vapors.  Wear self-contained breathing apparatus with a full face piece operated in pressure-demand or other positive pressure mode and special protective clothing.Use water spray, dry chemical, foam or carbon dioxide. Use water to keep fire-exposed containers cool. (EPA, 1998)

Reactivity:
STABILITY:  This compound is heat sensitive.  It darkens on exposure to air and light.  It also polymerizes to a resinous mass on exposure to air and light.  Steam volatile.REACTIVITY:  This compound can react vigorously with some oxidizing materials (including perchloric acid, fuming nitric acid, sodium peroxide and ozone).  It reacts violently with BCl3.  It combines with acids to form salts.  This compound dissolves alkalies or alkaline earth metals with evolution of hydrogen.  It is incompatible with albumin, solutions of iron, zinc and aluminum, acids and alkalies.  This compound couples readily with phenols and aromatic amines.  It is easily acylated and alkylated.  It is corrosive to copper and copper alloys.  Spontaneously explosive reactions occur with benzenediazonium-2-carboxylate, dibenzoyl peroxide, fluorine nitrate, nitrosyl perchlorate, peroxodisulfuric acid and tetranitromethane.  Violent reactions may occur with peroxyformic acid, diisopropyl peroxydicarbonate, fluorine, trichloronitromethane (293 F), acetic anhydride, chlorosulfonic acid, hexachloromelamine, (HNO3 + N2O4 + H2SO4), (nitrobenzene  glycerin), oleum, (HCHO + HClO4), perchromates, K2O2, beta-propiolactone, AgClO4, Na2O2, H2SO4, trichloromelamine, acids, peroxydisulfuric acid, FO3Cl, diisopropyl peroxy-dicarbonate, n-haloimides and trichloronitromethane.  Ignites on contact with sodium peroxide + water.  Forms heat or shock sensitive explosive mixtures with anilinium chloride (detonates at 464 F/7.6 bar), nitro methane, hydrogen peroxide, 1-chloro-2,3-epoxypropane and peroxomonosulfuric acid.  Reactions with perchloryl fluoride form explosive products. (NTP, 1992)

REL NOTES:
CARCINOGEN (Ca); REDUCE EXPOSURE TO LOWEST FEASIBLE CONC.

Symptoms:
headaches; weakness, dizziness; cyanosis; ataxia; dyspnea on effort; tachycardia; eye irritation (carcinogenic)

Health Effects:
hematologic (blood) disturbances---methemoglobinemia; acute toxicity---short-term high hazard effects; suspect carcinogen; LD50 (oral, rat) 440 mg/kg

Target Organ:
blood, cardiovascular system, eyes, liver, kidneys, respiratory system

Synonyms:
Aminobenzene, Aniline oil, Benzenamine, Phenylamine

Physical Description:
Colorless to brown, oily liquid with an aromatic amine-like odor.

Exposure Symptoms:
Head, weak, dizz; cyan; ataxia; dysp on effort; tacar; irrit eyes; methemo; cirr; [carc]


General Desc:
Dibromochloropropane is a colorless liquid which is soluble in water and weighs more than water.  It has a flash point of 170 deg. F.  and a boiling point of 195 deg. F.  It is toxic by ingestion and inhalation.  It is used as a pesticide and fumigant. (¬ AAR, 1999)

Properties:
Flash Point:  170¦ F (NTP, 1992)

Melting Point:  43¦ F (NTP, 1992)

Vapor Pressure:  0.8 mm Hg at 70¦ F (NTP, 1992)

Specific Gravity:  2.08 at 68¦ F (NTP, 1992)

Boiling Point:  385¦ F (NTP, 1992)

Molecular Weight:  236.35 (NTP, 1992)

Water Solubility:  <0.1 mg/mL at 64¦ F (NTP, 1992)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.  It is stable in neutral and acidic media.  It is hydrolyzed in alkali.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical reacts with chemically active metals such as aluminum, magnesium, tin and their alloys.  It will attack some rubber materials and coatings. (NTP, 1992)

Symptoms:
drowsiness, nausea, vomiting; eye, nose, throat, skin irritation; pulmonary edema (carcinogenic)

Target Organ:
eyes, skin, respiratory system, central nervous system, liver, kidneys, spleen, reproductive system, digestive system

Physical Description:
Dense yellow or amber liquid with a pungent odor at high concentrations.

Exposure Symptoms:
Irrit eyes, skin, nose, throat; drow; nau, vomit; pulm edema; liver, kidney inj; sterility; [carc]

86 REL Notes:
According to NIOSH, their recommendation is superseded by the OSHA standard


General Desc:
PHYSICAL DESCRIPTION:  Clear, colorless to  light amber liquid.

PHYSICAL DATA:  Spicy odor. (NTP, 1992)

Properties:
Flash Point:  222¦ F (NTP, 1992)

Melting Point:  41-45¦ F (NTP, 1992)

Vapor Pressure:  0.07 mm Hg at 77¦ F (NTP, 1992)

Vapor Density:  6.18 (NTP, 1992)

Specific Gravity:  1.024 at 77¦ F (NTP, 1992)

Boiling Point:  451¦ F (NTP, 1992)

Molecular Weight:  179.2 (NTP, 1992)

Water Solubility:  greater than or equal to 100 mg/mL at 64¦ F (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION.  Then, use absorbent paper to pick up all liquid spill material.  Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal.  Wash any surfaces you may have contaminated with a soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should store this chemical under refrigerated temperatures, and keep it away from oxidizing materials.  STORE AWAY FROM SOURCES OF IGNITION. (NTP, 1992)

Firefighting:
Fires involving this compound should be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.  Solutions of this chemical should be stable for 24 hours under normal lab conditions.REACTIVITY:  This compound may react with strong oxidizing agents and strong acids. (NTP, 1992)

REL NOTES:
REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION

Symptoms:
irritation eyes, skin, respiratory system; dyspnea (breathing difficulty); abdominal pain; potential occupational carcinogen

Target Organ:
eyes, skin, respiratory system, central nervous system, gastrointestinal tract

Synonyms:
Hexamethylphosphoric triamide, Hexamethylphosphorotriamide, HMPA, Tris(dimethylamino)phosphine oxide

Physical Description:
Clear, colorless liquid with an aromatic or mild, amine-like odor.

Exposure Symptoms:
Irrit eyes, skin, resp sys; dysp; abdom pain; [carc]


General Desc:
Ethyl acrylate is a clear colorless liquid with an acrid odor.  It has a flash point of 60 deg. F.  If the material is subjected to heat for prolonged periods or becomes contaminated it is subject to polymerization with evolution of heat.  If the polymerization takes place inside a container the container may violently rupture.  The material is lighter than water and slightly soluble in water.  The vapors are heavier than air.  It is used to make paints and plastics. (¬ AAR, 1999)

Properties:
Flash Point:  48¦ F (NTP, 1992)

Lower Exp Limit:  1.8% (NTP, 1992)

Upper Exp Limit:  12.1% (NTP, 1992)

Auto Igtn Temp:  721¦ F (USCG, 1999)

Melting Point:  -96.2¦ F (NTP, 1992)

Vapor Pressure:  29.3 mm Hg at 68¦ F; 40 mm Hg at 79¦ F (NTP, 1992)

Vapor Density:  3.45 (NTP, 1992)

Specific Gravity:  0.9234 at 68¦ F (NTP, 1992)

Boiling Point:  211.6¦ F (NTP, 1992)

Molecular Weight:  100.12 (NTP, 1992)

IDLH:  300 ppm; Not applicable for Ethyl acrylate, a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  5 ppm  Suspected human carcinogen. Skin. (¬ACGIH, 1999)

TLV STEL:  15 ppm  Suspected human carcinogen.  Skin. (¬ACGIH, 1999)

Water Solubility:  10-50 mg/mL at 70¦ F (NTP, 1992)

Reactivity:
CHEMICAL PROFILE:  A flammable liquid, confirmed carcinogen. It can react vigorously with oxidizing reagents, it reacts violently with chlorosulfonic acid [Sax, 9th ed., 1996, p. 1515]. When an inhibited monomer was placed in a clear glass bottle exposed to sunlight, exothermic polymerization set in and caused the bottle to burst. The use of brown glass or metal containers and increase in inhibitor concentration (to 200 ppm; tenfold) was recommended [MCA Case History No. 1759]. (REACTIVITY, 1999)

Symptoms:
eye, respiratory system, skin irritation;  (carcinogenic)

Synonyms:
Ethyl acrylate (inhibited), Ethyl ester of acrylic acid, Ethyl propenoate


General Desc:
Ethanolamine is a clear colorless liquid with an ammonia-like odor.  It is combustible and has a flash point of 185 deg. F.  It is soluble in water with release of heat.  It is corrosive to tissue and may attack some materials like copper, brass, and rubber.  Toxic oxides of nitrogen are produced during combustion of this material. (¬ AAR, 1999)

Properties:
Flash Point:  200¦ F (NTP, 1992)

Lower Exp Limit:  5.5% (NTP, 1992)

Upper Exp Limit:  17% (NTP, 1992)

Auto Igtn Temp:  770¦ F (NTP, 1992)

Melting Point:  50.5¦ F (NTP, 1992)

Vapor Pressure:  0.4 mm Hg at 68¦ F; 6 mm Hg at 140¦ F (NTP, 1992)

Vapor Density:  2.1 (NTP, 1992)

Specific Gravity:  1.0180 at 68¦ F (NTP, 1992)

Boiling Point:  338¦ F (NTP, 1992)

Molecular Weight:  61.08 (NTP, 1992)

IDLH:  30 ppm (NIOSH, 1997)

TLV TWA:  3 ppm (¬ACGIH, 1999)

TLV STEL:  6 ppm (¬ACGIH, 1999)

Water Solubility:  greater than or equal to 100 mg/mL at 68¦ F (NTP, 1992)

Reactivity:
CHEMICAL PROFILE:  A strong base, moderately toxic. Flammable when exposed to to heat or flame. Violent reaction with organic acids (acetic acid, acrylic acid), strong inorganic acids (hydrochloric acid, hydro-fluoric acid, nitric acid, sulfuric acid, chlorosulfonic acid), acetic anhydride, acrolein, acrylonitrile, cellulose, epichlorohydrine, mesityl oxide, beta-propiolactone, vinyl acetate. When heated to decomposition it emits toxic fumes of nitrogen oxides [Sax, 9th ed., 1996, p. 1498]. (REACTIVITY, 1999)

Symptoms:
respiratory system, skin, and eye irritation; lethargy

Health Effects:
irritation-eye, nose, throat, skin---marked; cumulative liver, lung and kidney damage; narcosis

Synonyms:
2-Aminoethanol,  -Aminoethyl alcohol, Ethylolamine, 2-Hydroxyethylamine, Monoethanolamine

Physical Description:
Colorless, viscous liquid or solid (below 51ºF) with an unpleasant, ammonia-like odor.


General Desc:
Physical State Shipped: Solid

Odor: Odorless

Color: Colorless

Characteristics in Water: Sinks in water. (USCG, 1999)

Properties:
Flash Point:  324-340¦ F (NTP, 1992)

Melting Point:  227-228¦ F (NTP, 1992)

Vapor Pressure:  0.00000015 mm Hg at 68¦ F (NTP, 1992)

Specific Gravity:  1.56 at 59¦ F (NTP, 1992)

Boiling Point:  500¦ F (NTP, 1992)

Molecular Weight:  354.49 (NTP, 1992)

IDLH:  500 mg/m3; Not applicable for DDT, a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  1 mg/m3 (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 70¦ F (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN:  IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION:  If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.  Generally, the induction of vomiting is NOT recommended outside of a physician's care due to the risk of aspirating the chemical into the victim's lungs.  However, if the victim is conscious and not convulsing and if medical help is not readily available, consider the risk of inducing vomiting because of the high toxicity of the chemical ingested.  Ipecac syrup or salt water may be used in such an emergency.  IMMEDIATELY transport the victim to a hospital.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body.  DO NOT INDUCE VOMITING.  IMMEDIATELY transport the victim to a hospital. OTHER:  Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring.  Recommendations from the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure. (NTP, 1992)

Firefighting:
Fire Extinguishing Agents: Water, foam, dry chemical, or carbon dioxide (USCG, 1999)

Reactivity:
STABILITY:  This chemical is sensitive to exposure to ultraviolet light.  It is also sensitive to high temperatures.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical may react with iron, aluminum, aluminum and iron salts, and alkalies.  It is incompatible with ferric chloride and aluminum chloride.  It can also react with strong oxidizing materials. (NTP, 1992)

Symptoms:
paresthesia of tongue, lips, face; tremors; apprehension, dizziness, fatigue,  confusion, malaise; headaches; convulsions; paresis of hands; vomiting; eye, skin irritation; [potential occupational carcinogen]

Health Effects:
chronic/cumulative toxicity-(central nervous system) and mutagen

Target Organ:
eyes, skin, central nervous system, kidneys, liver, peripheral nervous system, in animals: liver, lung, lymphatic tumors

Physical Description:
Colorless crystals or off-white powder with a slight, aromatic odor.

Exposure Symptoms:
Irrit eyes, skin; pares tongue, lips, face; tremor; appre, dizz, conf, mal, head, ftg; convuls; paresis hands; vomit; [carc]

86 REL Notes:
Carcinogen; lowest reliably detectable level (o.5mg/m3)


General Desc:
Helium is a colorless odorless gas.  The vapors are lighter than air (it is one-seventh as heavy as air).  Helium is non-flammable and is only slightly soluble in water.  It is chemically inert.  Exposure of the container to prolonged heat or fire may cause it to rupture violently and rocket.  Helium is used in arc welding, to trace leaks in refrigeration and other closed systems and as a lifting gas for lighter-than-air aircraft. (¬ AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Contact of very cold liquefied gas with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid gas contacts water in a closed container, (Handling Chemicals Safely 1980). (REACTIVITY, 1999)


General Desc:
Carbon black oil is a dark colored liquid with a petroleum-like odor.  It has a flash point below 200 deg. F.  It is lighter than water and insoluble in water.  Its vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  < 200¦ F (unspc) (¬ AAR, 1999)

Reactivity:
Strong oxidizers such as chlorates, bromates & nitrates

REL NOTES:
TWA = 0.1 mg PAHs/m3 IN THE PRESENCE OF PAHs, IDENTIFIED AS A CARCINOGEN (Ca) IN THE PRESENCE OF PAH's, 10-HR TWA

Symptoms:
cough; irritation eyes; in presence of polycyclic aromatic hydrocarbons: potential occupational carcinogen

Health Effects:
cumulative lung damage; cumulative heart damage

Synonyms:
Acetylene black, Channel black, Furnace black, Lamp black, Thermal black

Exposure Symptoms:
Cough; irrit eyes; in presence of polycyclic aromatic hydrocarbons: [carc]

86 REL Notes:
In presence of PAHs: Carcinogen; 0.1mg/m3 TWA


General Desc:
PHYSICAL DESCRIPTION:  White solid.

PHYSICAL DATA:  Aromatic odor. (NTP, 1992)

Properties:
Melting Point:  279¦ F (NTP, 1992)

Vapor Pressure:  <1 mm Hg at 68¦ F (NTP, 1992)

Specific Gravity:  1.78 (NIOSH, 1997)

Boiling Point:  649-729¦ F (NTP, 1992)

Molecular Weight:  334.90 (NTP, 1992)

IDLH:  2 mg/m3 (NIOSH, 1997)

Water Solubility:  Insoluble (NTP, 1992)

Symptoms:
acneform dermatitis; nausea; confusion; jaundice; coma

Physical Description:
White to light-yellow solid with an aromatic odor.


Main Chemical Name:
PHOSPHORUS PENTASULFIDE, FREE FROM YELLOW AND WHITE PHOSPHORUS

General Desc:
Phosphorus pentasulfide is a light greenish yellow solid with an odor of rotten eggs that may paralyze the sense of smell at hazardous concentrations in air.  It is heavier than water and will slowly react with water or moist air to form toxic hydrogen sulfide (H2S) gas and corrosive phosphoric acid.  It may also spontaneously heat and ignite in the presence of moisture.  Phosphorus pentasulfide is a flammable solid that can be ignited by sparks or friction and its dust presents an explosion hazard in air at sufficient concentrations.  Hydrogen sulfide gas evolved from reactions with water may also form explosive mixtures with air.  It weighs 127 lbs./cubic foot.  It is used for making lube oil additives, insecticides, flotation agents, safety matches, blown asphalt, and other products and chemicals. (¬ AAR, 1999)

Properties:
Auto Igtn Temp:  288¦ F (USCG, 1999)

Melting Point:  527¦ F (USCG, 1999)

Vapor Pressure:  1 mm at 572¦F (NIOSH, 1997)

Specific Gravity:  2.03 weight in lbs/cubic foot (¬ AAR, 1999)

Boiling Point:  957¦ F at 760 mm (USCG, 1999)

Molecular Weight:  222.27 (USCG, 1999)

IDLH:  250 mg/m3 (NIOSH, 1997)

TLV TWA:  1 mg/m3 (¬ACGIH, 1999)

TLV STEL:  3 mg/m3 (¬ACGIH, 1999)

Water Solubility:  Reacts (NIOSH, 1997)

First Aid:
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical. Skin: If this solid chemical contacts the skin, dust it off immediately and then flush the contaminated skin with water. If this chemical or liquid containing this chemical penetrate the clothing, promptly remove the clothing and flush the skin with water. Get medical attention immediately. Breathing: If a person breathes large amounts of this chemical, move the exposed  person to fresh air at once. If breathing has stopped, perform mouth-to-mouth  resuscitation. Keep the affected person warm and at rest. Get medical  attention as soon as possible. Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 1997)

Nonfire Spill Response:
Do not use water.  Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Keep material dry.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water.    Water spill:  Neutralize with agricultural lime (CaO), crushed limestone (CaCO3), or sodium bicarbonate (NaHCO3). ( AAR, 1999)

Firefighting:
Do not use water.  Use dry chemical or carbon dioxide.  When fire is out, cover all suspected material with dry sand or earth to prevent re-ignition until material can be permanently disposed of. ( AAR, 1999)

Reactivity:
AIR AND WATER REACTIONS:  Heats spontaneously, but may ignite in the presence of water (Haz. Chem. Data. 1969). Reaction with water forms toxic hydrogen sulfide gas and phosphoric acid. May heat and spontaneously ignite in presence of moisture.CHEMICAL PROFILE:  Light-green crystalline material, toxic and flammable. Dangerous when wet. Vigorous reaction with strong oxidants. Exothermically violent decomposition reaction with water, steam or acids to produce irritaiting fumes of phosphorus pentoxide and highly toxic hydrogen sulfide gas. In contact with limited amounts of water may ignite [Haz. Chem. Data, 1975, p. 239]. (REACTIVITY, 1999)

Symptoms:
apnea; coma, convulsions; eye irritation, conjunctivitis pain, lacrimation, photophobia, kerato-conjunctivitis, corneal vesiculation; respiratory system irritation; dizziness; headaches; fatigue; irritability, insomnia; gastrointestinal disturbance

Health Effects:
irritation-eye, nose, throat, skin---marked; h2s hazard

Synonyms:
Phosphorus persulfide, Phosphorus sulfide, Sulfur phosphide

Physical Description:
Greenish-gray to yellow, crystalline solid with an odor of rotten eggs.

Exposure Symptoms:
Irrit eyes, skin, resp sys; apnea, coma, convuls; conj pain, lac, photo, kerato-conj, corn vesic; dizz; head; ftg; irrity, insom; GI dist


General Desc:
Xylene is a clear colorless liquid with a characteristic aromatic odor.  It has a flash point between 81 and 115 deg. F.  It is lighter than water and insoluble in water.  It can be toxic by ingestion.  The vapors are heavier than air and may be narcotic in high concentrations.  It weighs 7.2 lbs./gal.  It is used as a solvent for paints and adhesives, and to make other chemicals. (¬ AAR, 1999)

Properties:
Flash Point:  78¦ F (NTP, 1992)

Lower Exp Limit:  1.0% (NTP, 1992)

Upper Exp Limit:  7.0% (NTP, 1992)

Auto Igtn Temp:  870¦ F (NTP, 1992)

Vapor Pressure:  6.72 mm Hg at 70¦ F; 10 mm Hg at 82¦ F (NTP, 1992)

Vapor Density:  3.7 (NTP, 1992)

Specific Gravity:  0.860 at 68¦ F (NTP, 1992)

Boiling Point:  279-291¦ F (NTP, 1992)

Molecular Weight:  106.17 (NTP, 1992)

IDLH:  900 ppm (NIOSH, 1997)

TLV TWA:  100 ppm (¬ACGIH, 1999)

TLV STEL:  150 ppm (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 72¦ F (NTP, 1992)

Reactivity:
CHEMICAL PROFILE:  Xylene reacts with sulfuric acid, nitric acid, and strong oxidants liberating heat.  (Handling Chemicals Safely 1980. p. 962). (REACTIVITY, 1999)

Synonyms:
1,2(3 or 4)-Dimethylbenzene, ortho(meta or para)-Xylene, o(m or p)-Xylol

Exposure Symptoms:
Irritation eyes, skin, nose, throat; dizziness, excitement, drowsiness, incoordination, staggering gait; corneal vacuolization; anorexia, nausea, vomiting, abdominal pain; dermatitis


General Desc:
Dinitri-o-cresol is a yellow solid which is a slightly soluble in water.  When heated to decomposition it emits toxic fumes of oxides of nitrogen.  It is toxic by skin absorption, inhalation and ingestion.  It is soluble in alcohol, acetone, ether and solutions of sodium or potassium hydroxides. (¬ AAR, 1999)

Properties:
Melting Point:  190¦ F (NIOSH, 1997)

Vapor Pressure:  0.00005 mm (NIOSH, 1997)

Specific Gravity:  1.1 (estimated) (NIOSH, 1997)

Boiling Point:  594¦F (NIOSH, 1997)

Molecular Weight:  198.1 (NIOSH, 1997)

IDLH:  5 mg/m3 (NIOSH, 1997)

TLV TWA:  0.2 mg/m3  Skin. (¬ACGIH, 1999)

Water Solubility:  0.01% (NIOSH, 1997)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water.    Water spill:  Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom.  Remove trapped material with suction hoses. ( AAR, 1999)

Symptoms:
sense of well being; headaches; fever; lassitude; profuse sweating, excessive thirst; tachycardia; hyperpnea, coughing, shortness of breathing; coma

Health Effects:
cumulative systemic (metabolic) toxin; mutagen

Synonyms:
4,6-Dinitro-o-cresol; 3,5-Dinitro-2-hydroxytoluene; 4,6-Dinitro-2-methyl phenol; DNC; DNOC

Exposure Symptoms:
Sense of well being; head, fever, lass, profuse sweat, excess thirst, tacar, hyperpnea, cough, short breath, coma


General Desc:
Resorcinol is a white crystalline solid changing to pink on exposure to light.  It is soluble in water.  It will burn though it may take some effort to ignite.  Resorcinol weighs approximately 10.5 lbs./gal.  Resorcinol is irritating to skin and eyes and may be toxic by ingestion.  It is used to make plastics, pharmaceuticals, and for many other uses. (¬ AAR, 1999)

Properties:
Flash Point:  261¦ F (NTP, 1992)

Lower Exp Limit:  1.4%  at 738¦ F (NTP, 1992)

Upper Exp Limit:  1.4 % at 200¦F. (USCG, 1999)

Auto Igtn Temp:  1,125¦ F (USCG, 1999)

Melting Point:  228-232¦ F (NTP, 1992)

Vapor Pressure:  1 mm Hg at 227.1¦ F; 0.0002 mm Hg at 77¦ F (NTP, 1992)

Vapor Density:  3.79 (NTP, 1992)

Specific Gravity:  1.272 at 59¦ F (NTP, 1992)

Boiling Point:  531-536¦ F (NTP, 1992)

Molecular Weight:  110.11 (NTP, 1992)

TLV TWA:  10 ppm (¬ACGIH, 1999)

TLV STEL:  20 ppm (¬ACGIH, 1999)

Water Solubility:  greater than or equal to 100 mg/mL at 65.3¦ F (NTP, 1992)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water.    Water spill:  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Firefighting:
Extinguish fire using agent suitable for type of surrounding fire.  (Material itself does not burn or burns with difficulty.)  Use water in flooding quantities as fog. ( AAR, 1999)

Reactivity:
STABILITY:  This chemical turns pink on exposure to air or light, or upon contact with iron.  It is hygroscopic.REACTIVITY:  This chemical is incompatible with acetanilide, albumin, alkalies, antipyrine, camphor, iron salts, menthol, spirit nitrous ether and urethane.  It can react with oxidizing materials. (NTP, 1992)

Symptoms:
irritation eyes, skin, nose, throat, upper respiratory system; methemoglobinemia; cyanosis, convulsions; restlessness, bluish skin, increase(d) heart rate, dyspnea (breathing difficulty); dizziness, drowsiness, hypothermia, hemoglobinuria; spleen, kidney, liver changes; dermatitis

Health Effects:
irritation-eye, nose, throat, skin---moderate; cumulative systemic toxicity; mutagen

Target Organ:
eyes, skin, respiratory system, cardiovascular system, central nervous system, blood, spleen, liver, kidneys

Synonyms:
1,3-Benzenediol; m-Benzenediol; 1,3-Dihydroxybenzene; m-Dihydroxybenzene; 3-Hydroxyphenol; m-Hydroxyphenol

Physical Description:
White needles, plates, crystals, flakes, or powder with a faint odor.

Notes 2:
[Note: Turns pink on exposure to air or light, or contact with iron.]

Exposure Symptoms:
Irrit eyes, skin, nose, throat, upper resp sys; methemo; cyan, convuls; restless, bluish skin, incr heart rate, dysp; dizz, drow, hypothermia, hemog; spleen, kidney, liver changes; derm


General Desc:
PHYSICAL DESCRIPTION:  White powder.

PHYSICAL DATA:  Weak chlorine odor.  Conflagrates at 414º F (turns brown).  Chlorine gas is evolved at >410º F.  pH of aqueous solution: 4.4. (NTP, 1992)

Properties:
Flash Point:  346¦ F (cc) (NIOSH, 1997)

Melting Point:  270¦ F (NTP, 1992)

Vapor Density:  6.8 (NTP, 1992)

Specific Gravity:  1.5 at 68¦ F (NTP, 1992)

Boiling Point:  Sublimes at 212¦ F (NTP, 1992)

Molecular Weight:  197.03 (NTP, 1992)

IDLH:  5 mg/m3 (NIOSH, 1997)

Water Solubility:  Reaction (NTP, 1992)

Reactivity:
STABILITY:  This chemical is sensitive to exposure to light, air, and moisture.REACTIVITY:  This compound reacts violently with xylene.  It is incompatible with strong acids, easily oxidized materials, ammonia salts and sulfides.  It will react with water or steam to produce toxic and corrosive fumes.  At a pH of 9, it decomposes completely. (NTP, 1992)

Symptoms:
eye, mucous membrane, and respiratory system irritation


General Desc:
Hexachlorobenzene is a white crystalline substance.  It is insoluble in water and weighs more than water.  Contact with the material may cause irritation to skin, eyes, and mucous membranes.  It may be toxic by ingestion.  It is used to make other chemicals. (¬ AAR, 1999)

Properties:
Flash Point:  468¦ F (NTP, 1992)

Melting Point:  441-444¦ F (NTP, 1992)

Vapor Pressure:  1 mm Hg at 237.9¦ F; 0.0000109 mm Hg at 68¦ F (NTP, 1992)

Vapor Density:  9.8 (NTP, 1992)

Specific Gravity:  2.044 at 73¦ F (NTP, 1992)

Boiling Point:  612¦ F (sublimes) (NTP, 1992)

Molecular Weight:  284.76 (NTP, 1992)

TLV TWA:  0.025 mg/m3, Suspected Human Carcinogen (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 68¦ F (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING.  If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.  Be prepared to transport the victim to a hospital if advised by a physician.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the Headache lower than the body.  DO NOT INDUCE VOMITING.  IMMEDIATELY transport the victim to a hospital. OTHER:  Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring.  Recommendations from the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure. (NTP, 1992)

Reactivity:
STABILITY:  This chemical is sensitive to moisture.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical reacts violently with dimethylformamide. (NTP, 1992)


General Desc:
PHYSICAL DESCRIPTION:  Liquid. (NTP, 1992)

Properties:
Melting Point:  23-32¦ F (NTP, 1992)

Boiling Point:  None reported (NIOSH, 1997)

Molecular Weight:  230.22 (NTP, 1992)

IDLH:  15 mg/m3; Not applicable for tert-Butyl chromate, a potential human carcinogen. (NIOSH, 1997)

Water Solubility:  ? (NIOSH, 1997)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN:  IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop.  IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION:  Some heavy metals are VERY TOXIC POISONS, especially if their salts are very soluble in water (e.g., lead, chromium, mercury, bismuth, osmium, and arsenic).  IMMEDIATELY call a hospital or poison control center and locate activated charcoal, egg whites, or milk in case the medical advisor recommends administering one of them.  Also locate Ipecac syrup or a glass of salt water in case the medical advisor recommends inducing vomiting.  Usually, this is NOT RECOMMENDED outside of a physician's care.  If advice from a physician is not readily available and the victim is conscious and not convulsing, give the victim a glass of activated charcoal slurry in water or, if this is not available, a glass of milk, or beaten egg whites and IMMEDIATELY transport victim to a hospital.  If the victim is convulsing or unconscious, do not give anything by mouth, assure that the victim's airway is open and lay the victim on his/her side with the Headache lower than the body.  DO NOT INDUCE VOMITING.  IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Reactivity:
STABILITY:  This compound is unstable except in solution.REACTIVITY:  This compound is hydrolyzed by water. (NTP, 1992)

Health Effects:
suspect carcinogen; irritation-eye, nose, throat, skin---marked;

Exposure Symptoms:
Irrit eyes, skin, resp sys; eye, skin burns; drow, musc weak; skin ulcers; lung changes; [carc]


General Desc:
Petroleum spirit is a clear colorless liquid with a petroleum-like odor.  It has a flash point of less than 73 deg. F.  It is lighter than water and insoluble in water.  Its vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  20 to 55¦ F (cc) (USCG, 1999)

Lower Exp Limit:  0.9 % (USCG, 1999)

Upper Exp Limit:  6.7 % (USCG, 1999)

Auto Igtn Temp:  450¦ F (USCG, 1999)

Vapor Pressure:  6.20 mm (USCG, 1999)

Specific Gravity:  0.73-0.76 at 60 ¦F (NIOSH, 1997)

Boiling Point:  200 to 300¦ F at 760 mm (USCG, 1999)

Molecular Weight:  87-114
(approx) (NIOSH, 1997)

TLV TWA:  300 ppm  For VM & P Naphtha. (¬ACGIH, 1999)

Water Solubility:  Insoluble (NIOSH, 1997)

First Aid:
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical. Skin: If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.  Breathing: If a person breathes large amounts of this chemical, move the exposed  person to fresh air at once. If breathing has stopped, perform mouth-to-mouth  resuscitation. Keep the affected person warm and at rest. Get medical  attention as soon as possible. Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 1997)

Reactivity:
This compound is incompatible with the following:None reported [Note: VM&P Naphtha is a refined petroleum solvent predominantly C7-C11 which is typically 55% paraffins, 30% monocycloparaffins, 2% dicycloparaffins & 12% alklybenzenes.] (NIOSH, 1997)

Symptoms:
irritation eyes, upper respiratory system; dermatitis; central nervous system depressant/depression; chemical pneumonia (aspir liquid)

Synonyms:
Ligroin, Painters naphtha, Petroleum ether, Petroleum spirit, Refined solvent naphtha, Varnish makers' & painters' naphtha

Physical Description:
Clear to yellowish liquid with a pleasant, aromatic odor.

Exposure Symptoms:
Irrit eyes, upper resp sys; derm; CNS depres; chemical pneu (aspir liquid)

86 REL Notes:
15 minute ceiling, as refined petroleum solvent


PEL NOTES:
MINIMIZE EXPOSURE TO NIAX(R) CATALYST ESN, COMPONENTS AND FORMULATIONS CONTAINING EITHER COMPONENT

REL NOTES:
MINIMIZE EXPOSURE TO NIAX(R) CATALYST ESN, COMPONENTS AND FORMULATIONS CONTAINING EITHER COMPONENT

Symptoms:
irritation eyes, skin; urinary dysfunction; neurological disorders; pins & needles in hands & feet; muscle weakness, lassitude (weakness, exhaustion), nausea, vomiting; decreased nerve conduction in lower legs

Target Organ:
eyes, skin, central nervous system, urinary tract

Synonyms:
3-(Dimethylamino)propionitrile; N,N-Dimethylamino-3-propionitrile [Note: a component (95%) of NAIX® Catalyst ESN, along with bis (2-(dimethylamino)ethyl) ether (5%)]

Exposure Symptoms:
Irrit eyes, skin; urinary dysfunc; neurological disorders; pins & needles in hands & feet; musc weak, lass, nau, vomit; decr nerve conduction in lower legs

86 REL Notes:
OSHA and NIOSH recommend that exposure to this Niax Catalyst ESN component be minimized


General Desc:
N,N-dimethyl formamide is a water-white liquid.  It has a faint fishy odor.  It is soluble in water and weighs slightly less than water.  Its flash point is 136 deg. F.  and the vapors are heavier than air.  It may cause harm if absorbed through the skin or inhaled.  It may irritate eyes and skin. (¬ AAR, 1999)

Properties:
Flash Point:  153¦ F (NTP, 1992)

Lower Exp Limit:  2.2%  at 212¦ F (NTP, 1992)

Upper Exp Limit:  15.2%  at 212¦ F (NTP, 1992)

Auto Igtn Temp:  833¦ F (USCG, 1999)

Melting Point:  -78¦ F (NTP, 1992)

Vapor Pressure:  3.7 mm Hg at 77¦ F; 2.7 mm Hg at 68¦ F (NTP, 1992)

Vapor Density:  2.51 (NTP, 1992)

Specific Gravity:  0.9487 at 68¦ F (NTP, 1992)

Boiling Point:  300-313¦ F at 760 mm Hg (NTP, 1992)

Molecular Weight:  73.09 (NTP, 1992)

IDLH:  500 ppm (NIOSH, 1997)

TLV TWA:  10 ppm  Skin. (¬ACGIH, 1999)

ERPG-1:  2 ppm (AIHA, 1999)

ERPG-2:  100 ppm (AIHA, 1999)

ERPG-3:  200 ppm (AIHA, 1999)

Water Solubility:  greater than or equal to 100 mg/mL at 72¦ F (NTP, 1992)

Reactivity:
CHEMICAL PROFILE:  Flammable liquid when exposed to heat or flame, moderately toxic. This common solvent may react violently with a broad range of chemicals, e.g.: alkaline metals (sodium, potassium), azides, hydrides (sodium borohydride, lithium aluminum hydride), bromine, chlorine, carbon tetrachloride, hexachlorocyclohexane, phosphorus pentoxide, triethylaluminum, magnesium nitrate, organic nitrates. Forms explosive mixtures with lithium azide [Bretherick, 5th ed., 1995, p. 453]. Oxidations by chromium trioxide or potassium permanganate may lead to explosion [Pal B. C. et al., Chem. Eng. News, 1981, 59, p. 47]. (REACTIVITY, 1999)

Symptoms:
nausea, vomiting, colic; liver damage, hepatomegaly; high blood pressure; face flush; dermatitis.  in animals:  kidney, heart damage

Health Effects:
cumulative liver damage; central nervous system effects; mutagen

Physical Description:
Colorless to pale-yellow liquid with a faint, amine-like odor.

Exposure Symptoms:
Irrit eyes, skin, resp sys; nau, vomit, colic; liver damage, enlarged liver; high BP; face flush; derm; in animals: kidney, heart damage


Properties:
Flash Point:  (est) 79¦ F (cc) (USCG, 1999)

Lower Exp Limit:  1.00 % (USCG, 1999)

Upper Exp Limit:  7.5 % (USCG, 1999)

Auto Igtn Temp:  715¦ F (USCG, 1999)

Melting Point:  >-148¦ F (USCG, 1999)

Specific Gravity, Liquid:  0.874 at 66.2¦ F (USCG, 1999)

Boiling Point:  256.5¦ F at 760 mm (USCG, 1999)

Molecular Weight:  130.18 (USCG, 1999)

First Aid:
Call a physician.  INHALATION:  Remove from exposure. Administer oxygen if needed.  EYES:  Flush with water for at least 15 min.  SKIN:  Remove contaminated clothing and shoes.  Wash with soap and water. Subsequent treatment is symptomatic and supportive in nature. (USCG, 1999)


General Desc:
Bromoform is a colorless, heavy liquid with a chloroform-like odor.  It is slightly soluble in water.  It is toxic by ingestion, inhalation and skin absorption.  It is used as a solvent and to make pharmaceuticals. (¬ AAR, 1999)

Properties:
Melting Point:  48¦ F (NTP, 1992)

Vapor Pressure:  5 mm Hg at 68¦ F; 5.6 mm Hg at 77¦ F (NTP, 1992)

Vapor Density:  8.7 (NTP, 1992)

Specific Gravity:  2.89 at 68¦ F (NTP, 1992)

Boiling Point:  301.1¦ F (NTP, 1992)

Molecular Weight:  252.75 (NTP, 1992)

IDLH:  850 ppm (NIOSH, 1997)

TLV TWA:  0.5 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  <0.1 mg/mL at 72.5¦ F (NTP, 1992)

Reactivity:
CHEMICAL PROFILE:  A colorless liquid, when heated to decomposition it produces highly toxic fumes of carbon oxybromide (carbonyl bromide) and hydrogen bromide [Sax, 9th ed., 1996, p. 519]. Reaction with powdered potassium or sodium hydroxide, Li or NaK alloys, is violently exothermic [Weizmann, C. et al., J. Am Chem. Soc., 1948, 70, p. 1189). Explosive reaction with crown ethers in the presence of potassium hydroxide [Le Goaller, R. et al., Synth. Comm., 1982, 12, p. 1163]. (REACTIVITY, 1999)

Symptoms:
eye, respiratory system irritation; central nervous system depression; liver damage

Health Effects:
irritation-eye, nose, throat---marked; cumulative liver damage; narcosis

Physical Description:
Colorless to yellow liquid with a chloroform-like odor.

Exposure Symptoms:
Irrit eyes, skin, resp sys; CNS depres; liver, kidney damage


General Desc:
Dichlorodifluoromethane is a colorless gas having a faint ethereal odor.  It is shipped as a liquid under its own vapor pressure.  It is non-combustible.  The vapors are heavier than air and can cause asphyxiation by the displacement of air.  Contact with the liquid can cause frostbite.  Toxic gases can be produced in fires involving this material.  Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. (¬ AAR, 1999)

Properties:
Auto Igtn Temp:  Not flammable (USCG, 1999)

Melting Point:  -252¦ F (NTP, 1992)

Vapor Pressure:  5 atm at 61.0¦ F (NTP, 1992)

Specific Gravity:  1.75 at -175¦ F (NTP, 1992)

Boiling Point:  -21.6¦ F at 760 mm Hg (NTP, 1992)

Molecular Weight:  120.91 (NTP, 1992)

IDLH:  15000 ppm (NIOSH, 1997)

TLV TWA:  1000 ppm (¬ACGIH, 1999)

Water Solubility:  Insoluble (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  If symptoms (such as redness or irritation) develop, immediately transport the victim to a hospital. SKIN:  CAUTION: Exposure of skin to compressed gases may result in freezing of the skin.  Treatment for frostbite may be necessary.  Remove the victim from the source of contamination.  IMMEDIATELY wash affected areas gently with COLD water (and soap, if necessary) while removing and isolating all contaminated clothing.  Dry carefully with clean, soft towels.  If symptoms such as inflammation or irritation develop, IMMEDIATELY call a physician or go to a hospital for treatment. INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  If symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION:  This compound is a gas, therefore inhalation is the first route of exposure. (NTP, 1992)

Reactivity:
CHEMICAL PROFILE:  The reaction of aluminum with various halogenated hydrocarbons produces a self-sustaining reaction with sufficient heat to melt aluminum pieces, examples of other halogenated hydrocarbons are fluorotrichloromethane, dichlorodifluoromethane, chlorodifluoromethane, tetrafluoromethane. The vigor of the reaction appears to be dependent on the combined degree of fluorination and the vapor pressure, Chem. Eng. News 39(27):44(1961). (REACTIVITY, 1999)

Symptoms:
dizziness; tremors; unconsciousness; cardiac arrhythmias, cardiac arrest; liquid: frostbite

Target Organ:
cardiovascular system, peripheral nervous system

Synonyms:
Difluorodichloromethane, Fluorocarbon 12, Freon®12, Genetron®12, Halon®122, Propellant 12, Refrigerant 12

Physical Description:
Colorless gas with an ether-like odor at extremely high concentrations.

Exposure Symptoms:
Dizz, tremor, asphy, uncon, card arrhy, card arrest; liquid: frostbite


General Desc:
Colorless liquid, dyed red, orange or blue with a slight musty odor.

This material is used as an antiknock additive for gasolines; component of mixed alkyl leads for gasoline additives. (EPA, 1998)

Properties:
Flash Point:  100.4¦ F (unspc) (EPA, 1998)

Lower Exp Limit:  1.8% (NTP, 1992)

Melting Point:  -17.5¦ F (EPA, 1998)

Vapor Pressure:  22 mm at 68¦ F (EPA, 1998)

Vapor Density:  6.5 (EPA, 1998)

Specific Gravity:  1.995 at 68¦ F (NTP, 1992)

Boiling Point:  230¦ F at 10 mm Decomposes above 212F (EPA, 1998)

Molecular Weight:  267.33 (EPA, 1998)

IDLH:  40 mg/m3 (NIOSH, 1997)

TLV TWA:  0.15 mg/m3  For Lead.  Skin. (¬ACGIH, 1999)

Water Solubility:  Insoluble (NTP, 1992)

First Aid:
Warning: Effects may be delayed for hours to days.  Caution is advised. Signs and Symptoms of Acute Tetramethyllead Exposure: Signs and symptoms of acute exposure to tetramethyllead may be severe and include anxiety, irritability, headache, insomnia, disorientation, violent/frightening dreams, hyperexcitability, delusions, and hallucinations.  Muscular weakness, tremor, incoordination, convulsions, cerebral edema, and coma may occur.  A metallic taste may be noted.  Sneezing, bronchitis, and pneumonia may be noted.  Bradycardia (slow heart rate), hypotension (low blood pressure), hypothermia, and pallor may also occur.  Gastrointestinal symptoms include vomiting and diarrhea.  Tetramethyllead may irritate moist skin, eyes, and mucous membranes. Emergency Life-Support Procedures: Acute exposure to tetramethyllead may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to tetramethyllead. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  RUSH to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to tetramethyllead. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas THOROUGHLY with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  RUSH to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 3.  Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup).  Water or milk should be given only if victims are conscious and alert. 4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  RUSH to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Caution : Flammable liquid. Avoid sources of extreme heat or ignition including sparks or fire. When burned, toxic fumes of lead oxide will be emitted.Do not touch spilled material; stop leak if you can do it without risk. Use water spray to reduce vapors. Small spills: take up with sand or other non-combustible absorbent material and place into containers for later disposal. Large spills: dike far ahead of spill for later disposal. (EPA, 1998)

Firefighting:
Use water to keep fire exposed containers cool. If leak or spill has not ignited, use water spray to disperse vapors or flush spill. For massive fire in cargo area, use unmanned hose holder or monitor nozzle; if this is impossible withdraw from area and let fire burn.On fires in which containers are not exposed, use water spray, dry chemical, foam or carbon dioxide. (EPA, 1998)

Reactivity:
STABILITY:  This compound is sensitive to heat.REACTIVITY:  This compound can react with strong oxidizers. (NTP, 1992)

Symptoms:
insomnia, bad dreams, restlessness, anxiety; hypotension; nausea, anorexia; delirium, mania; convulsions; coma

Health Effects:
cumulative liver and kidney damage; cumulative central nervous system damage; acute central nervous system effects

Target Organ:
central nervous system, cardiovascular system, kidneys

Physical Description:
Colorless liquid (unless dyed red, orange, or blue) with a fruity odor.

Notes 2:
[Note: Main usage is in anti-knock additives for gasoline.]

Exposure Symptoms:
Insom, bad dreams, restless, anxious; hypotension; nau, anor; delirium, mania, convuls; coma

87-88 TLV Notes:
biologic monitoring essential for personnel contol


General Desc:
Ethylene glycol monomethyl ether is a clear colorless liquid with a pleasant odor.  It has a flash point of 110 deg. F.  It is lighter than water and soluble in water.  Its vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  107¦ F (NTP, 1992)

Lower Exp Limit:  2.5% (NTP, 1992)

Upper Exp Limit:  14% (NTP, 1992)

Auto Igtn Temp:  551¦ F (USCG, 1999)

Melting Point:  -121.2¦ F (NTP, 1992)

Vapor Pressure:  6.2 mm Hg at 68¦ F; 10 mm Hg at 71.6¦ F (NTP, 1992)

Vapor Density:  2.62 (NTP, 1992)

Specific Gravity:  0.9647 at 68¦ F (NTP, 1992)

Boiling Point:  257¦ F at 768 mm Hg (NTP, 1992)

Molecular Weight:  76.11 (NTP, 1992)

IDLH:  200 ppm (NIOSH, 1997)

TLV TWA:  5 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  greater than or equal to 100 mg/mL at 70¦ F (NTP, 1992)

Reactivity:
STABILITY:  This chemical is unstable to prolonged exposure to air and light.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical is incompatible with oxygen and strong oxidizing agents.  Contact with caustics, including alkalies, may result in decomposition.  It is incompatible with acid chlorides and acid anhydrides. (NTP, 1992)

Symptoms:
headaches; drowsiness; weakness, ataxia, tremors; somnolence; anemic pallor; eye irritation; (carcinogenic)

Health Effects:
blood disorders; central nervous system effects; suspect reproductive effects

Target Organ:
eyes, respiratory system, central nervous system, blood, kidneys, reproductive system, hematopoietic system

Synonyms:
EGME, Glycol monomethyl ether, 2-Methoxyethanol, Methyl Cellosolve®

Exposure Symptoms:
Irrit eyes, nose, throat; head, drow, weak; ataxia, tremor, som; anemic pallor; in animals: repro, terato effects


Symptoms:
irritation eyes, skin; cough, chest pain, dyspnea (breathing difficulty), bronchitis pneumonitis; tremor, insomnia, irritability, indecision, headache, fatigue, weakness; stomatitis, salivation; gastrointestinal disturbance, anorexia, weight loss; proteinuria


General Desc:
Methyl isobutyl carbinol is a clear colorless liquid.  It has a flash point of 120 deg. F.  It is lighter than water and soluble in water.  The vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  120 to 130¦ F (oc); 106¦F (cc) (USCG, 1999)

Lower Exp Limit:  1.0 % (USCG, 1999)

Upper Exp Limit:  5.5 % (USCG, 1999)

Melting Point:  <-130¦ F (USCG, 1999)

Vapor Pressure:  3 mm (NIOSH, 1997)

Specific Gravity:  0.81 (NIOSH, 1997)

Boiling Point:  269.2¦ F at 760 mm (USCG, 1999)

Molecular Weight:  102.18 (USCG, 1999)

IDLH:  400 ppm (NIOSH, 1997)

TLV TWA:  25 ppm  Skin. (¬ACGIH, 1999)

TLV STEL:  40 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  2% (NIOSH, 1997)

Symptoms:
eye irritation; headaches; drowsiness; dermatitis

Synonyms:
Isobutylmethylcarbinol, Methyl amyl alcohol, 4-Methyl-2-pentanol, MIBC

Exposure Symptoms:
Irrit eyes, skin; head, drow; derm; in animals: narco


General Desc:
PHYSICAL DESCRIPTION:  Clear colorless liquid.

PHYSICAL DATA:  Sweet fruity odor. (NTP, 1992)

Properties:
Flash Point:  145¦ F (NTP, 1992)

Lower Exp Limit:  7 % (NIOSH, 1997)

Melting Point:  -31¦ F (NTP, 1992)

Vapor Pressure:  20 mm Hg at 63.9¦ F; 22.5 mm Hg at 68¦ F (NTP, 1992)

Specific Gravity:  1.426 at 68¦ F (NTP, 1992)

Boiling Point:  220.3¦ F at 760 mm Hg (NTP, 1992)

Molecular Weight:  164.97 (NTP, 1992)

Water Solubility:  <1 mg/mL at 66¦ F (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION.  Then, use absorbent paper to pick up all liquid spill material.  Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal.  Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should protect this material for prolonged exposure to light and store it under ambient temperatures. (NTP, 1992)

Firefighting:
Fires involving this compound can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

Reactivity:
STABILITY:  This compound may be sensitive to prolonged exposure to light.  Solutions of this compound in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal laboratory conditions. (NTP, 1992)

Symptoms:
irritation eyes; central nervous system depressant/depression, analgesia, anesthesia, seizure, respiratory depressant/depression; liver, kidney injury; in animals: reproductive, teratogenic effects

Target Organ:
eyes, central nervous system, liver, kidneys, reproductive system

Synonyms:
2,2-Dichloro-1,1-difluoroethyl methyl ether; 2,2-Dichloro-1,1-difluoro-1-methoxyethane; Methoflurane; Methoxyfluorane; Penthrane

Exposure Symptoms:
Irrit eyes; CNS depres, analgesia, anes, sez, resp depres; liver, kidney inj; in animals: repro, terato effects


General Desc:
alpha-Naphthylamine is a crystalline solid or a solid dissolved in a liquid.  It is insoluble in water and weighs more than water.  Contact with the material may cause slight irritation to skin, eyes, and mucous membranes.  It may be slightly toxic by ingestion.  It is used to make other chemicals. (¬ AAR, 1999)

Properties:
Flash Point:  315¦ F (NTP, 1992)

Auto Igtn Temp:  905¦ F (NTP, 1992)

Melting Point:  122¦ F (NTP, 1992)

Vapor Pressure:  1 mm Hg at 219.7¦ F; 5 mm Hg at 279.9¦ F (NTP, 1992)

Vapor Density:  4.93 (NTP, 1992)

Specific Gravity:  1.0228 at 68¦ F (NTP, 1992)

Boiling Point:  574¦ F (NTP, 1992)

Molecular Weight:  143.18 (NTP, 1992)

Water Solubility:  <1 mg/mL at 66¦ F (NTP, 1992)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Do not use water.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.    Water spill:  Use natural barriers or oil spill control booms to limit spill travel.  Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom.  Remove trapped material with suction hoses. ( AAR, 1999)

Reactivity:
STABILITY:  This compound is sensitive to exposure to air.  It is also sensitive to light.REACTIVITY:  This compound is incompatible with oxidizing agents.  It is also incompatible with nitrous acid.  It reduces warm ammoniacal silver nitrate. (NTP, 1992)

Symptoms:
dermatitis; hemorrhagic cystitis; dyspnea; ataxia; methemoglobinemia; hematuria; dysuria; (carcinogenic)

Physical Description:
Colorless crystals with an ammonia-like odor.

Notes 2:
[Note: Darkens in air to a reddish-purple color.]

Exposure Symptoms:
Derm; hemorrhagic cystitis; dysp, ataxia, methemo; hema; dysuria; [carc]

86 REL Notes:
Carcinogen; Use 29 CFR 1910.1004 [now included in 29 CFR 1910.1003]


General Desc:
White to yellow, needle-like, crystalline solid with a sweetish odor. (NIOSH, 1997)

Properties:
Flash Point:  290¦ F (cc) (NIOSH, 1997)

Melting Point:  237¦ F (NIOSH, 1997)

Boiling Point:  644¦F (NIOSH, 1997)

Molecular Weight:  199.2 (NIOSH, 1997)

Water Solubility:  Insoluble (NIOSH, 1997)

Reactivity:
This compound is incompatible with the following:Strong reducers (NIOSH, 1997)

Symptoms:
headaches, lethargy, dizziness; dyspnea; ataxia; weakness; methemoglobinemia; urinary burning, acute hemorrhagic cystitis; (carcinogenic)

Synonyms:
p-Nitrobipheny, p-Nitrodiphenyl, 4-Nitrodiphenyl, p-Phenylnitrobenzene, 4-Phenylnitrobenzene, PNB

Physical Description:
White to yellow, needle-like, crystalline solid with a sweetish odor.

Exposure Symptoms:
Head, leth, dizz; dysp; ataxia, weak; methemo; urinary burning; acute hemorrhagic cystitis; [carc]


General Desc:
Methyl acrylate is a clear colorless liquid with an acrid odor.  It has a flash point of 27 deg. F.  The vapors are irritating to the eyes and respiratory system.  If the material is subjected to heat for prolonged periods or becomes contaminated, it is subject to polymerization with evolution of heat.  If the polymerization takes place inside a container, the container may violently rupture.  The material is lighter than water and is slightly soluble in water.  Its vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  44¦ F (NTP, 1992)

Lower Exp Limit:  2.8% (NTP, 1992)

Upper Exp Limit:  25% (NTP, 1992)

Auto Igtn Temp:  875¦ F (NTP, 1992)

Melting Point:  -105.7¦ F (NTP, 1992)

Vapor Pressure:  40 mm Hg at 48.6¦ F; 760 mm Hg at 176.4¦ F (NTP, 1992)

Vapor Density:  3.0 (NTP, 1992)

Specific Gravity:  0.9535 at 68¦ F (NTP, 1992)

Boiling Point:  176.9¦ F (NTP, 1992)

Molecular Weight:  86.09 (NTP, 1992)

IDLH:  250 ppm (NIOSH, 1997)

TLV TWA:  2 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  10-50 mg/mL at 72¦ F (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  If symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION:  DO NOT INDUCE VOMITING.  Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems.  If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.  IMMEDIATELY transport the victim to a hospital.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the Headache lower than the body.  DO NOT INDUCE VOMITING.  IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Reactivity:
AIR AND WATER REACTIONS:  When exposed to air it forms peroxides, which may initiate spontaneous, autocatalytic, exothermic polymerization. Generally this reaction (peroxide formation) proceeds slowly.CHEMICAL PROFILE:  Colorless, moderately toxic liquid. Dangerous fire and explosion hazard when exposed to heat, flame or sparks. Vigorous reaction with strong oxidizing materials. When exposed to air it forms peroxides, which may initiate spontaneous, autocatalytic, exothermic polymerization. If the inhibitor is consumed during the storage, explosion may occur [MCA Case History No. 2033]. (REACTIVITY, 1999)

Symptoms:
eye, upper respiratory, and skin irritation

Health Effects:
irritation-eye, nose, throat, skin---marked; acute lung damage; cumulative lung, liver and kidney damage

Synonyms:
Methoxycarbonylethylene, Methyl acrylate, inhibited, Methyl ester of acrylic acid, Methyl propenoate


General Desc:
Benzotrichloride is a clear colorless to yellowish colored liquid with a penetrating odor.  It is heavier than water and its vapors are heavier than air.  It may be toxic by inhalation or ingestion.  It will cause burns to skin, eyes, and mucous membranes.  It is insoluble in water.  It is used to make dyes and other chemicals. (¬ AAR, 1999)

Properties:
Flash Point:  260¦ F (cc) (EPA, 1998)

Melting Point:  23¦ F (EPA, 1998)

Vapor Pressure:  1 to 10 mm at 114.44 to 189.68¦ F (EPA, 1998)

Vapor Density:  6.77 (EPA, 1998)

Specific Gravity:  1.38 at 59¦ F (NTP, 1992)

Boiling Point:  429.4¦ F at 760 mm (EPA, 1998)

Molecular Weight:  195.48 (EPA, 1998)

Water Solubility:  Decomposes (NTP, 1992)

First Aid:
Warning: Benzotrichloride is a strong irritant.  Direct contact may result in severe dermal or corneal burns. Signs and Symptoms of Benzotrichloride Exposure: Signs and symptoms of acute exposure to benzotrichloride may include strong irritation or burning of the eyes, skin, and respiratory tract.  It may cause esophageal or gastrointestinal tract irritation if ingested. Emergency Life-Support Procedures: Acute exposure to benzotrichloride may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to benzotrichloride. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer 100% humidified oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures. 4.  Rush to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self-exposure to benzotrichloride. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer 100% humidified oxygen or other respiratory support. 3.  Remove and isolate contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas thoroughly with soap and water. 6.  Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures. 7.  Rush to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer 100% humidified oxygen or other respiratory support to all victims. 2.  DO NOT induce vomiting or attempt to neutralize! 3.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 4.  Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz.  or 1 cup).  Water or milk should be given only if victims are conscious and alert. 5.  Rush to a health care facility.  (EPA, 1998)

Firefighting:
Wear self-contained breathing apparatus and full protective clothing. Normal fire fighting procedures may be used.Small fires: dry chemical, carbon dioxide, water spray, or foam. Large fires: water spray, fog, or foam. Cool containers that are exposed to flames with water from the side until well after the fire is out. (EPA, 1998)

Reactivity:
STABILITY:  This compound is sensitive to moisture.REACTIVITY:  This compound hydrolyzes in the presence of moisture.  It reacts with water, lime, ammonia, strong alkalies, organic amines, chlorates and acids. (NTP, 1992)


TLV NOTES:
TWA = 0.1 f/cc, RESPIRABLE FIBERS:LENGTH > 5u; ASPECT RATIO >/= 3:1


General Desc:
1,1,1-Trichloroethane is a colorless liquid with a sweet, pleasant odor.  It may be irritating to skin, eyes and mucous membranes; and in high concentrations the vapors may have a narcotic effect.  It is nonflammable, but if exposed to high temperatures it may decompose and emit toxic chloride fumes.  It is used as a solvent. (¬ AAR, 1999)

Properties:
Flash Point:  >200¦ F (NTP, 1992)

Lower Exp Limit:  7.5% (NTP, 1992)

Upper Exp Limit:  12.5% (NTP, 1992)

Auto Igtn Temp:  932¦ F (USCG, 1999)

Melting Point:  -26.5¦ F (NTP, 1992)

Vapor Pressure:  100 mm Hg at 68¦ F; 125 mm Hg at 77¦ F (NTP, 1992)

Vapor Density:  4.6 (NTP, 1992)

Specific Gravity:  1.3376 at 68¦ F (NTP, 1992)

Boiling Point:  165.4¦ F (NTP, 1992)

Molecular Weight:  133.40 (NTP, 1992)

IDLH:  700 ppm (NIOSH, 1997)

TLV TWA:  350 ppm (¬ACGIH, 1999)

TLV STEL:  450 ppm (¬ACGIH, 1999)

ERPG-1:  350 ppm (AIHA, 1999)

ERPG-2:  700 ppm (AIHA, 1999)

ERPG-3:  3,500 ppm (AIHA, 1999)

Water Solubility:  <1 mg/mL at 68¦ F (NTP, 1992)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.    Water spill:  Use natural barriers or oil spill control booms to limit spill travel.  Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom.  Remove trapped material with suction hoses. ( AAR, 1999)

Reactivity:
STABILITY:  This chemical is hygroscopic.  It is oxidized by atmospheric oxygen at high temperatures.  It is reactive to sunlight at high altitudes.  Solutions of this chemical in anhydrous DMSO or ethanol should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical decomposes in the presence of chemically active metals.  This includes aluminum, magnesium and their alloys.   It will react violently with dinitrogen tetraoxide, oxygen, liquid oxygen, sodium and sodium-potassium alloys.  It will also react violently with acetone, zinc and nitrates.  It can react with sodium hydroxide.  It is incompatible with strong oxidizers and strong bases.  Mixtures with potassium or its alloys are shock-sensitive and may explode on light impact.  This chemical can react with an aqueous suspension of calcium hydroxide, and with chlorine in sunlight.  It will attack some forms of plastics, rubber and coatings.  Upon contact with hot metal or on exposure to ultraviolet radiation, it will decompose to form irritant gases.  A cobalt/molybdenum-alumina catalyst will generate a substantial exotherm on contact with its vapor at ambient temperatures.  Hazardous reactions also occur with (aluminum oxide + heavy metals). (NTP, 1992)

Symptoms:
headaches; lassitude; central nervous system depression; poor equilibrium; eye irritation; dermatitis; cardiac arrhythmias

Target Organ:
eyes, skin, central nervous system, cardiovascular system, liver

Exposure Symptoms:
Irrit eyes, skin; head, lass, CNS depres, poor equi; derm; card arrhy; liver damage

86 REL Notes:
15 minute ceiling; TWA action level of 200ppm (1091 mg/m3)


General Desc:
Sodium metabisulfite is a white crystalline or powder solid with a slight sulfur odor.  It is toxic by inhalation of the powder and also a strong irritant to skin and tissue.  It is noncombustible, but when heated to high temperature it may decompose to emit toxic oxide fumes of sulfur and sodium.  Sodium oxide is a corrosive acid when mixed with water.  It is used as a food preservative and as a laboratory reagent. (¬ AAR, 1999)

Properties:
Melting Point:  >302¦ F (NIOSH, 1997)

Specific Gravity:  1.4 (NIOSH, 1997)

Boiling Point:  Decomposes (NIOSH, 1997)

Molecular Weight:  190.1 (NIOSH, 1997)

TLV TWA:  5 mg/m3 (¬ACGIH, 1999)

Water Solubility:  54% (NIOSH, 1997)

First Aid:
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical. Breathing: If a person breaths large amounts of this chemical, move the exposed person to fresh air at once. Other measures are usually unnecessary. Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 1997)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Do not use water on material itself.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.    Water spill:  Use natural barriers or oil spill control booms to limit spill travel.  Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom.  Remove trapped material with suction hoses. ( AAR, 1999)

Firefighting:
Use dry chemical, dry sand, or carbon dioxide.  Do not use water on material itself.  If large quantities of combustibles are involved, use water in flooding quantities as spray and fog.  Cool all affected containers with flooding quantities of water.  Apply water from as far a distance as possible. ( AAR, 1999)

Reactivity:
This compound is incompatible with the following:Heat (decomposes) [Note: Slowly oxidized to the sulfate on exposure to air & moisture.] (NIOSH, 1997)

Synonyms:
Disodium pyrosulfite, Sodium metabisulphite, Sodium pyrosulfite

Physical Description:
White to yellowish crystals or powder with an odor of sulfur dioxide.


General Desc:
Nitric acid is a colorless to yellow or red liquid sometimes fuming reddish brown vapors with a suffocating odor.  It is soluble in water with release of heat.  It is corrosive to metals or tissue.  It will accelerate the burning of combustible materials and it may even cause ignition upon contact with combustible material.  It is fully soluble in water and may react violently upon contact with water with the evolution of heat, fumes and spattering.  Prolonged exposure to low concentrations or short term exposure to high concentrations may result in adverse health effects.  It weighs 10.4 lbs./gal. (¬ AAR, 1999)

Properties:
Auto Igtn Temp:  Not flammable (USCG, 1999)

Melting Point:  -44¦ F (EPA, 1998)

Vapor Pressure:  47.8 mm at 68¦ F (EPA, 1998)

Specific Gravity:  1.25 (¬ AAR, 1999)

Boiling Point:  / For constant boiling acid at 68% nitric acid. (EPA, 1998)

Molecular Weight:  63.01 (EPA, 1998)

IDLH:  25 ppm (NIOSH, 1997)

TLV TWA:  2 ppm  For fuming nitric acid. (¬ACGIH, 1999)

TLV STEL:  4 ppm  For fuming nitric acid. (¬ACGIH, 1999)

Water Solubility:  Miscible (NIOSH, 1997)

First Aid:
Warning: Nitric acid is extremely corrosive.  Caution is advised. Signs and Symptoms of Acute Nitric Acid Exposure: Signs and symptoms of acute ingestion of nitric acid may be severe and include increased salivation, intense thirst, difficulty swallowing, chills, pain, and shock.  Oral, esophageal, and stomach burns are common.  Vomitus generally has a coffee-ground appearance.  The potential for circulatory collapse is high following ingestion of nitric acid.  Acute inhalation exposure may result in sneezing, hoarseness, choking, laryngitis, dyspnea (shortness of breath), respiratory tract irritation, and chest pain.  Bleeding of nose and gums, ulceration of the nasal and oral mucosa, pulmonary edema, chronic bronchitis, and pneumonia may also occur.  If the eyes have come in contact with nitric acid, irritation, pain, swelling, corneal erosion, and blindness may occur.  Dermal exposure may result in severe burns, pain, and dermatitis (red, inflamed skin). Emergency Life-Support Procedures: Acute exposure to nitric acid may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to nitric acid. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  RUSH to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to nitric acid. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas THOROUGHLY with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  RUSH to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  Rinse mouth with large amounts of water.  Instruct victims not to swallow the water. 3.  DO NOT induce vomiting or attempt to neutralize!  4.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 5.  Activated charcoal is of no value. 6.  Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup).  Water or milk should be given only if victims are conscious and alert. 7.  RUSH to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Use water spray to knock-down vapors.  Neutralize spilled material with crushed limestone, soda ash, or lime.    Vapor knockdown water is corrosive or toxic and should be diked for containment.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash or cement powder.  Neutralize with agricultural lime (CaO), crushed limestone (CaCO3) or sodium bicarbonate (NaHCO3).    Water spill:  Neutralize with agricultural lime (CaO), crushed limestone (CaCO3), or sodium bicarbonate (NaHCO3). ( AAR, 1999)

Firefighting:
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Ventilate closed spaces before entering them. Wear positive pressure breathing apparatus and special protective clothing.Use water spray. Small fires: water, dry chemical, or soda ash. Large fires: flood fire area with water. Move container from fire area if you can do so without risk. Spray cooling water on containers that are exposed to flames until well after fire is out. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (EPA, 1998)

Reactivity:
AIR AND WATER REACTIONS:  Fumes in airReacts violently with water with the production of heat, fumes, and spattering.CHEMICAL PROFILE:  Propellant; ignites upon contact with alcohols, amines, ammonia, beryllium alkyls, boranes, dicyanogen, hydrazines, hydrocarbons, hydrogen, nitroalkanes, powdered metals, silanes, or thiols (Bretherick 1979 p.174).  The reaction of finely divided antimony and nitric acid can be violent Pascal 10:504. 1931-34). Bromine pentafluoride reacts violently with strong nitric acid and strong sulfuric acid (Mellor 2, Supp. 1:172. 1956). A mixture of finely divided magnesium and nitric acid is explosive (Pieters 1957 p.28). Nitric acid oxidizes magnesium phosphide with incandescence (Mellor 8:842. 1946-47). Experiments show that mixtures of over 50% nitric acid by weight in acetic anhydride may act as detonating explosives (BCISC 42:2. 1971). An etching agent of equal portions of acetone, nitric acid, and 75% acetic acid exploded 4 hours after it was prepared and placed in a closed bottle. This is similar to a formulation for the preparation of tetranitromethane a sensitive explosive (Chem. Eng. News 38: 56. 1960). Phosphine is violently decomposed by concentrated nitric acid, and flame is produced. Warm fuming nitric acid, dropped in a container of phosphine gas produces an explosion (Edin. Roy. Soc. 13:88. 1835). An explosion occurs when nitric acid is brought into contact with phosphorus trichloride (Comp. Rend. 28:86). The reaction of sodium azide and strong nitric acid is energetic (Mellor8, Supp 2:315. 1967).  Reacts violently with water with the production of heat, fumes, and spattering. (REACTIVITY, 1999)

Symptoms:
eye, mucous membrane, skin irritation; delayed pulmonary edema, pneumonitis, bronchitis; dental erosion

Health Effects:
acute lung damage; irritation-eye, nose, throat, skin---marked

Synonyms:
Aqua fortis, Engravers acid, Hydrogen nitrate, Red fuming nitric acid (RFNA), White fuming nitric acid (WFNA)

Physical Description:
Colorless, yellow, or red, fuming liquid with an acrid, suffocating odor.

Notes 2:
[Note: Often used in an aqueous solution. Fuming nitric acid is concentrated nitric acid that contains dissolved nitrogen dioxide.]

Exposure Symptoms:
Irrit eyes, skin, muc memb; delayed pulm edema, pneuitis, bron; dental erosion


General Desc:
Trinitrotoluene, wet is a yellow crystalline slurry or sludge.  The dry material is a high explosive.  Dry it is easily ignited and burns very vigorously.  The wet material can burn though it may require some effort to ignite.  It is insoluble in water.  Toxic oxides of nitrogen are produced during combustion of this material. (¬ AAR, 1999)

Properties:
TLV TWA:  0.5 mg/m3  For 2,4,6-Trinitrotoluene.  Skin. (¬ACGIH, 1999)

First Aid:
Move victim to fresh air.  Call emergency medical care.  Apply artificial respiration if victim is not breathing.  Administer oxygen if breathing is difficult.  Remove and isolate contaminated clothing and shoes.  In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.  Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. (DOT, 1996)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Keep spilled material wet.  Do not attempt to sweep up dry material. ( AAR, 1999)

Firefighting:
Dangerously explosive.  Flood with water.  Cool all affected containers with flooding quantities of water.  Apply water from as far a distance as possible. ( AAR, 1999)

Reactivity:
Strong oxidizers, ammonia, strong alkalis, combustible materials, heat

Symptoms:
liver damage, jaundice; cyanosis; sneezing, coughing, sore throat; peripheral neuritis, muscle pain; kidney damage; cardiac irregularities; cataracts; sensitization dermatitis; leukocytosis, anemia

Health Effects:
methemoglobinemia; aplastic anemia; cumulative eye (cataracts) and liver damage

Target Organ:
eyes, skin, respiratory system, blood, liver, cardiovascular system, central nervous system, kidneys

Synonyms:
1-Methyl-2,4,6-trinitrobenzene; TNT; Trinitrotoluene; sym-Trinitrotoluene; Trinitrotoluol

Physical Description:
Colorless to pale-yellow, odorless solid or crushed flakes.

Exposure Symptoms:
Irrrit skin, muc memb; liver damage, jaun; cyan; sneez; cough, sore throat; peri neur, musc pain; kidney damage; cataract; sens derm; leucyt; anemia; card irreg


General Desc:
PHYSICAL DESCRIPTION:  White to grayish-white, very fine crystalline powder (unctuous).

PHYSICAL DATA:  Odorless.  Readily adheres to the skin. (NTP, 1992)

Properties:
Melting Point:  1700-1800¦ F (NTP, 1992)

Vapor Pressure:  Essentially 0 mm Hg at 68¦ F (NTP, 1992)

Specific Gravity:  2.7-2.8 (NTP, 1992)

Boiling Point:  None reported (NIOSH, 1997)

Molecular Weight:  379.26 (NTP, 1992)

IDLH:  1000 mg/m3 (NIOSH, 1997)

Water Solubility:  <1 mg/mL at 70¦ F (NTP, 1992)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions. (NTP, 1992)

TLV NOTES:
USE ASBESTOS TLV-TWA; (SHOULD NOT EXCEED 2 mg/m3 RESPIRABLE PARTICULATE), TWA = 0.1 f/cc, RESPIRABLE FIBERS

PEL NOTES:
USE ASBESTOS PEL-TWA, TWA = 0.1 f/cc, STEL (30 MINUES) = 1 f/cc, SEE 29 CFR 1910.1001

REL NOTES:
TWA = 0.1 f/cc AS DETERMINED BY A  400-LITER AIR SAMPLE COLLECTED OVER 100 MINUTES (NIOSH #7400); CARCINOGEN (Ca)

Carcinogen:
IARC-1, NIOSH-Ca, NTP-1, OSHA-Ca, TLV-A1

Synonyms:
Hydrous magnesium silicate, Steatite talc

87-88 TLV Notes:
see limits for individual forms of asbestos


General Desc:
Bromine is a reddish brown fuming liquid with a pungent odor.  It is very toxic by inhalation.  It is heavier than water and slightly soluble in water.  It accelerates the burning of combustible material.  It is very corrosive to tissue and corrosive to metals. (¬ AAR, 1999)

Properties:
Auto Igtn Temp:  Not flammable (USCG, 1999)

Melting Point:  19¦ F (EPA, 1998)

Vapor Pressure:  172 mm at 69.08¦ F (EPA, 1998)

Vapor Density:  5.51 at 59¦ F (EPA, 1998)

Specific Gravity:  3.12 (NIOSH, 1997)

Boiling Point:  139.2¦ F at 760 mm (EPA, 1998)

Molecular Weight:  159.81 (EPA, 1998)

IDLH:  3 ppm (NIOSH, 1997)

TLV TWA:  0.1 ppm (¬ACGIH, 1999)

TLV STEL:  0.2 ppm (¬ACGIH, 1999)

ERPG-1:  0.2 ppm (AIHA, 1999)

ERPG-2:  1 ppm (AIHA, 1999)

ERPG-3:  5 ppm (AIHA, 1999)

Water Solubility:  4% (NIOSH, 1997)

First Aid:
Warning: Effects may be delayed for several hours.  Caution is advised. Signs and Symptoms of Acute Bromine Exposure: Signs and symptoms of acute exposure to bromine may include hypotension (low blood pressure), tachycardia (rapid heart rate), cyanosis (blue tint to the skin and mucous membranes), and circulatory collapse.  Neurological effects may include headache, dizziness, delirium, stupor, and shock.  Gastrointestinal effects may include vomiting (vomitus may be blue), diarrhea, abdominal pain, and bloody stools.  Nephritis with oliguria (scanty urination) and anuria (absence of urine formation) has been reported.  Bromine is irritating to the skin, eyes, and mucous membranes; brown discoloration of the mucous membranes, lips, and tongue may be observed.  Lacrimation (tearing), photophobia (heightened sensitivity to light), nosebleeds, coughing, asphyxiation, and pulmonary edema may also occur.  A burning pain in the mouth and esophagus generally follows ingestion. Emergency Life-Support Procedures: Acute exposure to bromine may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying and supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to bromine. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to bromine. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed IMMEDIATELY with lukewarm water for at least 15 minutes. 5.  IMMEDIATELY wash exposed skin areas THOROUGHLY with soap and water. 6.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  DO NOT induce vomiting or attempt to neutralize! 3.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 4.  Activated charcoal is of no value. 5.  Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup).  Water or milk should be given only if victims are conscious and alert. 6.  Transport to a health care facility. (EPA, 1998)

Firefighting:
Wear positive pressure breathing apparatus and special protective clothing. Move containers from fire area. Cool containers that are exposed to flames with water.Nonflammable, but a strong oxidizer. Extinguish with dry chemical, carbon dioxide, water spray, fog or foam. (EPA, 1998)

Reactivity:
AIR AND WATER REACTIONS:  Fumes in air.CHEMICAL PROFILE:  A very powerful oxidizer, it may ignite a combustible material upon contact. It can react vigorously with reducing reagents. When heated or upon reaction with water or steam it emits highly toxic and corrosive fumes . It reacts explosively with hydrogen, diethylzinc, dimethylformamide, ammonia, trimethylamine, nitromethane, metal azides (silver or sodium azide). Mixtures with lithium or sodium are shock-sensitive. Ignition on contact with germanium, trialkyl boranes, copper and alkali metal acetylides [Sax, 9th ed., 1996, p. 506]. Upon contact with metals (Mg, Sr, B, Al, Hg, Ti, Sn, Sb) in powder or sheet form it can react violently to form bromides. Sodium, potassium, antimony and germanium ignite in bromine vapor and react explosively. Violent reaction with methanol, ethanol, aldehydes, ketones, carboxylic acids, diethyl ether, carbonyl compounds, tetrahydrofuran, acrylonitrile, ozone, phosphorus, natural rubber. Methyl acetylides or carbides ignite at room temperature on contact with bromine vapor. Reaction with red phosphorus, metal azides, nitromethane, silane and its homologues is explosively violent [Bretheric, 5th ed., 1995, p. 109]. On contact with natural rubber it reacts violently [Pascal, 1960, vol. 16.1, 371]. (REACTIVITY, 1999)

Symptoms:
dizziness, headaches; lacrimation; epistaxis; coughing; feeling of oppression; pulmonary edema; pneumonia; abdominal pain; diarrhea; measle-like eruptions; severe burns eyes, skin

Health Effects:
irritation-eye, nose, throat, bronchi, skin-marked; acute lung damage/edema

Target Organ:
respiratory system, eyes, central nervous system, skin

Physical Description:
Dark reddish-brown, fuming liquid with suffocating, irritating fumes.

Exposure Symptoms:
Dizz, head; lac, epis; cough, feeling of oppression, pulm edema, pneu; abdom pain, diarr; measle-like eruptions; eye, skin burns


General Desc:
Physical State Shipped: Liquid

Odor: Weak fruity odor

Color: Colorless

Characteristics in Water: Floats and mixes slowly with water. (USCG, 1999)

Properties:
Flash Point:  160¦ F (cc)
190¦ F (oc) (USCG, 1999)

Lower Exp Limit:  0.9 % (USCG, 1999)

Upper Exp Limit:  8.5 % (USCG, 1999)

Auto Igtn Temp:  645¦ F (USCG, 1999)

Melting Point:  -82.3¦ F (USCG, 1999)

Vapor Pressure:  0.3 mm (NIOSH, 1997)

Specific Gravity:  0.94 (NIOSH, 1997)

Boiling Point:  378.0¦ F at 760 mm (USCG, 1999)

Molecular Weight:  160.21 (USCG, 1999)

Water Solubility:  1.5% (NIOSH, 1997)

First Aid:
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical.  Skin: If this chemical contacts the skin, promptly wash the contaminated skin with soap and water. If this chemical penetrates the clothing promptly remove the clothing and wash the skin with soap and water. Get medical attention promptly.  Breathing: If a person breathes large amounts of this chemical, move the exposed  person to fresh air at once. If breathing has stopped, perform mouth-to-mouth  resuscitation. Keep the affected person warm and at rest. Get medical  attention as soon as possible.  Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 1997)

Firefighting:
Fire Extinguishing Agents Not to Be Used: Water may be ineffective.Fire Extinguishing Agents: Dry chemical, alcohol foam, carbon dioxide (USCG, 1999)

Symptoms:
irritation eyes, skin, nose, throat; hemolysis, hemoglobinuria; central nervous system depressant/depression, headache; vomiting

Target Organ:
eyes, skin, respiratory system, central nervous system, hematopoietic system, blood, kidneys, liver, lymphoid system

Synonyms:
2-Butoxyethyl acetate, 2-Butoxyethanol acetate, Butyl Cellosolve® acetate, Butyl glycol acetate, EGBEA, Ektasolve® EB  acetate

Physical Description:
Colorless liquid with a pleasant, sweet, fruity odor.

Exposure Symptoms:
Irrit eyes, skin, nose, throat; hemolysis, hemog; CNS depres, head; vomit


General Desc:
Methoxychlor is a white crystalline solid dissolved in a liquid carrier.  It can cause illness by inhalation, skin absorption and/or ingestion.  The primary hazard is the threat to the environment.  Immediate steps should be taken to limit its spread to the environment.  Since it is a liquid it can easily penetrate the soil and contaminate groundwater and nearby streams.  It is used as a pesticide. (¬ AAR, 1999)

Properties:
Melting Point:  187-190¦ F (NTP, 1992)

Vapor Pressure:  Very low (NTP, 1992)

Vapor Density:  12 (NTP, 1992)

Specific Gravity:  1.41 at 77¦ F (NTP, 1992)

Boiling Point:  Decomposes (NTP, 1992)

Molecular Weight:  345.66 (NTP, 1992)

IDLH:  5000 mg/m3; Not applicable for Methoxychlor, a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  10 mg/m3 (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 73¦ F (NTP, 1992)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash or cement powder.    Water spill:  Use natural barriers or oil spill control booms to limit spill travel.  If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount.  Remove trapped material with suction hoses.  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Reactivity:
STABILITY:  This chemical turns pink or tan on exposure to light.  It is described as resistant to ultraviolet light, but other studies have shown it to break down rapidly under UV in hexane solution.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical is incompatible with alkaline materials, especially in the presence of catalytically-active metals.  It is slightly corrosive to iron and aluminum.  It is decomposed by refluxing with sodium in isopropyl alcohol.  It is also incompatible with strong oxidizers.  It will attack some forms of plastics, rubber and coatings. (NTP, 1992)

REL NOTES:
CARCINOGEN (Ca);REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION (LOQ 0.07 mg/m3)

Symptoms:
none known in humans;  in animals: fasiculation, trembling, convulsions; kidney, liver damage; (carcinogenic)

Synonyms:
p,p'-Dimethoxydiphenylftrichloroethane; DMDT; Methoxy-DDT; 2,2-bis(p-Methoxyphenyl)-1,1,1-trichloroethane; 1,1,1-Trichloro-2,2-bis-(p-methoxyphenyl)ethane

Physical Description:
Colorless to light-yellow crystals with a slight, fruity odor.

Exposure Symptoms:
In animals: fasc, trembling, convuls; kidney, liver damage; [carc]


General Desc:
Tetraethyl pyrophosphate and compressed gas mixture is a liquid charged with a gas.  It is a colorless liquid.  Its vapor is heavier than air.  It is soluble in water.  It is lethal by skin absorption and inhalation.  Prolonged exposure of the containers to fire or heat may result in the violent rupturing and rocketing of the containers. (¬ AAR, 1999)

First Aid:
Move victim to fresh air.  Call emergency medical care.  Apply artificial respiration if victim is not breathing.  Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.  Administer oxygen if breathing is difficult.  Remove and isolate contaminated clothing and shoes.  In case of contact with liquefied gas, thaw frosted parts with lukewarm water.  In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.  Keep victim warm and quiet.  Keep victim under observation.  Effects of contact or inhalation may be delayed.  Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. (DOT, 1996)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Apply "universal" gelling agent to immobilize spill.    Water spill:  Neutralize with agricultural lime (CaO), crushed limestone (CaCO3), or sodium bicarbonate (NaHCO3).  If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount.  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Firefighting:
Extinguish fire using agent suitable for type of surrounding fire.  (Material itself does not burn or burns with difficulty.)  Use water in flooding quantities as fog.  Cool all affected containers with flooding quantities of water.  Apply water from as far a distance as possible.  Use "alcohol" foam, dry chemical or carbon dioxide. ( AAR, 1999)

Reactivity:
AIR AND WATER REACTIONS:  Reacts slowly with water to form phosphoric acid (REACTIVITY, 1999)

Symptoms:
eye pain, blurred vision, lacrimation, rhinorrhea; headaches; tightness chest; cyanosis; anorexia; nausea, vomiting, diarrhea; localized sweating; weakness; twitching; paralysis; cheyne-stokes respiration; convulsions; low blood pressure, cardiac irregularities

Target Organ:
eyes, respiratory system, central nervous system, cardiovascular system, gastrointestinal tract, blood cholinesterase

Physical Description:
Colorless to amber liquid with a faint, fruity odor.

Notes 2:
[insecticide] [Note: A solid below 32ºF.]

Exposure Symptoms:
Eye pain, blurred vision, lac; rhin; head, chest tight, cyan; anor, nau, vomit, diarr; weak, twitch, para, Cheyne-Stokes respiration, convuls; low BP, card irreg; sweat


General Desc:
Methyl propyl ketone is a clear colorless liquid with an odor of fingernail polish.  It has a flash point of 45 deg. F.  It is lighter than water and slightly soluble in water.  Its vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  45¦ F (NTP, 1992)

Lower Exp Limit:  1.56%  at 93¦ F (NTP, 1992)

Upper Exp Limit:  8.7%  at 144¦ F (NTP, 1992)

Auto Igtn Temp:  941¦ F (USCG, 1999)

Melting Point:  -108¦ F (NTP, 1992)

Vapor Pressure:  12 mm Hg at 68¦ F; 16 mm Hg at 77¦ F; 21 mm Hg at 86¦ F (NTP, 1992)

Vapor Density:  3.0 (NTP, 1992)

Specific Gravity:  0.809 at 68¦ F (NTP, 1992)

Boiling Point:  212-214¦ F (NTP, 1992)

Molecular Weight:  86.13 (NTP, 1992)

IDLH:  1500 ppm (NIOSH, 1997)

TLV TWA:  200 ppm (¬ACGIH, 1999)

TLV STEL:  250 ppm (¬ACGIH, 1999)

Water Solubility:  10-50 mg/mL at 72¦ F (NTP, 1992)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This compound is incompatible with oxidizing agents, strong bases and reducing agents.  It reacts violently with bromine trifluoride. (NTP, 1992)

Symptoms:
eye, mucous membrane irritation; headaches; dermatitis; narcosis, coma

Synonyms:
Ethyl acetone, Methyl propyl ketone, MPK

Physical Description:
Colorless to water-white liquid with a characteristic acetone-like odor.


TLV NOTES:
DOES NOT INCLUDE STEARATES OF TOXIC METALS


General Desc:
Chloronitrobenzenes can be either a clear yellow liquid or solid.  Its melting point is around 89 deg. F.  It will burn though it may require some effort to ignite.  It is heavier than water and insoluble in water.  It is toxic by inhalation and skin absorption.  Toxic oxides of nitrogen are produced during combustion of this material. (¬ AAR, 1999)

Properties:
Melting Point:  89¦ F approx. (AAR, 1999)

TLV TWA:  0.1 ppm  Skin (para isomer) (¬ACGIH, 1999)

First Aid:
Move victim to fresh air.  Call emergency medical care.  Apply artificial respiration if victim is not breathing.  Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.  Administer oxygen if breathing is difficult.  Remove and isolate contaminated clothing and shoes.  In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.  For minor skin contact, avoid spreading material on unaffected skin.  Keep victim warm and quiet.  Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.  Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. (DOT, 1996)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.    Water spill:  Use natural barriers or oil spill control booms to limit spill travel.  Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom.  Remove trapped material with suction hoses. ( AAR, 1999)

REL NOTES:
CARCINOGEN (Ca); REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION (LOQ 0.25 mg/m3)

Symptoms:
anoxia; unpleasant taste; mild anemia; (carcinogenic); in animals: hematuria, hemoglobinuria

Target Organ:
blood, liver, kidneys, cardiovascular system, spleen, bone marrow, reproductive system

Synonyms:
p-Chloronitrobenzene, 4-Chloronitrobenzene, 1-Chloro-4-nitrobenzene, 4-Nitrochlorobenzene, PCNB, PNCB

Physical Description:
Yellow, crystalline solid with a sweet odor.

Exposure Symptoms:
Anoxia; unpleasant taste; anemia; methemo; in animals: hema, hemog; spleen, kidney, bone marrow changes; repro effects; [carc]


General Desc:
PHYSICAL DESCRIPTION:  Yellow crystalline leaflets; Orange powder. (NTP, 1992)

Properties:
Melting Point:  232¦ F (decomposes) (NTP, 1992)

Vapor Pressure:  0.0000003 mm (est.) (NIOSH, 1997)

Vapor Density:  7.78 (NTP, 1992)

Boiling Point:  Sublimes (NIOSH, 1997)

Molecular Weight:  225.30 (NTP, 1992)

Water Solubility:  <1 mg/mL at 72¦ F (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container.  Use absorbent paper dampened with acetone to pick up any remaining material.  Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal.  Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should protect this material from exposure to light, and store it in a refrigerator. (NTP, 1992)

Reactivity:
STABILITY:  This chemical is sensitive to heat and light.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical is incompatible with strong oxidizing agents and strong acids. (NTP, 1992)

Symptoms:
enlarged liver, hepatic and renal dysfunction; contact dermatitis; coughing, wheezing, difficulty breathing, bloody sputum, bronchial secretions; frequent urination, hematuria, dysuria; (carcinogenic)

Target Organ:
skin, respiratory system, liver, kidneys, bladder

Synonyms:
Butter yellow; DAB; p-Dimethylaminoazobenzene; N,N-Dimethyl-4-aminoazobenzene; Methyl yellow

Exposure Symptoms:
Enlarged liver; liver, kidney dysfunc; contact derm; cough, wheez, dysp; bloody sputum; bronchial secretions; frequent urination, hema, dysuria; [carc]


REL NOTES:
CARCINOGEN (Ca); TWA BASE ON 10 HR EXPOSURE

Symptoms:
anoxia, cyanosis; anemia, jaundice; reproductive effects; [potential occupational carc]

Target Organ:
blood, liver, cardiovascular system, reproductive system; in animal: liver, skin, kidney tumors

Synonyms:
Dinitrotoluol, DNT, Methyldinitrobenzene [Note: Various isomers of DNT exist]


General Desc:
Ethylene glycol monobutyl ether is a colorless liquid with a mild, pleasant odor.  It is lighter than water and slightly soluble in water.  It has a flash point of 160 deg. F.  It is irritating to skin and eyes and may be toxic by ingestion.  It is used as a solvent and to make paints and varnish. (¬ AAR, 1999)

Properties:
Flash Point:  141¦ F (NTP, 1992)

Lower Exp Limit:  1.1% (NTP, 1992)

Upper Exp Limit:  10.6% (NTP, 1992)

Auto Igtn Temp:  472¦ F (USCG, 1999)

Melting Point:  -94¦ F (NTP, 1992)

Vapor Pressure:  0.76 mm Hg at 68¦ F; 0.88 mm Hg at 77¦ F; 300 mm Hg at 284¦ F (NTP, 1992)

Vapor Density:  4.07 (NTP, 1992)

Specific Gravity:  0.9012 at 68¦ F (NTP, 1992)

Boiling Point:  340¦ F at 743 mm Hg (NTP, 1992)

Molecular Weight:  118.18 (NTP, 1992)

IDLH:  700 ppm (NIOSH, 1997)

TLV TWA:  25 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  greater than or equal to 100 mg/mL at 72¦ F (NTP, 1992)

Firefighting:
Use water in flooding quantities as fog.  Solid streams of water may be ineffective.  Cool all affected containers with flooding quantities of water.  Apply water from as far a distance as possible.  Use "alcohol" foam, dry chemical or carbon dioxide.  Keep run-off water out of sewers and water sources. ( AAR, 1999)

Reactivity:
STABILITY:  This chemical is sensitive to air and light.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This compound may react with bases, aluminum and oxidizing materials.  It is liable to form peroxides on exposure to air and light.  It attacks some forms of plastics, rubber and coatings. (NTP, 1992)

Synonyms:
2-Butoxyethanol, Butyl Cellosolve®, Butyl oxitol, Dowanol® EB, EGBE, Ektasolve, EB®, Jeffersol EB


General Desc:
Nonane is a clear colorless liquid with a sharp odor.  It has a flash point of 86 deg. F.  It is insoluble in water and weighs less than water.  Contact with the eyes may cause irritation and possible injury to the cornea.  Contact with the skin may cause irritation.  Inhalation of vapors may cause irritation with prolonged exposure leading to breathing difficulty.  Ingestion will cause abdominal discomfort, nausea and diarrhea. (¬ AAR, 1999)

Properties:
Flash Point:  88¦ F (NTP, 1992)

Lower Exp Limit:  0.8% (NTP, 1992)

Upper Exp Limit:  2.9% (NTP, 1992)

Auto Igtn Temp:  401¦ F (USCG, 1999)

Melting Point:  -60¦ F (NTP, 1992)

Vapor Pressure:  3.22 mm Hg at 68¦ F; 10 mm Hg at 100.4¦ F (NTP, 1992)

Vapor Density:  4.41 (NTP, 1992)

Specific Gravity:  0.7176 at 68¦ F (NTP, 1992)

Boiling Point:  303.4¦ F (NTP, 1992)

Molecular Weight:  128.26 (NTP, 1992)

TLV TWA:  200 ppm (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 70¦ F (NTP, 1992)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical is incompatible with oxidizing materials.  It is also incompatible with oxygen. (NTP, 1992)

Symptoms:
irritation eyes, skin, nose, throat; headache, drowsiness, dizziness, confusion, nausea, tremor, incoordination; chemical pneumonia (aspir liquid)

Exposure Symptoms:
Irrit eyes, skin, nose, throat; head, drow, dizz, conf, nau, tremor, inco; chemical pneu (aspir liquid)


General Desc:
Finely divided white particulate dispersed in air. [Note: Exposure may occur when magnesium is burned, thermally cut, or welded upon.] (NIOSH, 1997)

Properties:
Melting Point:  5072¦ F (NIOSH, 1997)

Vapor Pressure:  0 mm (approx) (NIOSH, 1997)

Specific Gravity:  3.58 (NIOSH, 1997)

Boiling Point:  6512¦F (NIOSH, 1997)

Molecular Weight:  40.3 (NIOSH, 1997)

IDLH:  750 mg/m3 (NIOSH, 1997)

TLV TWA:  10 mg/m3 (¬ACGIH, 1999)

Water Solubility:  Sol(86¦F): 0.009% (NIOSH, 1997)

Reactivity:
CHEMICAL PROFILE:  Phosphorus pentachloride and magnesium oxide react with brilliant incandescence Mellor 8:1016. 1946-1947). (REACTIVITY, 1999)

TLV NOTES:
MEASURED AS INHALABLE FRACTION OF THE AEROSOL

Symptoms:
eye, nose irritation; metal fume fever: coughing, chest pain; flu-like fever

Physical Description:
Finely divided white particulate dispersed in air.

Notes 2:
[Note: Exposure may occur when magnesium is burned, thermally cut, or welded upon.]

Exposure Symptoms:
Irrit eyes, nose; metal fume fever: cough, chest pain, flu-like fever


Main Chemical Name:
MOLYBDENUM, METAL AND INSOLUBLE COMPOUNDS, as Mo

TLV NOTES:
MEASURED AS RESPIRABLE FRACTION; TLV = 10 mg/m3 MEASURED AS THE INHALABLE FRACTION


General Desc:
Dichlorodimethyl ether, symmetrical is a colorless, volatile liquid with a chloroform-like odor.  It is toxic by inhalation, skin absorption and ingestion.  It is also a dangerous fire risk because its flash point is less than 0 deg. F.  and its vapors are much heavier than air.  It is insoluble in water and heavier than water.  It is used to make paints and varnish, and as a solvent. (¬ AAR, 1999)

Properties:
Flash Point:  Less than 66.2F (EPA, 1998)

Melting Point:  -42.7¦ F (EPA, 1998)

Vapor Pressure:  30 mm at 71.6¦ F (EPA, 1998)

Vapor Density:  4 (EPA, 1998)

Specific Gravity:  1.32 (NIOSH, 1997)

Boiling Point:  223¦ F at 760 mm (EPA, 1998)

Molecular Weight:  114.97 (EPA, 1998)

TLV TWA:  0.001 ppm  Confirmed human carcinogen. (¬ACGIH, 1999)

Water Solubility:  Reacts (NIOSH, 1997)

First Aid:
Note: Chloromethyl ether is a recognized human carcinogen.  Signs and Symptoms of Chloromethyl Ether Exposure: Acute exposure to chloromethyl ether may produce the following signs and symptoms: severe irritation and burning of the skin, eyes, and mucous membranes.  Sore throat, fever, chills, dypsnea (difficulty breathing), chronic bronchitis, and pulmonary edema with productive cough may be noted.  Emergency Life-Support Procedures: Acute exposure to chloromethyl ether may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.  Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to chloromethyl ether. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer 100% humidified oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  4.  Transport to a health care facility.  Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self-exposure to chloromethyl ether.  2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer 100% humidified oxygen or other respiratory support. 3.  Remove and isolate contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes.  5.  Wash exposed skin areas thoroughly with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility.  Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer 100% humidified oxygen or other respiratory support. 2.  DO NOT induce vomiting or attempt to neutralize! 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water.  5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults.  6.  Transport to a health care facility. (EPA, 1998)

Firefighting:
Move container from fire area if you can do so without risk. Fight fire from maximum distance. Dike fire control water for later disposal; do not scatter the material.Small fires: dry chemical, carbon dioxide, water spray, or foam. Large fires: water spray, fog, or foam. (EPA, 1998)

Reactivity:
This compound is incompatible with the following:Acids, water [Note: Reacts with water to form hydrochloric acid & formaldehyde.] (NIOSH, 1997)

Symptoms:
irritates eyes, skin, mucous membranes of respiratory system; pulmonary congestion, edema; corneal damage, necrosis; reduced pulmonary function; coughing, dyspnea, wheezing; hemoptysis, bronchial secretions [potential occupational carcinogen]

Target Organ:
eyes, skin, respiratory system; lung cancer

Synonyms:
BCME, bis-CME, Chloromethyl ether, Dichlorodimethyl ether, Dichloromethyl ether, Oxybis(chloromethane)

Physical Description:
Colorless liquid with a suffocating odor.

Exposure Symptoms:
Irrit eyes, skin, muc memb, resp sys; pulm congestion, edema; corn damage, nec; decr pulm function, cough, dysp, wheez; blood-stained sputum, bronchial secretions; [carc]


General Desc:
Pale yellow liquid; technical grade is brown and has a garlic-like odor.

This material is used as an insecticide and is used almost exclusively in agriculture. (EPA, 1998)

Properties:
Flash Point:  248 to 320¦ F (unspc) (EPA, 1998)

Lower Exp Limit:  Not highly flammable. (EPA, 1998)

Upper Exp Limit:  Not highly flammable. (EPA, 1998)

Melting Point:  43¦ F (EPA, 1998)

Vapor Pressure:  3.78e-05 mm at 68¦ F (EPA, 1998)

Specific Gravity:  1.265 at 68¦ F (NTP, 1992)

Boiling Point:  707¦ F at 760 mm (EPA, 1998)

Molecular Weight:  291.27 (EPA, 1998)

IDLH:  10 mg/m3 (NIOSH, 1997)

TLV TWA:  0.1 mg/m3  For parathion.  Skin. (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 73¦ F (NTP, 1992)

First Aid:
CAUTION: Parathion is a cholinestorase inhibitor.  It has been reported that as little as one drop of parathion can endanger life if splashed in the eye.  Toxicity is highest by inhalation. Signs and Symptoms of Acute Parathion Exposure: Acute exposure to parathion may produce the following signs and symptoms: pinpoint pupils, blurred vision, headache, dizziness, muscle spasms, and profound weakness.  Vomiting, diarrhea, abdominal pain, seizures, and coma may also occur.  The heart rate may decrease following oral exposure or increase following dermal exposure.  Hypotension (low blood pressure) is not uncommon.  Respiratory symptoms include dyspnea (shortness of breath), respiratory depression, and respiratory paralysis.  Psychosis may occur. Emergency Life-Support Procedures: Acute exposure to parathion may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to parathion. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to parathion. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas three times with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 3.  Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of parathion is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.Ipecac should not be administered to children under 6 months of age. Warning: Ingestion of parathion may result in sudden onset of seizures or loss of consciousness.  Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4. The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  Transport to a health care facility. (EPA, 1998)

Nonfire Spill Response:
In case of leaks or spills, special protective clothing should be worn. Use water spray to disperse vapors and flush spills away.Ventilate area of spill or leak. Spills may be absorbed in vermiculite, dry sand, earth, or a similar material. (EPA, 1998)

Firefighting:
Use water spray to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to disperse vapors and to provide protection for firefighters. Water spray may be used to flush spills away from exposures. Fight advanced or massive fires from a safe distance or from a protected location. Special protective clothing should be worn; normal protective clothing may be penetrated.Use water spray, dry chemical, foam, or carbon dioxide. (EPA, 1998)

Reactivity:
CHEMICAL PROFILE:  Light-yellow liquid, it turn solid at 6 C, a deadly poison by all routes. Organic phosphate insecticide, acts as an inhibitor of cholinesterase.Violent reaction when used as solvent to dissolve endrin. When heated to decomposition it emits very toxic fumes of oxides of sulfur, phosphorus and nitrogen [Lewis, 3rd ed., 1993, p. 984]. (REACTIVITY, 1999)

TLV NOTES:
BEI, MEASURED AS INHALABLE FRACTION AND VAPOR, SKIN

Symptoms:
irritation eyes, skin, respiratory system; miosis; rhinorrhea; headaches; tightness chest, wheezing, laryngeal spasms; salivation; cyanosis; anorexia, nausea, vomiting, abdominal cramps, diarrhea; sweating; muscle fasciculation; weakness; paralysis, giddiness, confusion,  ataxia; convulsions; coma; low blood pressure; cardiac irregularities

Synonyms:
O,O-Diethyl-O(p-nitrophenyl) phosphorothioate; Diethyl parathion; Ethyl parathion; Parathion-ethyl

Physical Description:
Pale-yellow to dark-brown liquid with a garlic-like odor.

Notes 2:
[Note: A solid below 43ºF. Pesticide that may be absorbed on a dry carrier.]


General Desc:
PHYSICAL DESCRIPTION:  Colorless leaflets or plates; gold coarse powder.

PHYSICAL DATA:  Greenish-yellow fluorescence. (NTP, 1992)

Properties:
Melting Point:  315-318¦ F (NTP, 1992)

Boiling Point:  815¦ F (sublimes) (NTP, 1992)

Molecular Weight:  228.28 (NTP, 1992)

Water Solubility:  <1 mg/mL at 68¦ F (NTP, 1992)

Firefighting:
Fires involving this chemical can be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

Reactivity:
STABILITY:  This compound is stable under normal laboratory conditions.  Solutions of this chemical should be stable for 24 hours under normal lab conditions. (NTP, 1992)


General Desc:
Dioxane is a clear colorless liquid with a faint ethereal odor.  It has a flash point of 55 deg. F.  It is slightly heavier than water and is soluble in water.  The vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  54¦ F (NTP, 1992)

Lower Exp Limit:  2% (NTP, 1992)

Upper Exp Limit:  22% (NTP, 1992)

Auto Igtn Temp:  356¦ F (USCG, 1999)

Melting Point:  53.2¦ F (NTP, 1992)

Vapor Pressure:  29 mm Hg at 68¦ F; 37 mm Hg at 77¦ F (NTP, 1992)

Vapor Density:  3.03 (NTP, 1992)

Specific Gravity:  1.0329 at 68¦ F (NTP, 1992)

Boiling Point:  214¦ F (NTP, 1992)

Molecular Weight:  88.11 (NTP, 1992)

IDLH:  500 ppm; Not applicable for Dioxane, a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  25 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  greater than or equal to 100 mg/mL at 68¦ F (NTP, 1992)

Reactivity:
CHEMICAL PROFILE:  A flammable liquid; when exposed to air it undergoes autooxidation with formation of peroxides. In the distillation process peroxides will concentrate causing violent explosion. The addition complex with sulfur trioxide (1:1) sometimes decomposes violently on storing at room temperature [Sisler, H. H. et al., Inorg. Synth., 1947, 2, p. 174]. Evaporation of boron trifluoride in aqueous dioxane with nitric acid led to an explosion upon addition of perchloric acid [MCA Guide, 1972, p. 312]. Explosive reaction with Raney nickel catalyst above 210 C {Mozingo R., Org. Synth., 1955, Coll. Vol. 3, p. 182]. (REACTIVITY, 1999)

Symptoms:
drowsiness; headaches; nausea, vomiting; eyes, nose, and throat irritation; liver damage; kidney failure; skin irritation; (carcinogenic)

Health Effects:
cumulative liver and kidney damage; irritation-eyes, nose, throat---mild

Synonyms:
Diethylene dioxide; Diethylene ether; Dioxan; p-Dioxane; 1,4-Dioxane

Physical Description:
Colorless liquid or solid (below 53ºF) with a mild, ether-like odor.

Exposure Symptoms:
Irrit eyes, skin, nose, throat; drow, head; nau, vomit; liver damage; kidney failure; [carc]


General Desc:
Adipic acid is a white crystalline solid.  It is insoluble in water.  The primary hazard is the threat to the environment.  Immediate steps should be taken to limit its spread to the environment.  It is used to make plastics and foams and for other uses. (¬ AAR, 1999)

Properties:
Flash Point:  Combustible solid, 385¦ F (oc); 376¦F (cc) (USCG, 1999)

Lower Exp Limit:  (dust) 15 mg/l (USCG, 1999)

Upper Exp Limit:  (dust) 10-15 mg/l (USCG, 1999)

Auto Igtn Temp:  788¦ F; 450¦ F (USCG, 1999)

Melting Point:  304¦ F (USCG, 1999)

Specific Gravity, Solid:  1.36 at 68.0¦ F (USCG, 1999)

Molecular Weight:  146.1 (USCG, 1999)

TLV TWA:  5 mg/m3 (¬ACGIH, 1999)

First Aid:
INHALATION: remove victim to fresh air; get medical attention if irritation persists.  EYES:  flush with water for at least 15 min.  SKIN:  flush with water. (USCG, 1999)

Firefighting:
Use water in flooding quantities as fog.  Solid streams of water may spread fire.  Cool all affected containers with flooding quantities of water.  Apply water from as far a distance as possible.  Use foam, dry chemical, or carbon dioxide. ( AAR, 1999)


General Desc:
Carbon dioxide is a colorless, odorless gas at atmospheric temperatures and pressures.  It is relatively non-toxic and non-combustible.  The gas is heavier than air and can asphyxiate by the displacement of air.  Carbon dioxide is soluble in water and forms carbonic acid, a mild acid.  Exposure of the container to prolonged heat or fire can cause it to rupture violently and rocket.  Carbon dioxide is used to freeze food, to control chemical reactions, and as a fire extinguishing agent. (¬ AAR, 1999)

Properties:
Melting Point:  -109.3¦ F (USCG, 1999)

Vapor Pressure:  56.5 atm (NIOSH, 1997)

Specific Gravity, Solid:  1.56 at -110.2¦ F (USCG, 1999)

Boiling Point:  Sublimes (NIOSH, 1997)

Molecular Weight:  44.0 (USCG, 1999)

TLV TWA:  5000 ppm (¬ACGIH, 1999)

TLV STEL:  30000 ppm (¬ACGIH, 1999)

Water Solubility:  Sol(77¦F): 0.2% (NIOSH, 1997)

Nonfire Spill Response:
Attempt to stop leak if without undue personnel hazard.  Do not use water on material itself. ( AAR, 1999)

Firefighting:
Extinguish fire using agent suitable for type of surrounding fire.  (Material itself does not burn or burns with difficulty.)  Cool all affected containers with flooding quantities of water.  Do not use water on material itself.  Apply water from as far a distance as possible. ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Contact of very cold liquid/solid carbon dioxide with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid gas contacts water in a closed container. Forms weak carbonic acid in nonhazardous reaction with water. (REACTIVITY, 1999)

Symptoms:
headaches, dizziness, restlessness, paresthesis; dyspnea; sweating; malaise; increased heart rate, elevated blood pressure, pulse pressure; coma; asphyxia; convulsions; frostbite (dry ice)

Notes 2:
[Note: Shipped as a liquefied compressed gas. Solid form is utilized as dry ice.]

Exposure Symptoms:
Head, dizz, restless, pares; dysp; sweat, mal; incr heart rate, card output, BP; coma; asphy; convuls; frostbite (liq, dry ice)


General Desc:
Iron pentacarbonyl is a yellow to dark red colored liquid.  It is insoluble in water and heavier than water.  It is very toxic by inhalation, ingestion, and skin absorption.  It is a dangerous fire risk because its flash point is 5 deg. F.  It is used to make other chemicals. (¬ AAR, 1999)

Properties:
Flash Point:  5¦ F (unspc) (EPA, 1998)

Melting Point:  -5.8¦ F (EPA, 1998)

Vapor Pressure:  40 mm at 86.54¦ F (EPA, 1998)

Vapor Density:  6.74 (EPA, 1998)

Specific Gravity:  1.46-1.52 (NIOSH, 1997)

Boiling Point:  216.8¦ F at 749 mm (EPA, 1998)

Molecular Weight:  195.9 (EPA, 1998)

TLV TWA:  0.1 ppm (¬ACGIH, 1999)

TLV STEL:  0.2 ppm (¬ACGIH, 1999)

Water Solubility:  Insoluble (NIOSH, 1997)

First Aid:
Warning: Effects may be delayed 12 to 36 hours.  Caution is advised.  Emesis may be contraindicated if victim has ingested a mixture of iron, pentacarbonyl and a hydrocarbon solvent or fuel. Signs and Symptoms of Iron, Pentacarbonyl- Exposure: Acute exposure to iron, pentacarbonyl- may produce dizziness, nausea, and vomiting.  Delayed effects may include fever, cough, chest pain, pulmonary irritation, dypsnea (difficulty breathing), and respiratory failure.  Continuous exposure may lead to coma. Emergency Life-Support Procedures: Acute exposure to iron, pentacarbonyl- may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.  Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to iron, pentacarbonyl-.  2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.  3. Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  4.  Rush to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self-exposure to iron, pentacarbonyl-.  2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.  3.  Remove and isolate contaminated clothing as soon as possible.  4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes.  5.  Wash exposed skin areas thoroughly with soap and water. 6. Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  7.  Rush to a health care facility.  Ingestion Exposure: 1. Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.  2. Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  3. Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of iron, pentacarbonyl- is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.  Ipecac should not be administered to children under 6 months of age.  Warning: Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4. The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal.  4.  Activated charcoal may be administered if victims are conscious and alert. Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water.  5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6. Rush to a health care facility. (EPA, 1998)

Firefighting:
Isolate hazard area and deny entry. Stay upwind and keep out of low areas. Isolate area for 1/2 mile in all directions if tank car or truck is involved in fire. Wear positive pressure breathing apparatus and special protective clothing. Cool containers exposed to flames with water until fire is out. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire.This material is incompatible with water.  Use dry chemical, carbon dioxide, water spray, or foam for small fires, and water spray, fog, or foam for large fires. Move material from fire area if this can be done without risk. Dike fire control water for later disposal. (EPA, 1998)

Reactivity:
AIR AND WATER REACTIONS:  Iron pentacarbonyl is spontaneously flammable in air, R. Kamo, IIT Progs. Rept. 1, p. 23(1962). (REACTIVITY, 1999)

Symptoms:
irritation eyes, muc memb, respiratory system; headache, dizziness, nausea, vomiting; fever, cyanosis, cough, dyspnea (breathing difficulty); liver, kidney, lung injury; degenerative changes in central nervous system

Health Effects:
acute toxicity central nervous system; acute lung damage

Target Organ:
eyes, respiratory system, central nervous system, liver, kidneys

Physical Description:
Colorless to yellow to dark-red, oily liquid.

Exposure Symptoms:
Irrit eyes, muc memb, resp sys; head, dizz, nau, vomit; fever, cyan, cough, dysp; liver, kidney, lung inj; degenerative changes in CNS


General Desc:
PHYSICAL DESCRIPTION:  White powder.

PHYSICAL DATA:  Odorless.  Tasteless.  pH 7.5.  This compound occurs in three crystalline forms. (NTP, 1992)

Properties:
Melting Point:  3380¦ F (decomposes) (NTP, 1992)

Vapor Pressure:  Essentially 0 mm Hg at 68¦ F (NTP, 1992)

Specific Gravity:  3.9-4.2 (NTP, 1992)

Boiling Point:  4500-5400¦ F (NTP, 1992)

Molecular Weight:  79.90 (NTP, 1992)

IDLH:  5000 mg/m3; Not applicable for Titanium dioxide, a potential human carcinogen. (NIOSH, 1997)

Water Solubility:  <1 mg/mL at 68¦ F (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you spill this chemical, dampen the solid spill material with 5% ammonium hydroxide, then transfer the dampened material to a suitable container.  Use absorbent paper dampened with 5% ammonium hydroxide to pick up any remaining material.  Your contaminated clothing and the absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal.  Wash all contaminated surfaces with 5% ammonium hydroxide followed by washing with a soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should store this material under ambient temperatures. (NTP, 1992)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical is incompatible with strong oxidizers and strong acids.  Violent or incandescent reactions may occur with metals (e.g.  aluminum, calcium, magnesium, potassium, sodium, zinc and lithium). (NTP, 1992)

REL NOTES:
CARCINOGEN (Ca); REDUCE EXPOSURE TO LOWEST FEASIBLE CONCONCENTRATION (LOQ 0.2 mg/m3)

Synonyms:
Rutile, Titanium oxide, Titanium peroxide


General Desc:
Perchloromethyl mercaptan is a yellow oily liquid with an offensive odor.  It is slowly decomposed in moist air.  It is insoluble in water.  It is very toxic by inhalation and by skin absorption. (¬ AAR, 1999)

Properties:
Vapor Pressure:  25 mm at 123.8¦ F (EPA, 1998)

Vapor Density:  6.414 (EPA, 1998)

Specific Gravity:  1.700 at 68¦ F (NTP, 1992)

Boiling Point:  297 to 298¦ F at 760 mm (EPA, 1998)

Molecular Weight:  185.87 (EPA, 1998)

IDLH:  10 ppm (NIOSH, 1997)

TLV TWA:  0.1 ppm (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 70¦ F (NTP, 1992)

First Aid:
Signs and Symptoms of Acute Perchloromethylmercaptan Exposure: Signs and symptoms of acute exposure to perchloromethylmercaptan may lead to liver, heart, and kidney damage.  Respiratory effects include coughing, dyspnea (shortness of breath), painful breathing, and lung congestion.  Tachycardia (rapid heart rate) is often observed.  Nausea, vomiting, abdominal cramping, and diarrhea may also occur.  Contact with perchloromethylmercaptan may result in severe dermatitis (red, inflamed skin), conjunctivitis (red, inflamed eyes), and burns with ulceration and severe pain. Emergency Life-Support Procedures: Acute exposure to perchloromethylmercaptan may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to perchloromethylmercaptan. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to perchloromethylmercaptan. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  THOROUGHLY wash exposed skin areas with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  DO NOT induce vomiting! 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup).  Water or milk should be given only if victims are conscious and alert. 5.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 6.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 7.  Transport to a health care facility. (EPA, 1998)

Firefighting:
Fight fire from maximum distance. Dike fire control water for later disposal; do not scatter the material. Positive pressure breathing apparatus and special protective clothing should be worn.This compound is neither flammable nor a serious fire hazard, although it will support combustion.  Fight small fires with dry chemical, carbon dioxide, water spray, or foam, and large fires with water spray, fog, or foam. Move containers containing this compound away from fire area if possible. (EPA, 1998)

Reactivity:
AIR AND WATER REACTIONS:  Reacts only with hot water to give carbon dioxide, hydrochloric acid, and sulfur. (REACTIVITY, 1999)

Symptoms:
lacrimation, eye inflammation; nose, throat irritation; cough; dyspnea; deep breathing pain, coarse rales; vomiting; pallor; tachycardia; acidosis; anuria

Health Effects:
irritation-eye, nose, throat, skin---marked; suspect carcinogen

Synonyms:
PCM, PMM, Trichloromethane sulfenyl chloride, Trichloromethyl sulfur chloride

Physical Description:
Pale-yellow, oily liquid with an unbearable, acrid odor.

Exposure Symptoms:
Irrit eyes, skin, nose, throat; lac; cough, dysp, deep breath pain, coarse rales; vomit; pallor, tacar; acidosis; anuria; liver, kidney damage


General Desc:
Liquid; colorless; unpleasant odor (USCG, 1999)

Properties:
Flash Point:  144¦ F (NTP, 1992)

Vapor Pressure:  5.8 mm Hg at 77¦ F (NTP, 1992)

Vapor Density:  4.26 (NTP, 1992)

Specific Gravity:  1.209 at 68¦ F (NTP, 1992)

Boiling Point:  286-289¦ F (NTP, 1992)

Molecular Weight:  123.54 (NTP, 1992)

IDLH:  100 ppm (NIOSH, 1997)

Water Solubility:  1-5 mg/mL at 72¦ F (NTP, 1992)

Nonfire Spill Response:
Keep people away; shut off ignition sources; call fire department; notify local health and pollution control agencies; protect water intakes. (USCG, 1999)

Firefighting:
Extinguish with dry chemicals, CO2, or alcohol foam. Use water spray to "knock down" vapors and cool exposed containers. (USCG, 1999)

Reactivity:
STABILITY:  This chemical is sensitive to heat (may be explosive).  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical is incompatible with oxidizers.  It will attack some forms of plastics, rubber and coatings. (NTP, 1992)

Symptoms:
in animals: eye irritation; pulmonary edema; liver, kidney, heart damage

Health Effects:
irritation-eye, nose, throat, skin---moderate; acute lung edema

Target Organ:
respiratory system, liver, kidneys, cardiovascular system, eyes

Exposure Symptoms:
In animals: irrit eyes; pulm edema; liver, kidney, heart damage


Symptoms:
irritation eyes, skin, nose, throat, respiratory system; epistaxis (nosebleed); dermatitis; fingernail damage; irritation gastrointestinal tract; heart, liver, kidney damage

Target Organ:
eyes, skin, respiratory system, heart, liver, kidneys, gastrointestinal tract

Synonyms:
1,1'-Dimethyl-4,4'-bipyridinium dichloride; N,N'-Dimethyl-4,4'-bipyridinium dichloride; Paraquat chloride; Paraquat dichloride

Physical Description:
[herbicide] [Note: Paraquat may also be found commercially as a methyl sulfate

Exposure Symptoms:
Irrit eyes, skin, nose, throat, resp sys; epis; derm; fingernail damage; irrit GI tract; heart, liver, kidney damage


First Aid:
Eyes: Irrigate immediately; Skins: Soap prompt/molten flush immediately; Inhalation: Respiratory support; Ingestion: Medical Attention immediately

Symptoms:
headaches; fatigue; vertigo; anorexia; pruritis; acneform skin eruptions; jaundice, liver necrosis

Health Effects:
acute systemic toxicity/vascular and central nervous system damage; cumulative liver damage; irritation-eye, nose, throat, skin---marked

Physical Description:
Pale-yellow or white solid or powder with an aromatic odor.

Exposure Symptoms:
Head, ftg, verti, anor; pruritus, acne-form skin eruptions; jaun, liver nec


First Aid:
Eyes: Irrigate immediately; Skins: Soap wash immedidately; Inhalation: Respiratory support; Ingestion: Medical attention immediately

Symptoms:
irritation eyes, skin, respiratory system; headache, dizziness, weakness, cyanosis, nausea, convulsions

Synonyms:
1-Mercaptooctadecane, Octadecyl mercaptan, Stearyl mercaptan

Exposure Symptoms:
Irrit eyes, skin, resp sys; head, dizz, weak, cyan, nau, convuls


General Desc:
Octyl mercaptan is a water-white liquid with a flash point of 115 deg. F.  It is insoluble in water and weighs less than water.  It is used to make other chemicals. (¬ AAR, 1999)

Properties:
Flash Point:  115¦ F (oc) (NIOSH, 1997)

Melting Point:  -57¦ F (NIOSH, 1997)

Vapor Pressure:  3 mm at 212¦F (NIOSH, 1997)

Specific Gravity:  0.84 (NIOSH, 1997)

Boiling Point:  390¦F (NIOSH, 1997)

Molecular Weight:  146.3 (NIOSH, 1997)

Water Solubility:  Insoluble (NIOSH, 1997)

Firefighting:
Use water in flooding quantities as fog.  Use foam, dry chemical, or carbon dioxide.  Keep run-off water out of sewers and water sources.  Cool all affected containers with flooding quantities of water. ( AAR, 1999)

Reactivity:
This compound is incompatible with the following:Oxidizers, reducing agents, strong acids & bases, alkali metals (NIOSH, 1997)

Synonyms:
1-Mercaptooctane, n-Octyl mercaptan, Octylthiol, 1-Octylthiol


General Desc:
Physical State Shipped: Solid

Odor: Slight odor

Color: Yellow

Characteristics in Water: Sinks in water. (USCG, 1999)

Properties:
Flash Point:  302¦ F (cc) (NIOSH, 1997)

Melting Point:  194.04¦ F (NTP, 1992)

Specific Gravity:  1.575 at 64¦ F (NTP, 1992)

Boiling Point:  556¦ F at 756 mm Hg (NTP, 1992)

Molecular Weight:  168.11 (NTP, 1992)

IDLH:  50 mg/m3 (NIOSH, 1997)

TLV TWA:  0.15 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  0.02% (NIOSH, 1997)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you spill this chemical, use absorbent paper to pick up all liquid spill material.  Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal.  Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should store this material under freezer conditions. (NTP, 1992)

Firefighting:
Fire Extinguishing Agents: Water from protected location (USCG, 1999)

Reactivity:
CHEMICAL PROFILE:  Al three isomers have similar properties and may react vigorously with oxidizing materials. Their reaction with nitric acid (nitration) will lead to a mixture of trinitrobenzenes possessing high-explosive properties [Urbanski, 1967, vol. 3, p. 290]. If heat and reaction conditions of the nitration are not controlled, detonation comparable to TNT may occur [Anon., J. R. Inst. Chem., 1960, 84, p. 451]. Mixture of 1,3-dinitrobenzene with tetranitromethane was found highly explosive [Urbanski, 1964, vol. 1, 592]. 1,2-dinitrobenzene is a severe explosion hazard when shocked or exposed to heat or flame. When heated to decomposition all dinitrobenzens emit toxic fumes of nitrogen oxides [Sax, 9th ed., 1996, p. 1374]. (REACTIVITY, 1999)


General Desc:
p-Nitrotoluene is a yellow liquid.  It has a weak aromatic odor.  It is insoluble in water.  It is combustible though it may take some effort to ignite.  Toxic oxides of nitrogen are produced during the combustion of this material.  Avoid contact with strong oxidizers or sulfuric acid.  It can be toxic.  The primary hazard is the threat to the environment.  Immediate steps should be taken to limit its spread to the environment.  Since it is a liquid it can easily penetrate the soil and contaminate ground water or nearby streams.  It is used to make other chemicals. (¬ AAR, 1999)

Properties:
Flash Point:  223¦ F (NTP, 1992)

Lower Exp Limit:  1.6% (NTP, 1992)

Melting Point:  130.1¦ F (NTP, 1992)

Vapor Pressure:  1 mm Hg at 128.7¦ F (NTP, 1992)

Vapor Density:  4.72 (NTP, 1992)

Specific Gravity:  1.1038 at 167¦ F (NTP, 1992)

Boiling Point:  460.9¦ F (NTP, 1992)

Molecular Weight:  137.15 (NTP, 1992)

IDLH:  200 ppm (NIOSH, 1997)

Water Solubility:  <1 mg/mL at 68.9¦ F (NTP, 1992)

Reactivity:
STABILITY:  Solutions of this chemical should be stable for 24 hours under normal lab conditions At elevated temperatures, the vapors can form highly reactive mixtures with air.REACTIVITY:  This material may react violently with sodium, tetranitromethane, strong oxidizers, sulfuric and other acids. (NTP, 1992)

Symptoms:
anoxia, cyanosis; headache, weakness, dizziness; ataxia; dyspnea (breathing difficulty); tachycardia; nausea, vomiting

Physical Description:
Crystalline solid with a weak, aromatic odor.


General Desc:
2-Chloroethanal is a clear colorless liquid with a pungent odor.  It has a high flash point, around 190 deg. F.  It is corrosive to skin and mucous membranes.  It is very toxic by inhalation.  It is soluble in water and at concentrations above 50 percent it forms an insoluble hydrate in water. (¬ AAR, 1999)

Properties:
Flash Point:  190¦ F (NTP, 1992)

Melting Point:  3¦ F (USCG, 1999)

Vapor Pressure:  100 mm Hg at 113¦ F (40% aqueous solution) (NTP, 1992)

Vapor Density:  2.7 (40% aqueous solution) (NTP, 1992)

Specific Gravity:  1.19 at 77¦ F (40% aqueous solution) (NTP, 1992)

Boiling Point:  185¦ F (NTP, 1992)

Molecular Weight:  78.50 (NTP, 1992)

IDLH:  45 ppm (NIOSH, 1997)

TLV TWA:  1 ppm  Ceiling limit. (¬ACGIH, 1999)

Water Solubility:  greater than or equal to 100 mg/mL at 66¦ F (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN:  IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop.  IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION:  DO NOT INDUCE VOMITING.  Corrosive chemicals will destroy the membranes of the mouth, throat, and esophagus and volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting.  Thus, the risk of increasing the medical problems by inducing vomiting of a volatile corrosive chemical is very high.  If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.  IMMEDIATELY transport the victim to a hospital.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body.  DO NOT INDUCE VOMITING.  IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Firefighting:
Do not fight fires in a cargo of explosives.  If large quantities of combustibles are involved, use water in flooding quantities as spray and fog.  Use water spray to knock-down vapors.  Cool all affected containers with flooding quantities of water.  Apply water from as far a distance as possible. ( AAR, 1999)

Reactivity:
STABILITY:  This chemical polymerizes on standing.  At greater than 50% concentration in water, it forms an insoluble hemihydrate.  It is also sensitive to heat.REACTIVITY:  This chemical reacts with oxidizers.  It is incompatible with acids and water. (NTP, 1992)

Symptoms:
skin, eye, mucous membrane irritation; skin burns; eye damage; pulmonary edema; skin, respiratory sensitization; narcosis, coma

Synonyms:
Chloroacetaldehyde (40% aqueous solution), 2-Chloroacetaldehyde, 2-Chloroethanal

Physical Description:
Colorless liquid with an acrid, penetrating odor.

Notes 2:
[Note: Typically found as a 40% aqueous solution.]

Exposure Symptoms:
Irrit skin, eyes, muc memb; skin burns; eye damage; pulm edema; skin, resp sys sens


General Desc:
Ethylene glycol is a clear, colorless syrupy liquid.  The primary hazard is the threat to the environment.  Immediate steps should be taken to limit its spread to the environment.  Since it is a liquid it can easily penetrate the soil and contaminate groundwater and nearby streams. (¬ AAR, 1999)

Properties:
Flash Point:  232¦ F (NTP, 1992)

Lower Exp Limit:  3.2% (NTP, 1992)

Upper Exp Limit:  UEL not listed (USCG, 1999)

Auto Igtn Temp:  775¦ F (USCG, 1999)

Melting Point:  9¦ F (NTP, 1992)

Vapor Pressure:  0.06 mm Hg at 68¦ F; 1 mm Hg at 127.4¦ F (NTP, 1992)

Vapor Density:  2.14 (NTP, 1992)

Specific Gravity:  1.1135 at 68¦ F (NTP, 1992)

Boiling Point:  387.7¦ F (NTP, 1992)

Molecular Weight:  62.07 (NTP, 1992)

TLV TWA:  50 ppm  Ceiling limit. (¬ACGIH, 1999)

Water Solubility:  greater than or equal to 100 mg/mL at 63.5¦ F (NTP, 1992)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Attempt to stop leak if without undue personnel hazard.    Land spill:  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.    Water spill:  Remove trapped material with suction hoses. ( AAR, 1999)

Firefighting:
Extinguish fire using agent suitable for type of surrounding fire.  (Material itself does not burn or burns with difficulty.)  Use "alcohol" foam, dry chemical or carbon dioxide.  Keep run-off water out of sewers and water sources. ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Mixing ethylene glycol in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase:  chlorosulfonic acid, oleum, sulfuric acid, NFPA 1991. (REACTIVITY, 1999)

Symptoms:
irritation eyes, skin, nose, throat; nausea, vomiting, abdominal pain, weakness; dizziness, stupor, convulsions, central nervous system depressant/depression; skin sensitization

Health Effects:
irritation-eye, nose, throat, skin---moderate; central nervous system depression

Synonyms:
1,2-Dihydroxyethane; 1,2-Ethanediol; Glycol; Glycol alcohol; Monoethylene glycol

Physical Description:
Clear, colorless, syrupy, odorless liquid.

Exposure Symptoms:
Irrit eyes, skin, nose, throat; nau, vomit, abdom pain, weak; dizz, stupor, convuls, CNS depres; skin sens


General Desc:
Turpentine is a clear colorless liquid with a characteristic odor.  It has a flash point between 100 and 141 deg. F.  It is lighter than water and insoluble in water.  Its vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  95¦ F (cc) (USCG, 1999)

Lower Exp Limit:  0.8 % (USCG, 1999)

Auto Igtn Temp:  488¦ F (USCG, 1999)

Melting Point:  -58 to -76¦ F (NIOSH, 1997)

Vapor Pressure:  13.44 mm (USCG, 1999)

Specific Gravity:  0.86 (NIOSH, 1997)

Boiling Point:  302 to 320¦ F at 760 mm (USCG, 1999)

Molecular Weight:  136 (NIOSH, 1997)

IDLH:  800 ppm (NIOSH, 1997)

TLV TWA:  100 ppm (¬ACGIH, 1999)

Water Solubility:  Insoluble (NIOSH, 1997)

Reactivity:
CHEMICAL PROFILE:  Calcium hypochlorite was placed in a turpentine container, thought to be empty. A few minutes later, the reaction between the residual turpentine and calcium hypochlorite resulted in an explosion (Benson 1967). Naphthalene, camphor, glycerol, or turpentine will react violently with chromic anhydride (Haz. Chem. Data. 1967. p. 68). Stannic chloride reacts with turpentine, producing heat and sometimes flame (Mellor 7:430. 1946-47). (REACTIVITY, 1999)

Symptoms:
eye, nose, throat irritation; headaches, vertigo; hematuria, albuminuria; skin irritation, sensitization

Health Effects:
irritation-eye, nose, throat, skin---moderate; cumulative kidney damage; central nervous system effects

Synonyms:
Gumspirits, Gum turpentine, Spirits of turpentine, Steam distilled turpentine, Sulfate wood turpentine, Turps, Wood turpentine


Reactivity:
Strong oxidizers (e.g., bromine, chlorine, or fluorine), moisture, nitric acid (decomposes)

Symptoms:
irritation eyes, skin, upper respiratory system; garlic breathing

Synonyms:
Bismuth sesquitelluride, Bismuth telluride, Bismuth tritelluride, Tellurobismuthite

Exposure Symptoms:
Irrit eyes, skin, upper resp sys; garlic breath


First Aid:
Eyes: Irrigate immediately; Skins: Water flush prompt; Inhalation: Fresh air; Ingestion: Medical attention immediately

Synonyms:
Boric anhydride, Boric oxide, Boron trioxide

Physical Description:
Colorless, semitransparent lumps or hard, white, odorless crystals.

Exposure Symptoms:
Irrit eyes, skin, resp sys; cough; conj; skin eryt


Symptoms:
irritation eyes, skin, respiratory system; dermatitis, skin sensitization; conj. bronchitis, wheezing; diarrhea, vomiting; liver, kidney injury; high blood pressure; in animals: teratogenic effects; potential occupational carcinogen

Health Effects:
dermatitis; suspect teratogen; respiratory sensitization (asthma); mutagen; LD50 (oral, rat) 6200 mg/kg

Target Organ:
eyes, skin, respiratory system, central nervous system, liver, kidneys, cardiovascular system

Physical Description:
White, crystalline solid with a slight, characteristic pungent odor.

Notes 2:
[fungicide] [Note: Available commercially as a wettable powder or in liquid form.]

Exposure Symptoms:
Irrit eyes, skin, resp sys; derm, skin sens; conj. bron, wheez; diarr, vomit; liver, kidney inj; high BP; in animals: terato effects; [carc]


Reactivity:
Water, bromine pentafluoride, sodium nitrate, fluorine, strong oxidizers

Notes 2:
[Note: The principal fiber cell wall material of vegetable tissues (wood, cotton, flax, grass, etc.).]


Symptoms:
burning of eyes, nose, mouth; lacrimation, rhinorrhea; cough, choking, substernal pain; nausea, vomiting; headache, dizziness; syncope; pulmonary edema; pneumonia; hypoxia; dermatitis; liquid: frostbite

Synonyms:
Synonyms depend on the degree of chlorination of diphenyl oxide [(C6H5)2O], ranging from monochlorodiphenyl oxide [(C6H4Cl)O(C6H5)] to decachlorodiphenyl


General Desc:
Ethyl chloride is a clear, colorless, gas with a pungent odor.  It has a flash point of -58 deg. F.  and a boiling point of 54 deg. F.  It is lighter than water and insoluble in water.  Its vapors are heavier than air.  At temperatures below 54 deg. F.  it may exist as a liquid.  Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. (¬ AAR, 1999)

Properties:
Flash Point:  -58¦ F (NTP, 1992)

Lower Exp Limit:  3.8% (NTP, 1992)

Upper Exp Limit:  15.4% (NTP, 1992)

Auto Igtn Temp:  966¦ F (USCG, 1999)

Melting Point:  -218¦ F (NTP, 1992)

Vapor Pressure:  1000 mm Hg at 68¦ F; 457 mm Hg at 32¦ F (NTP, 1992)

Vapor Density:  2.22 (NTP, 1992)

Specific Gravity:  0.8978 at 68¦ F (liquid) (NTP, 1992)

Boiling Point:  54.1¦ F (NTP, 1992)

Molecular Weight:  64.52 (NTP, 1992)

IDLH:  3800 ppm (NIOSH, 1997)

TLV TWA:  100 ppm, Animal carcinogen (¬ACGIH, 1999)

Water Solubility:  0.574 g/100 mL at 68¦ F (NTP, 1992)

Reactivity:
STABILITY:  This compound is heat sensitive.REACTIVITY:  This compound will hydrolyze in the presence of alkalies and water.   It reacts with water or steam to produce toxic and corrosive fumes.  It can also react vigorously with oxidizing materials.   The vapor forms highly flammable mixtures with air.  A mixture of this compound with potassium is shock-sensitive.  Contact with chemically active metals such as Na, K, Ca, powdered Al, Zn and Mg may result in violent reactions. (NTP, 1992)

Symptoms:
incoordination, inebriation; abdominal cramps; cardiac arrhythmias, cardiac arrest; liver, kidney damage

Target Organ:
liver, kidneys, respiratory system, cardiovascular system, central nervous system

Synonyms:
Chloroethane, Hydrochloric ether, Monochloroethane, Muriatic ether

Physical Description:
Colorless gas or liquid (below 54ºF) with a pungent, ether-like odor.

Exposure Symptoms:
Inco, inebri; abdom cramps; card arrhy, card arrest; liver, kidney damage


General Desc:
Methacrylic acid, glacial is a clear colorless liquid having a pungent odor.  It is corrosive to metals and tissue.  It is also combustible and has a flash point of 170 deg. F., and a melting point of 61 deg. F.  If the material becomes contaminated or is subject to heat, it may polymerize.  If the polymerization takes place inside a container, the container may violently rupture.  It is lighter than water and is soluble in water.  Its vapors are heavier than air.  It is used to make plastics. (¬ AAR, 1999)

Properties:
Flash Point:  170¦ F (NTP, 1992)

Upper Exp Limit:  2.4 % (USCG, 1999)

Auto Igtn Temp:  752¦ F (USCG, 1999)

Melting Point:  61¦ F (NTP, 1992)

Vapor Pressure:  0.65 mm Hg at 68¦ F; 1 mm Hg at 77¦ F (NTP, 1992)

Vapor Density:  2.97 (NTP, 1992)

Specific Gravity:  1.0153 at 68¦ F (NTP, 1992)

Boiling Point:  325¦ F (NTP, 1992)

Molecular Weight:  86.09 (NTP, 1992)

TLV TWA:  20 ppm (¬ACGIH, 1999)

Water Solubility:  greater than or equal to 100 mg/mL at 63¦ F (NTP, 1992)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Use water spray to knock-down vapors.  Neutralize spilled material with crushed limestone, soda ash, or lime.    Vapor knockdown water is corrosive or toxic and should be diked for containment.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Neutralize with agricultural lime (CaO), crushed limestone (CaCO3) or sodium bicarbonate (NaHCO3).  Absorb bulk liquid with fly ash or cement powder.    Water spill:  Use natural barriers or oil spill control booms to limit spill travel.  Neutralize with agricultural lime (CaO), crushed limestone (CaCO3), or sodium bicarbonate (NaHCO3).  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Corrosive, moderately toxic liquid or low-melting solid, m.p. 16 C. Flammable when exposed to heat, flame or strong oxidizers. A storage hazard; violent exothermic polymerizations leading to explosion occurred spontaneously, particularly at low inhibitor or stabilizer concentration [Anon., CISHC Chem. Safety Summ., 1979, 50, p. 34; Bond, J., Loss Prev. Bull., 1991, 101, p. 1]. (REACTIVITY, 1999)

Synonyms:
Methacrylic acid (glacial), Methacrylic acid (inhibited), alpha-Methacrylic acid, 2-Methylacrylic acid, 2-Methylpropenoic acid

Physical Description:
Colorless liquid or solid (below 61ºF) with an acrid, repulsive odor.


First Aid:
Eyes: Irrigate immediately; Inhalation: Respiratory support

REL NOTES:
APPLIES TO METALLIC VANADIUM AND VANADIUM CARBIDE

Symptoms:
eye, respiratory system irritation;  in animals:  bronchitis, pneumonitis

Physical Description:
Dark, odorless particulate dispersed in air.

Notes 2:
[Note: Ferrovanadium metal is an alloy usually containing 50-80% vanadium.]

Exposure Symptoms:
Irrit eyes, resp sys; in animals: bron, pneuitis

86 REL Notes:
Applies to vanadium metal and vanadium carbide


Symptoms:
irritation eyes; central nervous system depressant/depression, analgesia, anesthesia, seizure, respiratory depressant/depression

Notes 2:
[inhalation anesthetic] [Note: A gas above 109ºF.]

Exposure Symptoms:
Irrit eyes; CNS depres, analgesia, anes, sez, resp depres


TLV NOTES:
RESPIRABLE FRACTION, ALL FORMS EXCEPT GRAPHITE FIBERS

Synonyms:
Black lead, Mineral carbon, Plumbago, Silver graphite, Stove black [Note: Also see specific listing for Graphite (synthetic).]

Physical Description:
Steel gray to black, greasy feeling, odorless solid

Exposure Symptoms:
Cough, dyspnea (breathing difficulty), black sputum, decreased pulmonary function, lung fibrosis


Reactivity:
Aluminum (at high temperatures), diazomethane

TLV NOTES:
Measured as inhalable fraction of the aerosol

Symptoms:
irritation eyes, skin, muc memb, upper respiratory system; cough, sneezing, rhinorrhea (discharge of thin nasal mucus)

Health Effects:
nuisance particulate (accumulation in lungs)

Synonyms:
Calcium(II) sulfate dihydrate, Gypsum stone, Hydrated calcium sulfate, Mineral white

Physical Description:
White or nearly white, odorless, crystalline solid.

Exposure Symptoms:
Irrit eyes, skin, muc memb, upper resp sys; cough, sneez, rhin


Main Chemical Name:
URANIUM METAL AND INSOLUBLE COMPOUNDS, as U

General Desc:
Uranium metal, pyrophoric is radioactive and when exposed to air is spontaneously flammable.  It is silver to grayish metal and is twice as heavy as lead.  Radioactive materials emit ionizing radiation that can only be detected using special instruments.  Exposure of humans to intense levels of radiation or prolonged exposure to low levels can be harmful.  Film is also damaged by this radiation. (¬ AAR, 1999)

Properties:
Melting Point:  2097¦ F (NIOSH, 1997)

Vapor Pressure:  0 mm (approx) (NIOSH, 1997)

Specific Gravity:  19.05 (metal) (NIOSH, 1997)

Boiling Point:  6895¦F (NIOSH, 1997)

Molecular Weight:  238.0 (NIOSH, 1997)

IDLH:  10 mg/m3; Not applicable for Uranium (insoluble compounds, as U), a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  0.2 mg/m3 (¬ACGIH, 1999)

TLV STEL:  0.6 mg/m3 (¬ACGIH, 1999)

Water Solubility:  Insoluble (NIOSH, 1997)

Nonfire Spill Response:
Contact the local, state, or Department Of Energy Radiological Response Team.  Do not use water.  Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Keep material dry.  Do not attempt to sweep up dry material.  Cover all suspected material with dry sand or earth to prevent ignition until material can be permanently disposed of. ( AAR, 1999)

Firefighting:
Contact the local, state, or Department Of Energy Radiological Response Team.  Do not use water.  Use graphite, soda ash, powdered sodium chloride, or suitable dry powder.  When fire is out, cover all suspected material with dry sand or earth to prevent re-ignition until material can be permanently disposed of. ( AAR, 1999)

Reactivity:
AIR AND WATER REACTIONS:  Clean uranium turnings or chips oxidize readily in air. If confined in a container without air movement, they will ignite spontaneously.  Moisture increases this reactivity. (Scott 1970).CHEMICAL PROFILE:  Uranium ignites in warm nitric oxide. Uranium reacts with incandescence with hot selenium or sulfur(boiling) (Mellor 12:31-2. 1946-47). An explosion occurred when carbon tetrachloride was used in an attempt to extinguish a small fire involving a small amount of uranium (Allison 1970). Nitric acid can react with uranium with explosive violence (Katz and Rabinowitch 1951). (REACTIVITY, 1999)

Symptoms:
dermatitis; kidney damage; blood changes; [potential occupational carcinogen]; in animals: lung, lymph node damage potential for cancer is a result of alpha-emitting properties & radioactive decay products (e.g., radon).

Target Organ:
skin, kidneys, bone marrow, lymphatic sys

Synonyms:
Uranium metal: Uranium I Synonyms of other insoluble uranium compounds vary depending upon the specific compound.

Physical Description:
Metal: Silver-white, malleable, ductile, lustrous solid.

Exposure Symptoms:
Derm; kidney damage; blood changes; [carc]; in animals: lung, lymph node damage Potential for cancer is a result of alpha-emitting properties & radioactive decay products (e.g., radon).


General Desc:
Boron trifluoride is a colorless gas with a pungent odor.  It is toxic by inhalation.  It is soluble in water and slowly hydrolyzed by cold water to give off hydrofluoric acid, a corrosive material.  Its vapors are heavier than air.  Prolonged exposure of the containers to fire or heat may result in their violent rupturing and rocketing. (¬ AAR, 1999)

Properties:
Lower Exp Limit:  Not Flammable. (EPA, 1998)

Upper Exp Limit:  Not Flammable. (EPA, 1998)

Melting Point:  -196.1¦ F (EPA, 1998)

Vapor Pressure:  760 mm at -149.26¦ F Liquid (EPA, 1998)

Vapor Density:  2.4 (EPA, 1998)

Specific Gravity, Liquid:  1.6 (EPA, 1998)

Boiling Point:  -148¦F (NIOSH, 1997)

Molecular Weight:  67.82 (EPA, 1998)

IDLH:  25 ppm (NIOSH, 1997)

TLV TWA:  1 ppm  Ceiling limit. (¬ACGIH, 1999)

ERPG-1:  2 mg/m3 (AIHA, 1999)

ERPG-2:  30 mg/m3 (AIHA, 1999)

ERPG-3:  100 mg/m3 (AIHA, 1999)

Water Solubility:  106% (in cold H2O) (NIOSH, 1997)

First Aid:
Warning: Boron trifluoride is extremely corrosive.  Caution is advised. Signs and Symptoms of Acute Boron Trifluoride Exposure: Acute inhalation exposure of boron trifluoride may result in sneezing, hoarseness, choking, laryngitis, and respiratory tract irritation.  Bleeding of the nose and gums, ulceration of the nasal and oral mucosa, bronchitis, pneumonia, dyspnea (shortness of breath), chest pain, and pulmonary edema may also occur.  If the eyes have come in contact with boron trifluoride, irritation, pain, swelling, corneal erosion, and blindness may result.  Dermal exposure may result in dermatitis (red, inflamed skin), severe burns, and pain. Emergency Life-Support Procedures: Acute exposure to boron trifluoride may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to boron trifluoride. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 4.  RUSH to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to boron trifluoride. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas THOROUGHLY with soap and water. 6.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 7.  RUSH to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.  Humidified oxygen is preferred. 2.  IMMEDIATELY give the victims milk or water to dilute the hydrofluoric acid: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup).  Milk or water should be given only if victims are conscious and alert. 3. DO NOT induce vomiting. 4. Milk of Magnesia should be administered if victims are conscious and alert.  Use 2.5 mL (1/2 tsp) for children up to 1 year old, 5 mL (1 tsp) for children 1 to 12 years old, and 10 mL (2 tsp) for adults.  Do not exceed 15 mL (3 tsp or 1 tbsp). 5.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 6.  Activated charcoal is of no value. 7.  Repeat the administration of water or milk to conscious and alert victims.  Use quantities listed above (see No.  2). 8.  Transport to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.  Do not use water on material itself. ( AAR, 1999)

Firefighting:
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Ventilate closed spaces before entering them. Wear positive pressure breathing apparatus and full protective clothing. Evacuate area endangered by gas. Do not get water inside container. Move container from fire area if you can do it without risk. Stay away from ends of tanks. Cool containers that are exposed to flames with water from the side until well after fire is out. Isolate area until gas has dispersed.Extinguish with dry chemical, carbon dioxide, water spray, fog, or foam. (EPA, 1998)

Reactivity:
AIR AND WATER REACTIONS:  Fumes in air, slowly hydrolysed by cold water to give hydrofluoric acid, more rapidly with hot water.CHEMICAL PROFILE:  A colorless, strongly irritaiting, toxic gas. Upon contact with water, steam or when heated to decomposition, it will produce toxic fluoride fumes. Incompatible with alkyl nitrates, calcium oxide. Reaction with alkali metals or alkaline earth metals (except magnesium) will cause incandescence [Bretherick, 5th ed., 1995, p. 65]. (REACTIVITY, 1999)

Symptoms:
nasal irritation, epistaxis; burns eyes, skin; in animals: pneumonia, kidney damage, nosebleeds

Health Effects:
acute and chronic lung irritation (pneumonia); irritation-eye, nose, skin---marked

Notes 2:
[Note: Forms dense white fumes in moist air. Shipped as a nonliquefied compressed gas.]

Exposure Symptoms:
Irrit eyes, skin, nose, resp sys; epis; eye, skin burns; in animals: pneu; kidney damage

86 REL Notes:
No limit recommended due to absence of reliable monitoring method


General Desc:
PHYSICAL DESCRIPTION:  White to reddish crystals or crystalline powder; light tan powder. (NTP, 1992)

Properties:
Melting Point:  264-268¦ F (NTP, 1992)

Specific Gravity:  1.0 (NTP, 1992)

Boiling Point:  392¦ F (NTP, 1992)

Molecular Weight:  212.29 (NTP, 1992)

Water Solubility:  <1 mg/mL at 66¦ F (NTP, 1992)

Reactivity:
STABILITY:  This chemical is sensitive to exposure to light.  It may be sensitive to prolonged exposure to air.REACTIVITY:  This chemical is a weak base that forms salts with hydrochloric acid or sulfuric acid.  It can be acetylated.  It is incompatible with strong oxidizers. (NTP, 1992)

Symptoms:
irritation eyes, nose; in animals: liver, kidney damage; potential occupational carcinogen

Synonyms:
4,4'-Diamino-3,3'-dimethylbiphenyl; Diaminoditolyl; 3,3'-Dimethylbenzidine; 3,3'-Dimethyl-4,4'-diphenyldiamine; 3,3'-Tolidine

Exposure Symptoms:
Irrit eyes, nose; in animals: liver, kidney damage; [carc]


Synonyms:
2-Chloro-1-(difluoromethoxy)-1,1,2-trifluoroethane; 2-Chloro-1,1,2-trifluoroethyl difluoromethyl ether; Ethrane®

Physical Description:
Clear, colorless liquid with a mild, sweet odor.


General Desc:
Epichlorohydrin is a clear, colorless liquid with an irritating chloroform like odor.  It has a flash point of 87 deg. F.  If contaminated, the material is subject to polymerization with evolution of intense heat.  If the polymerization takes place inside a container, the container is subject to rupture.  It is irritating to the skin and respiratory system and is toxic by ingestion.  It is heavier than water and soluble in water.  Its vapors are heavier than air.  It weighs 9.8 lbs./gal.  It is used to make plastics, and as a solvent. (¬ AAR, 1999)

Properties:
Flash Point:  93¦ F (cc) (EPA, 1998)

Lower Exp Limit:  3.8 % (EPA, 1998)

Upper Exp Limit:  21 % (EPA, 1998)

Auto Igtn Temp:  772¦ F (USCG, 1999)

Melting Point:  -54.4 to -14.1¦ F (EPA, 1998)

Vapor Pressure:  10 mm at 61.88¦ F (EPA, 1998)

Vapor Density:  3.29 (EPA, 1998)

Specific Gravity:  1.181 at 68¦ F (NTP, 1992)

Boiling Point:  241.7¦ F at 760 mm (EPA, 1998)

Molecular Weight:  92.53 (EPA, 1998)

IDLH:  75 ppm; Not applicable for Epichlorohydrin, a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  0.1 ppm  Skin, Suspected Human Carcinogen (¬ACGIH, 1999)

ERPG-1:  2 ppm (AIHA, 1999)

ERPG-2:  20 ppm (AIHA, 1999)

ERPG-3:  100 ppm (AIHA, 1999)

Water Solubility:  50-100 mg/mL at 72¦ F (NTP, 1992)

First Aid:
Warning: Effects may be delayed for several hours.  Caution is advised. Signs and Symptoms of Acute Epichlorohydrin Exposure: Acute exposure to epichlorohydrin may result in nausea, vomiting, and abdominal pain.  Liver and kidney effects may be observed.  The respiratory tract may become irritated, dyspnea (shortness of breath) may occur, and in acute cases, respiratory paralysis has been observed.  Central nervous system and respiratory depression have been noted.  Facial swelling, mucosal irritation, dermatitis (red, inflamed skin), and eye irritation may also occur following exposure to epichlorohydrin. Emergency Life-Support Procedures: Acute exposure to epichlorohydrin may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to epichlorohydrin. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to epichlorohydrin. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas twice with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 3.  Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of epichlorohydrin is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.Ipecac should not be administered to children under 6 months of age. Warning: Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4. The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  Transport to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Attempt to stop leak if without undue personnel hazard.  Use water spray to disperse vapors and dilute standing pools of liquid.    Apply water spray or mist to knock down vapors.  Combustion products include corrosive or toxic vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.  Apply "universal" gelling agent to immobilize spill.  Apply approriate foam to diminish vapor and fire hazard.    Water spill:  Use natural deep water pockets, excavated lagoons, or sand bag barriers to trap material at bottom.  If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount.  Remove trapped material with suction hoses.  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Firefighting:
If fire becomes uncontrollable, or containers are exposed to direct flames, evacuate for a radius of 1,500 feet. Isolate for one-half mile in all directions if tank car or truck is involved in fire.Epichlorohydrin may react violently with water.Use water spray, dry chemical, foam or carbon dioxide. Water spray may be used to dilute spills to non-flammable mixtures. If leak or spill has not ignited, use water spray to disperse the vapors. Keep fire-exposed containers cooled with water. (EPA, 1998)

Reactivity:
CHEMICAL PROFILE:  Flammable liquid when exposed to heat or flame, confirmed carcinogen. It reacts explosively with aniline, it ignites on contact with potassium tert-butoxide. Reaction with trichloroethylene produces the explosive dichloroacetylene. Violent rection with sulfuric acid or isopropylamine. Exothermic polymerization on contact with strong acids or bases, zinc, aluminum, aluminum chloride, iron, ferric chloride [Sax, 9th ed., 1996, p. 1469]. (REACTIVITY, 1999)

REL NOTES:
CARCINOGEN (Ca); REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION (LOQ 2.5 mg/m3)

Carcinogen:
IARC-2A, NIOSH-Ca, NTP-R, TLV-A3, EPA-B2

Symptoms:
nausea, vomiting; abdominal pain; respiratory distress, coughing; cyanosis; irritated eyes, skin with deep pain; (carcinogenic)

Health Effects:
irritation-eye, skin---marked/skin sensitization; suspect carcinogen/mutagen; kidney and liver damage

Target Organ:
eyes, skin, respiratory system, kidneys, liver, reproductive system

Synonyms:
2-Chloropropylene oxide;  beta-Chloropropylene oxide; Epichlorohydrin

Physical Description:
Colorless liquid with a slightly irritating, chloroform-like odor.

Exposure Symptoms:
Irrit eyes, skin with deep pain; nau, vomit; abdom pain; resp distress, cough; cyan; repro effects; [carc]

86 REL Notes:
Carcinogen; Occupational exposure to be minimized


General Desc:
Diethyl ketone is a clear colorless liquid with an acetone-like odor.  It has a flash point of 55 deg. F.  It is lighter than water and slightly soluble in water.  Its vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  55¦ F (cc) (USCG, 1999)

Lower Exp Limit:  1.6 % (USCG, 1999)

Upper Exp Limit:  6.4 % (USCG, 1999)

Auto Igtn Temp:  842¦ F (USCG, 1999)

Melting Point:  -44¦ F (USCG, 1999)

Vapor Pressure:  25.85 mm (USCG, 1999)

Specific Gravity:  0.81 (NIOSH, 1997)

Boiling Point:  216¦ F at 760 mm (USCG, 1999)

Molecular Weight:  86.13 (USCG, 1999)

TLV TWA:  200 ppm (¬ACGIH, 1999)

Water Solubility:  5% (NIOSH, 1997)

Reactivity:
This compound is incompatible with the following:Strong oxidizers, alkalis, mineral acids, (hydrogen peroxide + nitric acid) (NIOSH, 1997)

Symptoms:
irritation eyes, skin, mucous membrane, respiratory system; cough, sneezing

Synonyms:
DEK, Dimethylacetone, Ethyl ketone, Metacetone, 3-Pentanone, Propione

Exposure Symptoms:
Irrit eyes, skin, muc memb, resp sys; cough, sneez


Symptoms:
lacrimation (discharge of tears), conjunctivitis; shortness breathing, cough, chest rales; nausea, vomiting; skin burns; red blood cell, casts in urine; albuminuria; high blood urea nitrogen; [potential occupational carcinogen] potential for cancer is a result of alpha-emitting properties & radioactive decay products (e.g., radon).

Synonyms:
Synonyms vary depending upon the specific soluble uranium compound.

Physical Description:
Colorless liquid with a strong, acrid, pungent odor.

Exposure Symptoms:
lac, conj; short breath, cough, chest rales; nau, vomit; skin burns; red blood cell, casts in urine; album; high Blood urea nitrogen; [Potential occupational carcinogen] Potential for cancer is a result of alpha-emitting properties


General Desc:
Zirconium, dry is grayish-white, lustrous, metal.  It is insoluble in water and weighs more than water.  It may be toxic by ingestion.  If exposed to high temperatures or flames this material may ignite and burn with an intense flame. (¬ AAR, 1999)

Firefighting:
Use water in flooding quantities as fog.  Solid streams of water may spread fire.  Use foam, dry chemical, or carbon dioxide.  Keep run-off water out of sewers and water sources.  Cool all affected containers with flooding quantities of water.  Apply water from as far a distance as possible. ( AAR, 1999)

Symptoms:
skin, lung granulomas;  in animals:  x-ray evidence of retention in lungs; skin, mucous membrane irritation

Health Effects:
pneumoconiosis; lung and skin granulomas

Synonyms:
Zirconium metal: Zirconium Synonyms of other zirconium compounds vary depending upon the specific compound.

Physical Description:
Metal: Soft, malleable, ductile, solid or gray to gold, amorphous powder.

Exposure Symptoms:
Skin, lung granulomas; in animals: irrit skin, muc memb; X-ray evidence of retention in lungs


General Desc:
Sulfur dioxide is a colorless gas with an irritating sulfur odor.  The vapors are irritating to the eyes and mucous membranes.  It is soluble in water to form sulfurous acid, a corrosive liquid.  The vapor is heavier than air.  The vapors are very toxic by inhalation.  Prolonged exposure of the containers to fire or heat may result in their violent rupturing and rocketing.  It is used to manufacture chemicals, in paper pulping, in metal and food processing, and for many other uses. (¬ AAR, 1999)

Properties:
Auto Igtn Temp:  Not flammable (USCG, 1999)

Melting Point:  -98.9¦ F (EPA, 1998)

Vapor Pressure:  2432 mm at 68¦ F (EPA, 1998)

Vapor Density:  2.26 (EPA, 1998)

Specific Gravity, Liquid:  1.434 (EPA, 1998)

Boiling Point:  14¦ F at 760 mm (EPA, 1998)

Molecular Weight:  64.07 (EPA, 1998)

IDLH:  100 ppm (NIOSH, 1997)

TLV TWA:  2 ppm (¬ACGIH, 1999)

TLV STEL:  5 ppm (¬ACGIH, 1999)

ERPG-1:  0.3 ppm (AIHA, 1999)

ERPG-2:  3 ppm (AIHA, 1999)

ERPG-3:  15 ppm (AIHA, 1999)

Water Solubility:  10% (NIOSH, 1997)

First Aid:
Note: Persons with asthma, subnormal pulmonary function, or cardiovascular disease are at greater risk. Signs and Symptoms of Acute Sulfur Dioxide Exposure: Sulfur dioxide may irritate the eyes and respiratory tract.  Signs and symptoms of acute exposure to sulfur dioxide may be severe and include coughing, choking, dyspnea (shortness of breath), sneezing, wheezing, and chest discomfort.  Upper airway edema (swelling) or obstruction, bronchoconstriction, pneumonia, pulmonary edema, and respiratory paralysis may occur.  Fatigue may be noted.  Gastrointestinal effects may include nausea, vomiting, and abdominal pain.  Cyanosis (blue tint to skin and mucous membranes) may be noted following exposure to sulfur dioxide. Emergency Life-Support Procedures: Acute exposure to sulfur dioxide may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to sulfur dioxide. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to sulfur dioxide. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: No information is available. (EPA, 1998)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.  Neutralize spilled material with crushed limestone, soda ash, or lime.  Do not use water on material itself. ( AAR, 1999)

Firefighting:
Wear self-contained breathing apparatus and full protective clothing. Move container from fire area. Stay away from ends of tanks. Cool containers that are exposed to flames with water from the side until well after the fire is out. Isolate area until gas has dispersed. Keep unnecessary people away.Not flammable. Extinguish fires with dry chemical, carbon dioxide, water spray, fog or foam. (EPA, 1998)

Reactivity:
AIR AND WATER REACTIONS:  With water or moisture in air, gas forms an acid; moist sulfur dioxide is very corrosive (due to the slow formation of sulfuric acid).  (Handling Chemicals Safely 1980 p.876)CHEMICAL PROFILE:  Powdered aluminum burns in the vapor of carbon disulfide, sulfur dioxide, sulfur dichloride, nitrous oxide, nitric oxide, or nitrogen peroxide (Mellor 5:209-212 1946-47).  Each bubble of sulfur dioxide gas led into a container of fluorine produces an explosion (Mellor 2:1 1946-47). Manganese burns with a brilliant flame when heated in sulfur dioxide vapor (Mellor 12:187 1946-47).  Contact of very cold liquefied gas with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid gas contacts water in a closed container (Handling Chemicals Safely 1980). (REACTIVITY, 1999)

Symptoms:
eye, nose, throat irritation; rhinorrhea; choking, coughing; reflex bronchoconstriction; eye, skin burns

Health Effects:
irritation-eye, nose, throat, skin---marked; mutagen; bronchoconstriction; suspect reproductive effects

Synonyms:
Sulfurous acid anhydride, Sulfurous oxide, Sulfur oxide

Physical Description:
Colorless gas with a characteristic, irritating, pungent odor.

Notes 2:
[Note: A liquid below 14ºF. Shipped as a liquefied compressed gas.]

Exposure Symptoms:
Irrit eyes, nose, throat; rhin; choking, cough; reflex bronchoconstriction; liquid: frostbite


General Desc:
Silane is a colorless, flammable and poisonous gas, with a strong repulsive odor.  It is easily ignited in air, reacts with oxidizing agents, is very toxic by inhalation, and is a strong irritant to skin, eyes and mucous membranes.  Silane is lighter than air.  Under prolonged exposure to fire or heat the containers may rupture violently and rocket.  It is used in the production of amorphous silicon. (¬ AAR, 1999)

Properties:
Melting Point:  -301¦ F (NIOSH, 1997)

Vapor Pressure:  greater than 1 atm (NIOSH, 1997)

Boiling Point:  -169¦F (NIOSH, 1997)

Molecular Weight:  32.1 (NIOSH, 1997)

TLV TWA:  5 ppm (¬ACGIH, 1999)

Water Solubility:  Decomposes (NIOSH, 1997)

Firefighting:
Do not extinguish fire unless flow can be stopped.  Do not apply water to point of leak in tank car or container.  Use water in flooding quantities as fog.  Cool all affected containers with flooding quantities of water.  Apply water from as far a distance as possible.  Use "alcohol" foam, dry chemical or carbon dioxide. ( AAR, 1999)

Reactivity:
AIR AND WATER REACTIONS:  Pure state ignites in air, the first seven to eight of the series 6H2n+1 ignite spontaneously in air at room temperature or slightly elevated temperatures Mellor 1:376 1946-47).CHEMICAL PROFILE:  Slowly reacts with water to form silicon hydroxides and hydrogen gas (Hydrides of the Elements of Main Groups I - IV 1971 p.513). (REACTIVITY, 1999)

Symptoms:
irritation eyes, skin, muc memb; nausea, headache

Health Effects:
acute systemic toxicity (analogy with other metal hydrides);


General Desc:
1,1,2-Trichloroethane is a clear to light colored liquid with a flash point between 0 and 74 deg. F.  It is insoluble in water and slightly heavier than water.  It may be toxic by inhalation. (¬ AAR, 1999)

Properties:
Flash Point:  0-74¦ F (unspc) (¬ AAR, 1999)

Lower Exp Limit:  6.0% (NTP, 1992)

Upper Exp Limit:  15.5% (NTP, 1992)

Melting Point:  -35¦ F (NTP, 1992)

Vapor Pressure:  16.7 mm Hg at 68¦ F; 20 mm Hg at 70.9¦ F (NTP, 1992)

Vapor Density:  4.63 (NTP, 1992)

Specific Gravity:  1.4416 at 68¦ F (NTP, 1992)

Boiling Point:  235¦ F (NTP, 1992)

Molecular Weight:  133.42 (NTP, 1992)

IDLH:  100 ppm; Not applicable for 1,1,2-Trichloroethane, a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  10 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  1-5 mg/mL at 68¦ F (NTP, 1992)

Reactivity:
STABILITY:  This compound is light and heat sensitive.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This material is incompatible with strong oxidizers and strong bases.   It reacts violently with sodium, potassium, magnesium, and aluminum.  It will attack some forms of plastics, rubber and coatings. (NTP, 1992)

Symptoms:
eye, nose irritation; central nervous system depression; liver, kidney damage; (carcinogenic)

Synonyms:
Ethane trichloride, beta -Trichloroethane, Vinyl trichloride

Exposure Symptoms:
Irrit eyes, nose; CNS depres; liver, kidney damage; derm; [carc]


General Desc:
Trichloroethylene is a clear colorless volatile liquid having a chloroform-like odor.  It is heavier than water and is slightly soluble in water.  It is non-combustible.  It is used as a solvent, fumigant, in the manufacture of other chemicals, and for many other uses. (¬ AAR, 1999)

Properties:
Flash Point:  >200¦ F (NTP, 1992)

Lower Exp Limit:  12.5% (NTP, 1992)

Upper Exp Limit:  90% (NTP, 1992)

Auto Igtn Temp:  770¦ F (USCG, 1999)

Melting Point:  -99¦ F (NTP, 1992)

Vapor Pressure:  60 mm Hg at 68¦ F; 77 mm Hg at 77¦ F (NTP, 1992)

Vapor Density:  4.53 (NTP, 1992)

Specific Gravity:  1.4649 at 68¦ F (NTP, 1992)

Boiling Point:  189¦ F (NTP, 1992)

Molecular Weight:  131.40 (NTP, 1992)

IDLH:  1000 ppm; Not applicable for Trichloroethylene, a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  50 ppm.  Not suspected as a human carcinogen. (¬ACGIH, 1999)

TLV STEL:  100 ppm.  Not suspected as a human carcinogen. (¬ACGIH, 1999)

ERPG-1:  100 ppm (AIHA, 1999)

ERPG-2:  500 ppm (AIHA, 1999)

ERPG-3:  5,000 ppm (AIHA, 1999)

Water Solubility:  <1 mg/mL at 70¦ F (NTP, 1992)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.    Apply water spray or mist to knock down vapors.  Combustion products include corrosive or toxic vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash or cement powder.    Water spill:  If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount.  Remove trapped material with suction hoses.  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  It has been determined experimentally that mixtures of finely divided barium metal and a number of halogenated hydrocarbons possess an explosive capability. Specifically, impact sensitivity tests have shown that granular barium in contact with monofluorotrichloromethane, trichlorotrifluoroethane, carbon tetrachloride, trichloroethylene, or tetrachloroethylene can detonate (ASESB Pot. Incid. 39. 1968; Chem. Eng. News 46(9):38. 1968). It has been determined experimentally that a mixture of beryllium powder with carbon tetrachloride or with trichloroethylene will flash or spark on heavy impact (ASESB Pot. Incid. 39. 1968). A mixture of powdered magnesium with trichloroethylene or with carbon tetrachloride will flash or spark under heavy impact (ASESB Pot. Incid, 39. 1968). (REACTIVITY, 1999)

PEL NOTES:
PEAK = 300 ppm FOR A 5 MINUTE INTERVAL DURING ANY 2 HOURS

REL NOTES:
CARCINOGEN (Ca);10-Hr REL-TWA.  60 MINUTE CEILING, CEILING IS FOR EXPOSURE TO WASTE ANESTHETIC GASES

Symptoms:
headaches, vertigo; visual disturbance; tremor; somnolence; nausea, vomiting; eye irritation; dermatitis; cardiac arrhythmias; paresthesia; (carcinogenic)

Health Effects:
narcosis; cumulative systemic toxicity; mutagen/suspect carcinogen; suspect teratogen

Target Organ:
eyes, skin, respiratory system, heart, liver, kidneys, central nervous system

Synonyms:
Ethylene trichloride, TCE, Trichloroethene, Trilene

Physical Description:
Colorless liquid (unless dyed blue) with a chloroform-like odor.

Exposure Symptoms:
Irrit eyes, skin; head, verti; vis dist, ftg, gidd, tremor, som, nau, vomit; derm; card arrhy, pares; liver inj; [carc]


General Desc:
Thioglycolic acid is a colorless liquid with an unpleasant odor.  It is soluble in water.  It is corrosive to metals and tissue. (¬ AAR, 1999)

Properties:
Flash Point:  235¦ F (NTP, 1992)

Lower Exp Limit:  5.9 % (NIOSH, 1997)

Melting Point:  2.3¦ F (NTP, 1992)

Vapor Pressure:  10 mm at 64¦F (NIOSH, 1997)

Specific Gravity:  1.3253 at 68¦ F (NTP, 1992)

Boiling Point:  248¦ F at 20 mm Hg (NTP, 1992)

Molecular Weight:  92.12 (NTP, 1992)

TLV TWA:  1 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  greater than or equal to 100 mg/mL at 64¦ F (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN:  IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop.  IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. INHALATION:  If any of your laboratory personnel should inhale this chemical, remove them at once to open air and arrange for immediate transportation to a medical facility. INGESTION:  DO NOT INDUCE VOMITING.  Corrosive chemicals will destroy the membranes of the mouth, throat, and esophagus and, in addition, have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems.  If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.  IMMEDIATELY transport the victim to a hospital.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the Headache lower than the body.  DO NOT INDUCE VOMITING.  Transport the victim IMMEDIATELY to a hospital. (NTP, 1992)

Reactivity:
STABILITY:  This material is readily oxidized by air.REACTIVITY:  This material is readily oxidize by air. (NTP, 1992)

Symptoms:
irritation eyes, skin, nose, throat; lacrimation (discharge of tears), corneal damage; skin burns, blisters; in animals: weakness; gasping respirations; convulsions

Synonyms:
Acetyl mercaptan, Mercaptoacetate, Mercaptoacetic acid, 2-Mercaptoacetic acid, 2-Thioglycolic acid, Thiovanic acid

Physical Description:
Colorless liquid with a strong, disagreeable odor characteristic of mercaptans.

Notes 2:
[Note: Olfactory fatigue may occur after short exposures.]

Exposure Symptoms:
Irrit eyes, skin, nose, throat; lac, corn damage; skin burns, blisters; in animals: weak; gasping respirations; convuls


General Desc:
Physical State Shipped: Watery liquid Odor: Gasoline-like odor

Characteristics in Water: Floats on water.  Flammable, irritating vapor is produced. (USCG, 1999)

Properties:
Flash Point:  -20¦ F (cc) (USCG, 1999)

Lower Exp Limit:  1.2 % (USCG, 1999)

Upper Exp Limit:  7.7 % (USCG, 1999)

Auto Igtn Temp:  585¦ F (USCG, 1999)

Melting Point:  -244.6¦ F (USCG, 1999)

Vapor Pressure:  310.20 mm (USCG, 1999)

Specific Gravity, Liquid:  0.653 at 68.0¦ F (USCG, 1999)

Boiling Point:  140.5¦ F at 760 mm (USCG, 1999)

Molecular Weight:  86.18 (USCG, 1999)

TLV TWA:  500 ppm (¬ACGIH, 1999)

TLV STEL:  1000 ppm (¬ACGIH, 1999)

First Aid:
INHALATION:  maintain respiration, give oxygen if needed. ASPIRATION:  enforce bed rest; give oxygen. INGESTION:  do NOT induce vomiting; call a doctor.  EYES:  wash with copious amount of water.  SKIN: wipe off, wash with soap and water. (USCG, 1999)


General Desc:
Physical State Shipped: Liquid (USCG, 1999)

Properties:
Flash Point:  91.4¦ F (cc) (USCG, 1999)

Vapor Pressure:  3 mm (NIOSH, 1997)

Specific Gravity:  0.90 (NIOSH, 1997)

Boiling Point:  285.8¦ F at 760 mm (USCG, 1999)

Molecular Weight:  104.15 (USCG, 1999)

Water Solubility:  Miscible (NIOSH, 1997)

Firefighting:
Fire Extinguishing Agents: Water, carbon dioxide, dry chemical, alcohol foam. (USCG, 1999)

Reactivity:
CHEMICAL PROFILE:  Oxidizes readily in air to form unstable peroxides that may explode spontaneously(Bretherick, 1979 p.151-154, 164). (REACTIVITY, 1999)

Symptoms:
in animals: irritation eyes, skin; hemoglobinuria, anemia, pulmonary edema

Synonyms:
Ethylene glycol isopropyl ether,  -Hydroxyethyl isopropyl ether, Isopropyl Cellosolve®, Isopropyl glycol

Physical Description:
Colorless liquid with a mild, ethereal odor.

Exposure Symptoms:
In animals: irrit eyes, skin; hemog, anemia, pulm edema


General Desc:
N-propyl acetate is a clear colorless liquid with a pleasant odor.  It has a flash point of 58 deg. F.  It is lighter than water and slightly soluble in water.  Its vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  58¦ F (cc)
65¦ F (oc) (USCG, 1999)

Lower Exp Limit:  2.0 % (USCG, 1999)

Upper Exp Limit:  8.0 % (USCG, 1999)

Auto Igtn Temp:  842¦ F (USCG, 1999)

Melting Point:  -139¦ F (USCG, 1999)

Vapor Pressure:  67.21 mm (USCG, 1999)

Specific Gravity:  0.84 (NIOSH, 1997)

Boiling Point:  214.9¦ F at 760 mm (USCG, 1999)

Molecular Weight:  102.13 (USCG, 1999)

IDLH:  1700 ppm (NIOSH, 1997)

TLV TWA:  200 ppm (¬ACGIH, 1999)

TLV STEL:  250 ppm (¬ACGIH, 1999)

Water Solubility:  2% (NIOSH, 1997)

Reactivity:
CHEMICAL PROFILE:  Colorless, highly flammable liquid, moderately toxic. Dangerous fire hazard when exposed to heat, flame, sparks, or strong oxidizers. When heated to decomposition it emits acrid smoke and irritaiting fumes [Lewis, 3rd ed., 1993, p. 1093]. (REACTIVITY, 1999)

Synonyms:
Propylacetate, n-Propyl ester of acetic acid

Physical Description:
Colorless liquid with a mild, fruity odor.

Exposure Symptoms:
In animals: irrit eyes, nose, throat; narco; derm


General Desc:
Benzene is a clear colorless liquid with a petroleum-like odor.  It has a flash point of less than 0 deg. F.  It is lighter than water and insoluble in water.  Its vapors are heavier than air. (¬ AAR, 1999)

Properties:
Flash Point:  12¦ F (NTP, 1992)

Lower Exp Limit:  1.4% (NTP, 1992)

Upper Exp Limit:  8% (NTP, 1992)

Auto Igtn Temp:  1097¦ F (USCG, 1999)

Melting Point:  41.9¦ F (NTP, 1992)

Vapor Pressure:  60 mm Hg at 59¦ F; 76 mm Hg at 68¦ F (NTP, 1992)

Vapor Density:  2.77 (NTP, 1992)

Specific Gravity:  0.8765 at 68¦ F (NTP, 1992)

Boiling Point:  176.2¦ F (NTP, 1992)

Molecular Weight:  78.11 (NTP, 1992)

IDLH:  500 ppm; Not applicable for Benzene, a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  0.1 ppm, Confirmed human carcinogen, skin. (¬ACGIH, 1999)

ERPG-1:  50 ppm (AIHA, 1999)

ERPG-2:  150 ppm (AIHA, 1999)

ERPG-3:  1000 ppm (AIHA, 1999)

Water Solubility:  1-5 mg/mL at 64¦ F (NTP, 1992)

Reactivity:
CHEMICAL PROFILE:  Allyl chloride or other alkyl halides will react vigorously with benzene or toluene, even at minus 70C. in the presence of ethyl aluminum dichloride or ethyl aluminum sesquichloride. Explosions have been reported (NFPA 491M 1991). Benzene ignites in contact with the powdered chromic anhydride (Mellor 11:235 1946-47). (REACTIVITY, 1999)

PEL NOTES:
SEE 29 CFR 1910.1028, FOR INDUSTRIES EXEMPT FROM THIS STANDARD THE PELs ARE LOCATED IN 29 CFR 1910.1000 TABLE Z-2 (8-HR TWA=10 ppm, C=25ppm, PEAK=50ppm FOR A 10 MINUTE INTERVAL DURING AN 8-HOUR SHIFT)

Carcinogen:
IARC-1, NIOSH-Ca, NTP-K, OSHA-Ca, TLV-A1, EPA-K

Symptoms:
eye, nose, respiratory system irritation; giddiness; headaches; nausea; staggered gait; fatigue; anorexia; lassitude; dermatitis; bone marrow depression; [carcinogenic]

Health Effects:
suspect leukemogen; cumulative bone marrow damage; TDlo (oral, human) 130 mg/mg

Target Organ:
eyes, skin, respiratory system, blood, central nervous system, bone marrow

Physical Description:
Colorless to light-yellow liquid with an aromatic odor.

Exposure Symptoms:
Irrit eyes, skin, nose, resp sys; gidd; head, nau, staggered gait; ftg, anor, lass; derm; bone marrow depres; [carc]


General Desc:
Methane is a colorless odorless gas.  It is also known as marsh gas or methyl hybride.  It is easily ignited.  The vapors are lighter than air.  Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket.  It is used in making other chemicals and as a constituent of the fuel, natural gas. (¬ AAR, 1999)

Properties:
Flash Point:  -306¦ F (NTP, 1992)

Lower Exp Limit:  5% (NTP, 1992)

Upper Exp Limit:  15% (NTP, 1992)

Auto Igtn Temp:  1004¦ F (USCG, 1999)

Melting Point:  -296.5¦ F (NTP, 1992)

Vapor Pressure:  258574 mm Hg at 100.0¦ F; 760 mm Hg at -258.7¦ F (NTP, 1992)

Vapor Density:  0.55 (NTP, 1992)

Specific Gravity:  0.425 (NTP, 1992)

Boiling Point:  -258.7¦ F (NTP, 1992)

Molecular Weight:  16.04 (NTP, 1992)

Water Solubility:  3.5 mL/100 mL at 63¦ F (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN:  CAUTION: Exposure of skin to compressed gases may result in freezing of the skin.  Treatment for frostbite may be necessary.  Remove the victim from the source of contamination.  IMMEDIATELY wash affected areas gently with COLD water (and soap, if necessary) while removing and isolating all contaminated clothing.  Dry carefully with clean, soft towels.  If symptoms such as inflammation or irritation develop, IMMEDIATELY call a physician or go to a hospital for treatment. INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  If symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: This compound is a gas, therefore inhalation is the first route of exposure. (NTP, 1992)

Reactivity:
CHEMICAL PROFILE:  Liquid oxygen gives an explosive mixture when combined with liquid methane (NFPA 1991).  Contact of very cold liquefied gas with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid gas contacts water in a closed container (Handling Chemicals Safely 1980). (REACTIVITY, 1999)

TLV NOTES:
TLV-TWA HAS Varies mg/m3, SEE ALIPHATIC HYGROCABON GASES, ALKANE [C1-C4], "INERT" GAS OR VAPOR THAT ACTS PRIMARILY AS A SIMPLE ASPHYXIANT

Health Effects:
explosive; asphyxiant; if oxygen level is 18% or less by volume


General Desc:
Brown, waxy solid, colorless solid.

This material is used as a nematocide. (EPA, 1998)

Properties:
Melting Point:  121¦ F (EPA, 1998)

Vapor Pressure:  9.8e-09 mm at 86¦ F (EPA, 1998)

Specific Gravity:  1.14 at 39-120¦ F (NTP, 1992)

Boiling Point:  Decomposes (NTP, 1992)

Molecular Weight:  303.39 (EPA, 1998)

TLV TWA:  0.1 mg/m3  Skin. (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 69¦ F (NTP, 1992)

First Aid:
Note: Fenamiphos is a cholinesterase inhibitor. Signs and Symptoms of Acute Fenamiphos Exposure: Acute exposure to fenamiphos may produce the following signs and symptoms: pinpoint pupils, blurred vision, headache, dizziness, muscle spasms, and profound weakness.  Vomiting, diarrhea, abdominal pain, seizures, and coma may also occur.  The heart rate may increase following oral exposure or decrease following dermal exposure.  Hypotension (low blood pressure) may occur although hypertension (high blood pressure) is not uncommon.  Chest pain may be noted.  Respiratory symptoms include dyspnea (shortness of breath), respiratory depression, and respiratory paralysis.  Psychosis may occur. Emergency Life-Support Procedures: Acute exposure to fenamiphos may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to fenamiphos. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to fenamiphos. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas three times with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 3.  Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of fenamiphos is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.Ipecac should not be administered to children under 6 months of age. Warning: Ingestion of fenamiphos may result in sudden onset of seizures or loss of consciousness.  Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4. The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  Transport to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Caution :  Explosion potential is high; containers may explode in heat of fire. Avoid sources of extreme heat.(Non-Specific -- Organophosphorus Pesticide, n.o.s.) Stay upwind; keep out of low areas. Ventilate closed spaces before entering them. Remove and isolate contaminated clothing at the site. Do not touch spilled material. Use water spray to reduce vapors. Take up small spills with sand or other noncombustible absorbent material and place in containers for later disposal. Take up small, dry spills with clean shovel and place in clean, dry container. Dike far ahead of large spills for later disposal. (EPA, 1998)

Firefighting:
(Non-Specific -- Organophosphorus Pesticide, n.o.s.) Stay upwind; keep out of low areas. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Dike fire control water for later disposal; do not scatter the material. Wear positive pressure breathing apparatus and special protective clothing.(Non-Specific -- Organophosphorus Pesticide, n.o.s.) This material may burn, but does not ignite readily. For small fires, use dry chemical, carbon dioxide, water spray, or foam. For large fires, use water spray, fog, or foam. (EPA, 1998)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.REACTIVITY:  This compound is hydrolyzed by strong acids and strong alkalies. (NTP, 1992)

Notes 2:
[insecticide] [Note: Found commercially as a granular ingredient (5-15%) or in an emulsifiable concentrate (400 g/l).]


General Desc:
PHYSICAL DESCRIPTION:  Pale yellow solid.

PHYSICAL DATA:  Aromatic odor. (NTP, 1992)

Properties:
Melting Point:  387-388¦ F (NTP, 1992)

Vapor Pressure:  <1 mm Hg at 68¦ F (NTP, 1992)

Vapor Density:  13.9 (air=1 at boiling point of octachloronaphthalene) (NTP, 1992)

Specific Gravity:  2.0 (NTP, 1992)

Boiling Point:  824¦ F (NTP, 1992)

Molecular Weight:  403.70 (NTP, 1992)

Water Solubility:  Insoluble (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN:  IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  If symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION:  DO NOT INDUCE VOMITING.  If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.  Be prepared to transport the victim to a hospital if advised by a physician.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the Headache lower than the body.  DO NOT INDUCE VOMITING.  IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then dampen the solid spill material with toluene, then transfer the dampened material to a suitable container.  Use absorbent paper dampened with toluene to pick up any remaining material.  Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal.  Solvent-wash all contaminated surfaces with toluene followed by washing with a soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should store this material in a refrigerator. (NTP, 1992)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.REACTIVITY:  Contact with strong oxidizing agents may cause fire and explosion. (NTP, 1992)

Symptoms:
acneform dermatitis; liver damage, jaundice

Physical Description:
Waxy, pale-yellow solid with an aromatic odor.


REL NOTES:
CARCINOGEN (Ca); TWA BASED ON 10 HR EXPOSURE

Target Organ:
blood, liver, cardiovascular system, reproductive system; in animals: liver, skin, kidney tumors


General Desc:
PHYSICAL DESCRIPTION:  Silver-bluish white soft metal. (NTP, 1992)

Properties:
Melting Point:  621.5¦ F (NTP, 1992)

Vapor Pressure:  1.77 mm Hg (NTP, 1992)

Specific Gravity:  11.3437 at 61¦ F (NTP, 1992)

Boiling Point:  3164¦ F (NTP, 1992)

Molecular Weight:  207.19 (NTP, 1992)

IDLH:  100 mg/m3 (NIOSH, 1997)

Water Solubility:  Insoluble (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: Some heavy metals are VERY TOXIC POISONS, especially if their salts are very soluble in water (e.g., lead, chromium, mercury, bismuth, osmium, and arsenic).  IMMEDIATELY call a hospital or poison control center and locate activated charcoal, egg whites, or milk in case the medical advisor recommends administering one of them.  Also locate Ipecac syrup or a glass of salt water in case the medical advisor recommends inducing vomiting.  Usually, this is NOT RECOMMENDED outside of a physician's care.  If advice from a physician is not readily available and the victim is conscious and not convulsing, give the victim a glass of activated charcoal slurry in water or, if this is not available, a glass of milk, or beaten egg whites and IMMEDIATELY transport victim to a hospital.  If the victim is convulsing or unconscious, do not give anything by mouth, assure that the victim's airway is open and lay the victim on his/her side with the Headache lower than the body.  DO NOT INDUCE VOMITING.  IMMEDIATELY transport the victim to a hospital. OTHER: Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring.  Recommendations from the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure. (NTP, 1992)

Nonfire Spill Response:
STORAGE PRECAUTIONS:  You should store this chemical under refrigerated temperatures, and keep it away from oxidizing materials. (NTP, 1992)

Firefighting:
Fires involving this material can be controlled with a dry chemical, carbon dioxide, foam, or Halon extinguisher. (NTP, 1992)

Reactivity:
CHEMICAL PROFILE:  In the presence of carbon, the combination of chlorine trifluoride with aluminum, copper, lead, magnesium, silver, tin, or zinc results in a violent reaction (Mellor 2,  Supp. 1: 1956).  A solution of sodium azide in copper pipe with lead joints formed copper and lead azide, both are detonating compounds (Klotz 1973). (REACTIVITY, 1999)

REL NOTES:
AIR CONCENTRATIONS SHOULD BE MAINTAINED SO THAT WORKER BLOOD LEAD REMAINS BELOW 0.06 mg Pb/100 g WHOLE BLOOD

Carcinogen:
TLV-A3*, EPA-B2, NTP-R, IARC-2A*     *inorganic compounds


General Desc:
Silicon powder is a steel-grey crystalline solid or a dark brown powder.  It is insoluble in water and heavier than water.  It burns readily when exposed to heat or flames, and may be difficult to extinguish.  Water may not be effective in extinguishing the flames.  It is used to make computer micro-chips. (¬ AAR, 1999)

Properties:
Melting Point:  2570¦ F (NIOSH, 1997)

Vapor Pressure:  0 mm (approx) (NIOSH, 1997)

Specific Gravity:  2.33 at 77 ¦F (NIOSH, 1997)

Boiling Point:  4271¦F (NIOSH, 1997)

Molecular Weight:  28.1 (NIOSH, 1997)

TLV TWA:  10 mg/m3 (¬ACGIH, 1999)

Water Solubility:  Insoluble (NIOSH, 1997)

Firefighting:
Solid streams of water may spread fire.  Use water in flooding quantities as fog.  Use dry chemical, graphite, or dry earth. ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Selenium, silicon, or sulfur ignites in fluorine gas at ordinary temperatures (Mellor 2:11-13 1946-47). Silicon burns spontaneously in gaseous chlorine.  A mixture of silicon, aluminum, and lead oxide explodes when heated (Mellor 7:657 1946-47). When a mixture of amorphous silicon and an alkali carbonate is heated, a vigorous reaction attended by incandescence occurs (Mellor 6:164 1946-47). Silicon (powdered) reacts violently with silver fluoride (Mellor 3:389 1946-47). The reaction of silicon and sodium-potassium alloy forms sodium silicide, which is spontaneously flammable in air (Mellor 2 Supp. 2:564 1961). (REACTIVITY, 1999)

Physical Description:
Black to gray, lustrous, needle-like crystals.

Notes 2:
[Note: The amorphous form is a dark-brown powder.]


Reactivity:
Strong oxidizers (e.g., chlorine, bromine, fluorine)

Symptoms:
headache, nausea, confusion; in animals: irritation eyes, skin

Synonyms:
1,3-Benzenedicarbonitrile; m-Dicyanobenzene; 1,3-Dicyanobenzene; Isophthalodinitrile; m-PDN

Physical Description:
Needle-like, colorless to white, crystalline, flaky solid with an almond-like odor.

Exposure Symptoms:
Head, nau, conf; in animals: irrit eyes, skin


First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. 

SKIN:  IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. 

INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION:  DO NOT INDUCE VOMITING.  If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.  Be prepared to transport the victim to a hospital if advised by a physician.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body.  DO NOT INDUCE VOMITING.  IMMEDIATELY transport the victim to a hospital.

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you should spill this chemical, use absorbent paper to pick up all liquid spill material.  Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal.  Wash any surfaces you may have contaminated with a soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
STORAGE PRECAUTIONS:  You should store this chemical under refrigerated temperatures, and keep it away from oxidizing materials.

Firefighting:
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher.  A water spray may also be used.

Reactivity:
Water soluble.
2,3-DIBROMO-1-PROPANOL is incompatible with strong oxidizers.

REACTIVE GROUPS:
Alcohols and Polyols, Halogenated Organic Compounds.

Symptoms:
Symptoms of exposure to this compound include irritation of the skin, eyes, mucous membranes and upper respiratory tract.

Health Effects:
It is an irritant of the skin, eyes, mucous membranes and upper respiratory tract.  When heated to decomposition it emits toxic fumes of carbon monoxide, carbon dioxide and hydrogen bromide gas.

Physical Description:
Clear colorless to slightly yellow viscous liquid.


General Desc:
Mustard gas is a clear amber colored oily liquid with a faint odor of mustard/garlic.  It is not readily combustible.  Its vapors are heavier than air, are very toxic, and can be absorbed through the skin.  The effects from exposure to the material include blindness which may be delayed.  Prolonged exposure of the container to fire or intense heat may cause it to violently rupture and rocket.  Mustard gas is also known as dichlorodiethyl sulfide. 

CRIMINAL/TERRORIST USE OF CHEMICAL/BIOLOGICAL AGENTS

The following is intended to supply information to first responders for use in making a preliminary assessment of a situation that they suspect involves criminal/terrorist use of chemical and/or biological (CB) agents.  To aid in the assessment, a list of observable indicators of the use and/or presence of a CB agent is provided in the following paragraphs.

This preamble about differences goes into indicators section of bio and chem. databases
DIFFERENCES BETWEEN A CHEMICAL AND A BIOLOGICAL AGENT

Chemical and biological agents can be dispersed in the air we breathe, the water we drink, or on surfaces we physically contact.  Dispersion methods may be as simple as opening a container, using conventional (garden) spray devices, or as elaborate as detonating an improvised explosive device.

Chemical Incidents are characterized by the rapid onset of medical symptoms (minutes to hours) and easily observed signatures (colored residue, dead foliage, pungent odor, dead insects and animals).

Biological Incidents are characterized by the onset of symptoms in hours to days.  Typically, there will be no characteristic signatures because biological agents are usually odorless and colorless.  Because of the delayed onset of symptoms in a biological incident, the area affected may be greater due to the movement of infected individuals.


INDICATORS OF A POSSIBLE CHEMICAL INCIDENT

Dead animals/birds/fish
Not just an occasional road kill, but numerous animals (wild and domestic, small and large), birds, and fish in the same area.

Lack of insect life
If normal insect activity (ground, air, and/or water) is missing, check the ground/water surface/shore line for dead insects.  If near water, check for dead fish/aquatic birds.

Unexplained odors
Smells may range from fruity to flowery to sharp/pungent to garlic/ horseradish-like to bitter almonds/peach kernels to new mown hay.  It is important to note that the particular odor is completely out of character with its surroundings.

Unusual numbers of dying or sick people (mass casualties)
Health problems including nausea, disorientation, difficulty in breathing, convulsions, localized sweating, conjunctivitis (reddening of eyes/nerve agent symptoms), erythema (reddening of skin/vesicant symptoms) and death.

Pattern of casualties
Casualties will likely be distributed downwind, or if indoors, by the air ventilation system

Blisters/rashes
Numerous individuals experiencing unexplained water-like blisters, weals (like bee stings), and/or rashes.

Illness in confined area
Different casualty rates for people working indoors versus outdoors dependent on where the agent was released.

Unusual liquid droplets
Numerous surfaces exhibit oily droplets/film; numerous water surfaces have an oily film.  (No recent rain.)

Different looking areas
Not just a patch of dead weeds, but trees, shrubs, bushes, food crops, and/or lawns that are dead, discolored, or withered.  (No current drought.)

Low-lying clouds
Low-lying cloud/fog-like condition that is not consistent with its surroundings.

Unusual metal debris
Unexplained bomb/munitions-like material, especially if it contains a liquid.

First Aid:
Warning: May cause death or permanent injury after very short exposure to small quantities.  Mustard gas is a powerful irritant and vesicant, producing corrosion and necrosis of the skin, eyes, and respiratory tract.  Effects may be delayed by several hours or, in case of ocular effects, by many years.  Cough may occur 1-12 hours after exposure.  Caution is advised.

Signs and Symptoms of Mustard Gas Exposure: Signs and symptoms of acute exposure to mustard gas may include dyspnea (difficult or labored breathing), cough, fever, headache, severe eye irritation, photophobia (sensitivity to light), lacrimation (tearing), and blindness.  Irritation or ulceration of the respiratory tract may occur from inhalation; lesions may be fatal.  Dizziness, malaise (body discomfort), anorexia, and lethargy can occur after acute exposure.  Arrhythmias and CNS excitation with convulsions followed by CNS depression may occur.  Nausea, vomiting, and diarrhea may be caused by ingestion or by systemic absorption.  Hemorrhage and anemia may develop several days after exposure.

Emergency Life-Support Procedures: Treatment has traditionally involved rapid decontamination and symptomatic treatment; TIME IS OF THE ESSENCE in decontamination.  Acute exposure to mustard gas may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.

Inhalation Exposure:
1.  Move victims to fresh air as rapidly as possible.  TIME IS OF THE ESSENCE! Emergency personnel should avoid self-exposure to mustard gas.
2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.
3.  Obtain authorization and/or further instructions from the local hospital for administration an antidote or performance of other invasive procedures.
4.  Rush to a health care facility.

Dermal/Eye Exposure:
1.  Remove victims from exposure.  TIME IS OF THE ESSENCE! Emergency personnel should avoid self-exposure to mustard gas.
2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.  
3.  Remove contaminated clothing as soon as possible.
4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes.
5.  Wash exposed skin areas thoroughly with water.  Treat blisters as burns.
6.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures.
7.  Rush to a health care facility.

Ingestion Exposure:
1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.
2.  DO NOT induce vomiting or attempt to neutralize.
3.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures.
4.  Rush to a health care facility.

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.

Firefighting:
Protective clothing and self-contained breathing apparatus required in presence of mustard gas.
Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible.
Extinguish with water, foam, dry chemical, or carbon dioxide.

Reactivity:
Reacts with water or steam to produce toxic and corrosive fumes(oxides of sulfur and chlorine)
MUSTARD GAS is incompatible with bleaching powder.  Reacts violently with oxidizing materials.  Reacts with water or steam to produce toxic and corrosive fumes.  Unstable,  hydrolyzed in aqueous solution.  Avoid high heat; contact with acid or acid fumes.

REACTIVE GROUPS:
Sulfides, Organic, Halogenated Organic Compounds.

Health Effects:
he median lethal dosage is 1500 mg-minute/m3 for inhalation and 10,000 mg-minute/m3 for skin absorption (masked personnel). The median incapacitating dosage is 200 mg-minute/m3 for eye injury and 2000 mg-minute/m3 for skin absorption (masked personnel).

Physical Description:
Mustard gas is a clear amber colored oily liquid with a faint odor of mustard/garlic.


First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN:  IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop.  IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.

INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION:  DO NOT INDUCE VOMITING.  Corrosive chemicals will destroy the membranes of the mouth, throat, and esophagus and, in addition, have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems.  If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.  IMMEDIATELY transport the victim to a hospital.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body.  DO NOT INDUCE VOMITING.  Transport the victim IMMEDIATELY to a hospital.

OTHER:  Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring.  Recommendations from the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure.

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION.  Then, use absorbent paper to pick up all liquid spill material.  Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal.  Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

STORAGE PRECAUTIONS:  You should store this chemical under refrigerated temperatures, and protect it from moisture.  Keep it away from oxidizing materials, acids and bases.

Reactivity:
Insoluble in water. 
STYRENE OXIDE is incompatible with oxidizing agents.  Also incompatible with acids and bases.  Reacts with 4-(4'-nitrobenzyl) pyridine.  Polymerizes exothermally and reacts vigorously with compounds possessing a labile hydrogen (e.g. alcohols and amines) in the presence of catalysts such as acids, bases and certain salts.

Symptoms:
Symptoms of exposure to this compound may include severe irritation of the skin and eyes, and skin sensitization.  It can cause corrosion of tissues.  Other symptoms may include burns, irritation of mucous membranes and upper respiratory tract, nausea, vomiting and headaches.  Exposure may also cause central nervous system depression, hepatic lesions and pain to the eyes.  Symptoms of exposure to a related compound include drying and cracking of the skin on contact, primary irritation to mucosal surfaces, fatigue, weakness, depression, unsteadiness, feeling of drunkenness, abnormal electroencephalograms and one case of toxic retrobulbar neuritis.  Chronic exposure to a related compound has caused peripheral neuropathies (distal hypesthesia and decreased nerve conduction velocities).

Physical Description:
Clear colorless straw-colored liquid with a sweet pleasant odor.


General Desc:
PHYSICAL DESCRIPTION:  Clear, yellowish to reddish or brown liquid.

PHYSICAL DATA:  Amine (fishy) odor. (NTP, 1992)

Properties:
Flash Point:  210¦ F (NTP, 1992)

Melting Point:  41¦ F (NTP, 1992)

Vapor Pressure:  <0.1 mm Hg at 68¦ F; 1 mm Hg at 141.8¦ F (NTP, 1992)

Vapor Density:  4.25 (NTP, 1992)

Specific Gravity:  1.0923 at 68¦ F (NTP, 1992)

Boiling Point:  437¦ F (NTP, 1992)

Molecular Weight:  123.15 (NTP, 1992)

IDLH:  50 mg/m3; Not applicable for o-Anisidine, a potential human carcinogen. (NIOSH, 1997)

TLV TWA:  0.1 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  <0.1 mg/mL at 66¦ F (NTP, 1992)

Reactivity:
STABILITY:  This chemical darkens on exposure to air.  It is sensitive to heat.  It is also sensitive to exposure to light.REACTIVITY:  This chemical is incompatible with strong oxidizers.  It is also incompatible with acids, acid chlorides, acid anhydrides and chloroformates.  It will attack some forms of plastics, rubber and coatings. (NTP, 1992)

Symptoms:
headache, dizziness; cyanosis; red blood cell heinz bodies; potential occupational carcinogen

Synonyms:
ortho-Aminoanisole, 2-Anisidine, o-Methoxyaniline [Note: o-Anisidine has been used as a basis for many dyes.]

Physical Description:
Red or yellow, oily liquid with an amine-like odor.

Exposure Symptoms:
Head, dizz; cyan; RBC Heinz bodies; [carc]


Properties:
Melting Point:  316¦ F (NTP, 1992)

Vapor Pressure:  approximately 0.0 mm Hg at 68¦ F (NTP, 1992)

Specific Gravity:  1.80 at 68¦ F (NTP, 1992)

Boiling Point:  Decomposes (NTP, 1992)

Molecular Weight:  255.49 (NTP, 1992)

IDLH:  250 mg/m3 (NIOSH, 1997)

TLV TWA:  10 mg/m3 (¬ACGIH, 1999)

Water Solubility:  <0.1 mg/mL at 69.8¦ F (NTP, 1992)

Firefighting:
Fire Extinguishing Agents: Water, foam, dry chemical, carbon dioxide (USCG, 1999)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.   It is stable in aqueous solution at pH 5-9.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal laboratory conditions.REACTIVITY:  This chemical forms water-soluble salts with alkali metals and amines.  It reacts with organic and inorganic bases to form salts and with alcohols to form esters.  It is incompatible with strong oxidizing agents and strong bases.  It can be corrosive to common metals.   It may be deleterious to painted surfaces.  Precipitation occurs with hard water in the absence of sequestering agents. (NTP, 1992)

Symptoms:
animal studies: ataxia, skin irritation, acne-like rash

Physical Description:
Colorless to tan, odorless, crystalline solid.

Exposure Symptoms:
In animals: ataxia; skin irrit, acne-like rash; liver damage


General Desc:
Physical State Shipped: Solid powder or granules

Odor: Odorless

Color: White

Characteristics in Water: Sinks in water. (USCG, 1999)

Properties:
Flash Point:  176¦ F (cc) (NIOSH, 1997)

Auto Igtn Temp:  176¦ F (NTP, 1992)

Melting Point:  217-221¦ F (decomposes) (NTP, 1992)

Vapor Pressure:  <0.1 mm Hg at 68¦ F (NTP, 1992)

Specific Gravity:  1.334 (NTP, 1992)

Boiling Point:  Decomposes explosively (NTP, 1992)

Molecular Weight:  242.23 (NTP, 1992)

IDLH:  1500 mg/m3 (NIOSH, 1997)

TLV TWA:  5 mg/m3 (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 79¦ F (NTP, 1992)

Nonfire Spill Response:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).  Keep combustibles (wood, paper, oil, etc.) away from spilled material.  Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.  Keep substance wet using water spray.  Stop leak if you can do it without risk.  SMALL SPILLS:  Take up with inert, damp, noncombustible material using clean non-sparking tools and place into loosely covered plastic containers for later disposal.  LARGE SPILLS:  Wet down with water and dike for later disposal.  Prevent entry into waterways, sewers, basements or confined areas.  DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. (DOT, 1996)

Firefighting:
Fire Extinguishing Agents Not to Be Used: Do not use hand extinguishersFire Extinguishing Agents: Difficult to extinguish once ignited. Use water spray to cool surrounding area. (USCG, 1999)

Reactivity:
CHEMICAL PROFILE:  White, odorless powder, moderately toxic. It is most dangerous when it contains less then 1% water. A moisture content of 3% allowed slow burning only, and at 5% ignition did not occur [McCloskey, C. M. et al., Chem. Abs., 1967, 66, 12613c]. Mixed with a large surplus of water (30% or more) it is relatively safe. In dry form it is a very dangerous material; it will explode spontaneously when heated above melting point (103 C). An explosion which occured when a screw-capped bottle of the peroxide was opened was attributed to friction initiating a mixture of peroxide ond organic dust in the cap threads [Lappin, G. R., Chem. Eng. News, 1948, 26, p.3518]. A violent explosion occurred during purification of the peroxide by Soxhlet extraction with hot chloroform [Anon., Sichere Chemiearb., 1976, 28, p. 49]. It is a powerful oxidizer, it ignites readily and burns rapidly. In contact with reducing agents it may ignite by spontaneous chemical reaction. It must be kept in a cool place in isolation, out of the sunlight or sources of heat, avoid shock or friction. It reacts violently with inorganic or organic acids, alcohols, amines, metallic naphthenates and polymerization accelerators (e.g., N,N-dimethylaniline). Explosive or violent reaction on contact with dimethyl sulfide, lithium aluminum hydride or aniline [Bretherick, 5th ed., 1995, p. 1140]. Mixture with carbon tetrachloride and ethylene explodes when exposed to heat [Bolt, R. O. et al., Chem. Eng. News, 1947, 25, p. 1866]. Ignition occured on contact with methyl methacrylate [MCA Case History No.996], polymerization of vinyl acetate in ethyl acetate accelerated out of control leading to ignition and explosion [Vervalin, 1973, p. 81]. At 50 C a mixture of dibenzoyl peroxide and charcoal reacts violently producing dense white smoke of benzoic acid, benzene, phenyls and carbon dioxide [Leleu, Cashiers, 1980, 99, p. 279]. (REACTIVITY, 1999)

Symptoms:
skin, eye, mucous membrane irritation; sensitization; dermatitis

Physical Description:
Colorless to white crystals or a granular powder with a faint, benzaldehyde-like odor.


General Desc:
Odorless, colorless to white, crystalline solid. [herbicide] [Note: Commercially available as a wettable powder or in liquid formulations.] (NIOSH, 1997)

Properties:
Melting Point:  317¦ F (NIOSH, 1997)

Vapor Pressure:  0.0008 mm at 212¦F (NIOSH, 1997)

Specific Gravity:  1.55 (NIOSH, 1997)

Boiling Point:  Sublimes (NIOSH, 1997)

Molecular Weight:  261.2 (NIOSH, 1997)

Water Solubility:  Sol(77¦F): 0.08% (NIOSH, 1997)

Reactivity:
This compound is incompatible with the following:Strong acids (decomposes slowly), oxidizers, heat, sparks, open flames (NIOSH, 1997)

Symptoms:
irritation eyes, skin, upper respiratory system; in animals: thyroid injury

Physical Description:
Odorless, colorless to white, crystalline solid.

Notes 2:
[herbicide] [Note: Commercially available as a wettable powder or in liquid formulations.]

Exposure Symptoms:
Irrit eyes, skin, upper resp sys; in animals: thyroid inj


87-88 TLV Notes:
Containing no asbestos and <1% crystalline silica


General Desc:
Propionitrile is a colorless liquid with an ether-like odor.  It weighs much less than water and is soluble in water.  It has a flash point of 61 deg. F.  It is toxic by inhalation, skin absorption, and ingestion.  The vapors are heavier than air.  It is used as a solvent, and to make other chemicals. (¬ AAR, 1999)

Properties:
Flash Point:  35.6¦ F (cc) (EPA, 1998)

Lower Exp Limit:  3.1 % (EPA, 1998)

Upper Exp Limit:  14.0% (NTP, 1992)

Melting Point:  -133¦ F (EPA, 1998)

Vapor Pressure:  40 mm at 71.6¦ F (EPA, 1998)

Vapor Density:  1.9 (EPA, 1998)

Specific Gravity:  0.7818 at 68¦ F (NTP, 1992)

Boiling Point:  207¦ F at 760 mm (EPA, 1998)

Molecular Weight:  55.08 (EPA, 1998)

Water Solubility:  50-100 mg/mL at 73¦ F (NTP, 1992)

First Aid:
Warning: Effects, including skin reactions, may be delayed.  Caution is advised.  Vital signs should be monitored closely.  Heart palpitation may begin within minutes after exposure.  Note: Propionitrile is very readily absorbed through the skin.  Signs and Symptoms of Propionitrile Exposure: Signs and symptoms of acute exposure to propionitrile may include hypertension (high blood pressure) and tachycardia (rapid heart rate), followed by hypotension (low blood pressure) and bradycardia (slow heart rate).  Cherry-red mucous membranes and blood, cardiac arrhythmias, and other cardiac abnormalities are common.  Cyanosis (blue tint to the skin and mucous membranes) is not a consistent finding.  Tachypnea (rapid respiratory rate) may be followed by respiratory depression.  Lung hemorrhage and pulmonary edema may also occur.  Headache, vertigo (dizziness), agitation, and giddiness may be followed by combative behavior, convulsions, paralysis, protruding eyeballs, dilated and unreactive pupils, and coma.  Propionitrile is irritating to the skin and mucous membranes.  Lacrimation (tearing) and a burning sensation of the mouth and throat are common.  Excessive salivation, nausea, and vomiting may also occur.  Emergency Life-Support Procedures: Acute exposure to propionitrile may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.  Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to propionitrile.  2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  IMMEDIATELY begin administering 100% oxygen to all victims.  Monitor victims for respiratory distress. Warning: To prevent self-poisoning, avoid mouth-to-mouth breathing; use a forced-oxygen mask.  Direct oral contact with propionitrile-contaminated persons or their gastric contents may result in self-poisoning.  3.  Rush to a health care facility.  4.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self-exposure to propionitrile.  2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  IMMEDIATELY begin administering 100% oxygen to all victims.  Monitor victims for respiratory distress. Warning: To prevent self-poisoning, avoid mouth-to-mouth breathing; usea forced-oxygen mask.  Direct oral contact with propionitrile-contaminated persons or their gastric contents may result in self-poisoning.  3.  Rush to a health care facility.  4.  Remove and isolate contaminated clothing as soon as possible.  5.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes.  6.  Wash exposed skin areas thoroughly with water.  7.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  IMMEDIATELY begin administering 100% oxygen to all victims.  Monitor victims for respiratory distress. Warning: To prevent self-poisoning, avoid mouth-to-mouth breathing; use a forced-oxygen mask.  Direct oral contact with propionitrile-contaminated persons or their gastric contents may result in self-poisoning.  2.  Rush to a health care facility. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  DO NOT induce vomiting or attempt to neutralize! 5.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 6.  Give the victims water or milk: children up to 1 year old, 125 mL (4 oz or 1/2 cup); children 1 to 12 years old, 200 mL (6 oz or 3/4 cup); adults, 250 mL (8 oz or 1 cup).  Water or milk should be given only if victims are conscious and alert. (EPA, 1998)

Firefighting:
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Wear positive pressure breathing apparatus and special protective clothing. Isolate for 1/2 mile in all directions if tank car or truck is involved in fire.Small fires: dry chemical, carbon dioxide, water spray, and foam. Large fires: water spray, fog, or foam. Move containers from fire area if you can do it without risk. Dike fire control water for later disposal; do not scatter the material. Cool containers that are exposed to flames with water from the side until well after fire is out. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. (EPA, 1998)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This compound is incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.  After refluxing for 24 hours at 221 F, a mixture of this compound with N-Bromosuccinimide exploded. (NTP, 1992)

Symptoms:
irritation eyes, skin, respiratory system; nausea, vomiting; chest pain; weakness; stupor, convulsions; in animals: liver, kidney damage

Target Organ:
eyes, skin, respiratory system, cardiovascular system, central nervous system, liver, kidneys

Synonyms:
Cyanoethane, Ethyl cyanide, Propanenitrile, Propionic nitrile, Propiononitrile

Physical Description:
Colorless liquid with a pleasant, sweetish, ethereal odor.

Exposure Symptoms:
Irrit eyes, skin, resp sys; nau, vomit; chest pain; weak; stupor, convuls; in animals: liver, kidney damage


PEL NOTES:
SEE QUARTZ LISTING. TWA TOTAL DUST = (30mg/m3)/(%SiO2+2), TWA RESPIRABLE FRACTION = (10mg/m3)/(%SiO2+2) OR (250mppcf)/(%SiO2+5)


Main Chemical Name:
RHODIUM METAL AND INSOLUBLE COMPOUNDS, as Rh

Synonyms:
Rhodium metal: Elemental rhodium. Synonyms of other insoluble rhodium compounds vary depending upon the specific compound.

Physical Description:
Metal: White, hard, ductile, malleable solid with a bluish-gray luster.


General Desc:
Strontium chromate is a light yellow powder or granular solid.  It is insoluble in water.  The primary hazard is the threat to the environment.  Immediate steps should be taken to limit its spread to the environment.  It is used as a pigment, a protective coating against corrosion, and in pyrotechnics. (¬ AAR, 1999)

Properties:
Auto Igtn Temp:  Not flammable (USCG, 1999)

Specific Gravity, Solid:  3.895 at 59.0¦ F (USCG, 1999)

Molecular Weight:  203.64 (USCG, 1999)

TLV TWA:  0.0005 mg/m3  For Chromium, Suspected Human Carcinogen (¬ACGIH, 1999)

First Aid:
INHALATION:  Remove to fresh air.  EYES:  Irrigate with running water for 15 minutes.  Consult a physician.  SKIN:  Wash thoroughly with soap and water.  INGESTION:  Induce vomiting, give demulcents and fluids. (USCG, 1999)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water.    Water spill:  Add sodium bisulfite (NaHSO3).  Neutralize with agricultural lime (CaO), crushed limestone (CaCO3), or sodium bicarbonate (NaHCO3).  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Reactivity:
Reactivity in Water: Produces hazardous solution.Avoid contact with water, acids, and bases.Polymerization: Will not occur (USCG, 1999)


General Desc:
Bromine pentafluoride is a colorless fuming liquid with a pungent odor.  It is use to make other chemicals and in rockets.  It is decomposed by water to hydrofluoric acid and other materials with release of heat.  It is very toxic by inhalation.  It is corrosive to metals and tissue.  It will accelerate the burning of combustible material.  If the containers are involved in a fire they may rupture violently and rocket. (¬ AAR, 1999)

Properties:
Melting Point:  -76¦ F (USCG, 1999)

Vapor Pressure:  328 mm (NIOSH, 1997)

Specific Gravity:  2.48 (NIOSH, 1997)

Boiling Point:  106¦ F at 760 mm (USCG, 1999)

Molecular Weight:  174.9 (USCG, 1999)

TLV TWA:  0.1 ppm (¬ACGIH, 1999)

Water Solubility:  Reacts violently (NIOSH, 1997)

Nonfire Spill Response:
Do not use water on material itself.  Keep material out of water sources and sewers.  Use water spray to knock-down vapors.  Neutralize spilled material with crushed limestone, soda ash, or lime. ( AAR, 1999)

Firefighting:
Do not use water on material itself.  Use dry chemical or carbon dioxide.  Cool all affected containers with flooding quantities of water.  If large quantities of combustibles are involved, use water in flooding quantities as spray and fog.  Use water spray to knock-down vapors. ( AAR, 1999)

Reactivity:
AIR AND WATER REACTIONS:  Fumes in air, corrosive, and irritating to eyes, skin, mucous membranes.  Produces explosion on contact with water, very reactive usually with conflagration  (Merck, 11th ed. 1989). Reaction with water is very violent (Mellor 2 Supp. 1:172 1956).CHEMICAL PROFILE:  Contact with water causes violent reaction or explosion, oxygen being evolved. Combination of bromine pentafluoride with the following hydrogen containing substances is likely to cause fire or explosion: acetic acid, ammonia, benzene, ethanol, hydrogen, hydrogen sulfide, methane, cork, grease paper , wax, etc. Combinations of bromine pentafluoride with acids, halogens, metal halides, metals, non-metals, or metal oxides at ambient or slightly above amient temperatures have resulted in violent reaction (nitric acid, sulfuric acid, chlorine, iodine, ammonium chloride, potassium iodide, boron powder, selenium, tellurium, aluminum powder, bismuth, cobalt powder, iron powder, arsenic, nickel powder, chromium trioxide, charcoal, red phosporus, sulfur dioxide, magnesium oxide, etc. Solutions of acetonitrile and 9% bromine pentafluoride have been found to decompose violently at ambient temperatures. Mixtures of perchloryl perchlorate and bromine pentafluoride form shock sensitive explosives. [Bretherick, 5th ed., 1995, p. 640] (REACTIVITY, 1999)

Symptoms:
irritation eyes, skin, respiratory system; corneal necrosis; skin burns; cough, dyspnea (breathing difficulty), pulmonary edema; liver, kidney injury

Health Effects:
irritation-eyes, nose, throat, bronchi, lungs---marked; acute lung damage/edema

Physical Description:
Colorless to pale-yellow, fuming liquid with a pungent odor.

Notes 2:
[Note: A colorless gas above 105ºF. Shipped as a compressed gas.]

Exposure Symptoms:
Irrit eyes, skin, resp sys; corn nec; skin burns; cough, dysp, pulm edema; liver, kidney inj


TLV NOTES:
INHALABLE FRACTION AND VAPOR (TWA); VAPOR AND AEROSOL (STEL)

Symptoms:
irritation eyes, skin, nose; lacrimation (discharge of tears); headache; chest tightness; skin burns, rash; cutaneous hypersensitivity

Physical Description:
Violet solid with a sharp, characteristic odor.

Exposure Symptoms:
Irrit eyes, skin, nose; lac; head; chest tight; skin burns, rash; cutaneous hypersensitivity


General Desc:
Oily liquid; colorless; banana odor.  Floats and mixes with water.  Flammable, irritating vapor is produced (USCG, 1999)

Properties:
Flash Point:  77¦ F (NTP, 1992)

Lower Exp Limit:  1%  at 212¦ F (NTP, 1992)

Upper Exp Limit:  7.5% (NTP, 1992)

Auto Igtn Temp:  680¦ F (USCG, 1999)

Melting Point:  -109.3¦ F (NTP, 1992)

Vapor Pressure:  4 mm Hg at 68¦ F; 5 mm Hg at 74.7¦ F; 760 mm Hg at 288¦ F (NTP, 1992)

Vapor Density:  4.49 (NTP, 1992)

Specific Gravity:  0.8670 at 68¦ F (NTP, 1992)

Boiling Point:  288¦ F (NTP, 1992)

Molecular Weight:  130.18 (NTP, 1992)

IDLH:  1000 ppm (NIOSH, 1997)

TLV TWA:  50 ppm (¬ACGIH, 1999)

TLV STEL:  100 ppm (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 66¦ F (NTP, 1992)

Nonfire Spill Response:
Shut off ignition sources ...  Stop discharge if possible.  Keep people away.  Avoid contact with liquid and vapor.  Stay upwind and use water spray to ``knock down'' vapor.  Isolate and remove discharged material.  Notify local health and pollution control agencies. (USCG, 1999)

Firefighting:
Extinguish with dry chemical, alcohol foam, or carbon dioxide.  Water may be ineffective on fire.  Cool exposed containers with water. (USCG, 1999)

Reactivity:
STABILITY:  This chemical is stable under normal laboratory conditions.  Solutions of this chemical should be stable for 24 hours under normal lab conditions.REACTIVITY:  This compound can react violently with oxidizing materials, nitrates, strong alkalies and strong acids. (NTP, 1992)

Synonyms:
Banana oil, Isopentyl acetate, 3-Methyl-1-butanol acetate, 3-Methylbutyl ester of acetic acid, 3-Methylbutyl ethanoate

Physical Description:
Colorless liquid with a banana-like odor.

Exposure Symptoms:
Irrit eyes, skin, nose, throat; derm; in animals: narco


General Desc:
Physical State Shipped: Watery liquid

Odor: Kerosene odor

Color: Colorless

Characteristics in Water: Floats on water. (USCG, 1999)

Properties:
Flash Point:  100¦ F (cc) (USCG, 1999)

Lower Exp Limit:  0.7 % (USCG, 1999)

Upper Exp Limit:  5 % (USCG, 1999)

Auto Igtn Temp:  444¦ F (USCG, 1999)

Melting Point:  -55¦ F (USCG, 1999)

Specific Gravity, Liquid:  0.81 0.85 at 59.0¦ F liquid) (USCG, 1999)

Boiling Point:  380 560¦ F at 760 mm (USCG, 1999)

First Aid:
INGESTION:  do NOT lavage or induce vomiting; call physician. ASPIRATION:  enforce bed rest; administer oxygen; call physician.  EYES:  wash with plenty of water.  SKIN:  wipe off and wash with soap and water. (USCG, 1999)

TLV NOTES:
as TOTAL HYDROCARBON VAPOR; Avoid prolonged and repeated skin contact to diesel fuels which can lead to dermal irritation and may be associated with increased risk of skin cancer; SKIN

Symptoms:
irritation eyes, skin, nose, throat; burning sensation in chest; headache, nausea, weakness, restlessness, incoordination, confusion, drowsiness; vomiting, diarrhea; dermatitis; chemical pneumonia (aspir liquid)

Physical Description:
Colorless to yellowish, oily liquid with a strong, characteristic odor.

Exposure Symptoms:
Irrit eyes, skin, nose, throat; burning sensation in chest; head, nau, weak, restless, inco, conf, drow; vomit, diarr; derm; chemical pneu (aspir liquid)


General Desc:
Colorless gas with a strong, characteristic, foul odor. [Note: A fuel that is shipped as a liquefied compressed gas.]

First Aid:
Eye: Frostbite Skin: Frostbite Breathing: Respiratory support [NIOSH]

Reactivity:
Strong oxidizers, copper alloys [Note: Forms explosive compounds at high pressure in contact with alloys containing more than 67% copper.]

Symptoms:
irritation respiratory system; excitement, confusion, anesthesia; liquid: frostbite

Synonyms:
MAPP gas, Methyl acetylene-allene mixture, Methyl acetylene-propadiene mixture (stabilized), Propadiene-methyl acetylene, Propyne-allene mixture, Propyne-propadiene mixture

Physical Description:
Colorless gas with a strong, characteristic, foul odor.

Exposure Symptoms:
Irritation respiratory system; excitement, confusion, anesthesia; liquid: frostbite


Main Chemical Name:
NICKEL SULFIDE ROASTING, DUST AND FUME, as Ni

TLV NOTES:
MEASURED AS INHALABLE FRACTION OF THE AEROSOL. INORGANIC ONLY. NICKEL, INSOLUBLE COMPOUNDS, AS Ni


First Aid:
Eye: Irrigate immediately Skin: Water flush immediately Breathing: Respiratory support Swallow: Medical attention immediately [NIOSH]

Symptoms:
in animals: irritation eyes, skin; liver, kidney, lung damage [NIOSH]

Synonyms:
1,3-bis(Aminomethyl)benzene; 1,3-Benzenedimethanamine; MXDA; m-Phenylenebis(methylamine); m-Xylylenediamine

Exposure Symptoms:
in animals: irritation eyes, skin; liver, kidney, lung damage


General Desc:
Brownish-black powder. [Note: Fumes are generated whenever manganese oxides are heated strongly in air.]

First Aid:
Eye: Irrigate immediately; Skin: Soap wash; Breathing: Respiratory support; Swallow: Medical attention immediately (NIOSH)

Reactivity:
Soluble in hydrochloric acid (liberates chlorine gas)

Symptoms:
asthenia, insomnia, mental confusion; low-back pain; vomiting; malaise (vague feeling of discomfort), lassitude (weakness, exhaustion); kidney damage; pneumonitis (NIOSH)

Target Organ:
respiratory system, central nervous system, blood, kidneys (NIOSH)

Synonyms:
Manganese oxide, Manganomanganic oxide, Trimanganese tetraoxide, Trimanganese tetroxide

Notes 2:
[Note: Fumes are generated whenever manganese oxides are heated strongly in air.]

Exposure Symptoms:
Asthenia, insomnia, mental confusion; low-back pain; vomiting; malaise (vague feeling of discomfort), lassitude (weakness, exhaustion); kidney damage; pneumonitis


General Desc:
Methyl tert-butyl ether is a colorless, flammable liquid with a distinctive anesthetic-like odor.  Vapors from methyl tert-butyl ether are heavier than air and produce a narcotic effect.  It's boiling point is 131 deg. F.  and it's flash point is 18 deg. F.  The liquid is lighter than, and miscible in water.  It is used as a octane booster in gasoline. (¬ AAR, 1999)

Properties:
Flash Point:  -14¦ F (cc) (USCG, 1999)

Melting Point:  -164.2¦ F (USCG, 1999)

Specific Gravity, Liquid:  0.7405 at 68.0¦ F (USCG, 1999)

Boiling Point:  131.4¦ F at 760 mm (USCG, 1999)

Molecular Weight:  88.15 (USCG, 1999)

TLV TWA:  40 ppm (¬ACGIH, 1999)

First Aid:
INHALATION: Move victim to fresh air; call emergency medical care. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. EYES OR SKIN: Flush with running water for at least 15 minutes; hold eyelids open if necessary. Remove and isolate contaminated clothing and shoes at the site. Keep victim quiet and maintain normal body temperature. INGESTION: If victim is unconscious or having convulsions, do nothing except keep victim warm. (USCG, 1999)

Reactivity:
CHEMICAL PROFILE:  Oxidizes readily in air to form unstable peroxides that may explode spontaneously (Bretherick 1979. p.151-154, 164). A mixture of liquid air and diethyl ether exploded spontaneously (MCA Case History 616. 1960). (REACTIVITY, 1999)


General Desc:
White crystalline solid with slight sulfurous smell.

This material is used as a nematocide, and an insecticide on vegetables, tobacco, cotton, alfalfa, soy beans, and corn. (EPA, 1998)

Properties:
Melting Point:  172 to 174¦ F (EPA, 1998)

Vapor Pressure:  5e-05 mm at 77¦ F (EPA, 1998)

Specific Gravity:  1.29 at 75 ¦F (NIOSH, 1997)

Boiling Point:  None reported (NIOSH, 1997)

Molecular Weight:  162.23 (EPA, 1998)

TLV TWA:  2.5 mg/m3 (¬ACGIH, 1999)

Water Solubility:  Sol(77¦F): 6% (NIOSH, 1997)

First Aid:
Signs and Symptoms of Acute Methomyl Exposure: Acute exposure to methomyl usually leads to a cholinergic crisis.  Signs and symptoms may include increased salivation, lacrimation (tearing), spontaneous defecation, and spontaneous urination.  Pinpoint pupils, blurred vision, tremor, muscle twitching, and loss of muscle coordination may occur.  Mental confusion, convulsions, and coma may also be noted.  Gastrointestinal effects include nausea, vomiting, diarrhea, and abdominal pain.  Bradycardia (slow heart rate) occurs frequently.  Dyspnea (shortness of breath), pulmonary edema, and respiratory arrest may also occur. Emergency Life-Support Procedures: Acute exposure to methomyl may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to methomyl. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to methomyl. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas three times with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 3.  Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of methomyl is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.Ipecac should not be administered to children under 6 months of age. Warning: Ingestion of methomyl may result in sudden onset of seizures or loss of consciousness.  Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4. The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  Transport to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Caution :  Flammable. Avoid sources of extreme heat or ignition including sparks or fire. Methomyl will liberate toxic nitrogen and sulfur oxide fumes when heated to decomposition.(Non-Specific -- Carbamate Pesticide, Solid) Keep unnecessary people away; isolate hazard areas and deny entry. Stay upwind and keep out of low areas. Do not touch spilled material, or handle broken packages without protective equipment. Do not breathe dust, vapors, or the fumes from burning material. (EPA, 1998)

Firefighting:
(Non-Specific -- Carbamate Pesticide, Solid) Wear self-contained breathing apparatus.(Non-Specific -- Carbamate Pesticide, Solid) Use agent suitable for type of surrounding fire. Use water in flooding quantities as a fog. Use alcohol foam, carbon dioxide, or dry chemical. (EPA, 1998)

Reactivity:
This compound is incompatible with the following:Strong bases (NIOSH, 1997)

Symptoms:
irritation eyes; blurred vision, miosis; salivation; abdominal cramps, nausea, vomiting; dyspnea (breathing difficulty); weakness, muscle twitching; liver, kidney damage

Health Effects:
cholinesterase inhibition; mutagen; LD50 (oral, rat) 17 mg/kg

Target Organ:
eyes, respiratory system, central nervous system, cardiovascular system, liver, kidneys, blood cholinesterase

Physical Description:
White, crystalline solid with a slight, sulfur-like odor.

Exposure Symptoms:
Irrit eyes; blurred vision, miosis; salv; abdom cramps, nau, vomit; dysp; weak, musc twitch; liver, kidney damage


General Desc:
Decaborane is a colorless to white crystalline material with a persistent, disagreeable odor.  It is readily ignited and once ignited burns with a green flame.  It may spontaneously ignite on exposure to air.  It is toxic by skin absorption.  It is slightly soluble in cold water and is slowly hydrolyzed by hot water to give off hydrogen, a flammable gas.  It forms shock sensitive compounds when dissolved in oxygenated or halogenated solvents. (¬ AAR, 1999)

Properties:
Flash Point:  176¦ F (cc) (EPA, 1998)

Auto Igtn Temp:  300¦ F (USCG, 1999)

Melting Point:  211¦ F (EPA, 1998)

Vapor Pressure:  19 mm at 212¦ F (EPA, 1998)

Specific Gravity:  0.94 (NIOSH, 1997)

Boiling Point:  415¦ F at 760 mm (EPA, 1998)

Molecular Weight:  122.22 (EPA, 1998)

IDLH:  15 mg/m3 (NIOSH, 1997)

TLV TWA:  0.05 ppm  Skin. (¬ACGIH, 1999)

TLV STEL:  0.15 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  Slight (NIOSH, 1997)

First Aid:
Warning: Effects may be delayed up to 24 hours.  Caution is advised. Signs and Symptoms of Acute Decaborane Exposure: Signs and symptoms of acute exposure to decaborane may include tightness in the chest, dyspnea (shortness of breath), cough, and wheezing.  Nausea and pulmonary edema may also occur.  Neurological effects of acute exposure include dizziness, headache, weakness, incoordination, muscle spasms, tremor, and seizures.  Exposure to decaborane may irritate or burn the skin, eyes, and mucous membranes. Emergency Life-Support Procedures: Acute exposure to decaborane may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to decaborane. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self- exposure to decaborane. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas at least twice with large amounts of cool water. 6.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support. 2.  Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures. 3.  Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of decaborane is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.  Ipecac should not be administered to children under 6 months of age. Warning: Ingestion of decaborane may result in sudden onset of seizures or loss of consciousness.  Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4. The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal. 4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water. 5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  Transport to a health care facility. (EPA, 1998)

Firefighting:
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Wear positive pressure breathing apparatus and full protective clothing.Small fires: cover with sand, earth or water spray and keep it wet. Large fires: water spray or fog. Do not scatter spilled material with more water than needed for fire control. Move container from fire area if you can do so without risk. Spray cooling water on containers that are exposed to flames until well after fire is out. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (EPA, 1998)

Reactivity:
AIR AND WATER REACTIONS:  It may spontaneously ignite upon exposure to air.CHEMICAL PROFILE:  It forms impact-sensitive mixtures with halocarbons (carbon tetrachloride) or with ethers (dioxane). It ignites in oxygen at 100 C. When heated to decomposition it emits toxic fumes of boron oxides [Hawthorne, M. F., Inorg. Synth., 1967, 10, p. 93]. It may form an explosive mixture with dimethyl sulfoxide [Shriver, 1969, p. 209]. (REACTIVITY, 1999)

Symptoms:
dizziness, headache, nausea, lightheadedness, drowsiness, incoordination; localized muscle spasms, tremors; convulsions; fatigue in animals:  dyspnea; weakness; liver, kidney damage

Health Effects:
acute and chronic central nervous system toxicity; nervous system disturbances---nervous system effects other than narcosis

Physical Description:
Colorless to white crystalline solid with an intense, bitter, chocolate-like odor.

Exposure Symptoms:
Dizz, head, nau, li-head, drow; inco, local musc spasm, tremor, convuls; ftg; in animals: dysp; weak; liver, kidney damage


General Desc:
White crystal or powder; technical product is gray powder. No odor, bitter taste.

This material was used primarily as a rodenticide for control of adult Norway rats. It is not produced commercially in the U.S. (EPA, 1998)

Properties:
Flash Point:  May burn but will not ignite readily (EPA, 1998)

Melting Point:  388¦ F (EPA, 1998)

Vapor Pressure:  0 mm at 77¦ F (EPA, 1998)

Vapor Density:  6.99 (EPA, 1998)

Boiling Point:  Decomposes (NIOSH, 1997)

Molecular Weight:  202.23 (EPA, 1998)

IDLH:  100 mg/m3 (NIOSH, 1997)

TLV TWA:  0.3 mg/m3 (¬ACGIH, 1999)

Water Solubility:  0.06% (NIOSH, 1997)

First Aid:
Signs and Symptoms of ANTU Exposure: Acute exposure to ANTU may result in skin irritation, vomiting, difficult breathing, noisy breathing, pulmonary edema or effusion, low body temperature, and seizures.  Antithyroid activity and hyperglycemia may be observed after chronic sublethal exposure. Emergency Life-Support Procedures: Acute exposure to ANTU may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should  avoid self-exposure to ANTU. 2.  Evaluate vital signs including pulse and respiratory  rate, and note any trauma.  If no pulse is detected,  provide CPR.  If not breathing, provide artificial  respiration.  If breathing is labored, administer  oxygen or other respiratory support. 3.  Obtain authorization and/or further instructions from  the Localized hospital for administration of an antidote or  performance of other invasive procedures. 4.  Transport to a health care facility. Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel  should avoid self-exposure to ANTU. 2.  Evaluate vital signs including pulse and respiratory  rate, and note any trauma.  If no pulse is detected,  provide CPR.  If not breathing, provide artificial  respiration.  If breathing is labored, administer  oxygen or other respiratory support. 3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with  lukewarm water for at least 15 minutes. 5.  Wash exposed skin areas thoroughly with water. 6.  Obtain authorization and/or further instructions from  the Localized hospital for administration of an antidote or  performance of other invasive procedures. 7.  Transport to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory  rate, and note any trauma.  If no pulse is detected,  provide CPR.  If not breathing, provide artificial  respiration.  If breathing is labored, administer  oxygen or other respiratory support. 2.  Obtain authorization and/or further instructions from  the Localized hospital for administration of an antidote or  performance of other invasive procedures. 3.  Vomiting may be induced with syrup of Ipecac.  If  elapsed time since ingestion of ANTU is unknown or  suspected to be greater than 30 minutes, do not induce  vomiting and proceed to Step 4.  Ipecac should not be  administered to children under 6 months of age. Warning: Syrup of Ipecac should be administered only  if victims are alert, have an active gag-reflex, and  show no signs of impending seizure or coma.  If ANY  uncertainty exists, proceed to Step 4. The following dosages of Ipecac are recommended:  children up to 1 year old, 10 mL (1/3 oz); children 1  to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities  of water.  If vomiting has not occurred after 15  minutes, Ipecac may be readministered.  Continue to  ambulate and give water to the victims.  If vomiting  has not occurred within 15 minutes after second  administration of Ipecac, administer activated  charcoal. 4.  Activated charcoal may be administered if victims are  conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for  children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults,  with 125 to 250 mL (1/2 to 1 cup) of water. 5.  Promote excretion by administering a saline cathartic  or sorbitol to conscious and alert victims.  Children  require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to  100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  Transport to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Avoid inhalation and skin contact. Do not touch spilled material, stay upwind, keep out of low areas, deny entry. (EPA, 1998)

Firefighting:
Stay upwind, and out of low areas. Wear self-contained breathing apparatus and full protective clothing.Extinguish with dry chemical, carbon dioxide, water spray, fog, or foam. (EPA, 1998)

Reactivity:
This compound is incompatible with the following:Strong oxidizers, silver nitrate (NIOSH, 1997)

Symptoms:
vomiting; dyspnea; cyanosis; coarse pulmonary  rales; mild liver damage

Health Effects:
cumulative endocrine (thyroid and adrenal) damage; LD50 (oral, rat) 6 mg/kg; skin irritation: eczema

Synonyms:
à-Naphthyl thiocarbamide, 1-Naphthyl thiourea, à-Naphthyl thiourea

Physical Description:
White crystalline or gray, odorless powder.

Exposure Symptoms:
After ingestion of large doses: vomit, dysp, cyan, coarse pulm rales; liver damage


General Desc:
Hexachlorobutadiene is a colorless liquid with a mild odor.  It is insoluble in water and heavier than water.  It is also nonflammable.  It may be toxic by ingestion or inhalation.  It is used as a solvent and heat transfer fluid. (¬ AAR, 1999)

Properties:
Auto Igtn Temp:  1,130¦ F (USCG, 1999)

Melting Point:  -6¦ F (NTP, 1992)

Vapor Pressure:  0.15 mm Hg at 68¦ F; approximately 0.3 mm Hg at 77¦ F (NTP, 1992)

Vapor Density:  8.99 (NTP, 1992)

Specific Gravity:  1.675 at 59.9¦ F (NTP, 1992)

Boiling Point:  419¦ F (NTP, 1992)

Molecular Weight:  260.76 (NTP, 1992)

TLV TWA:  0.02 ppm  Suspected human carcinogen.  Skin. (¬ACGIH, 1999)

ERPG-1:  3 ppm (AIHA, 1999)

ERPG-2:  10 ppm (AIHA, 1999)

ERPG-3:  30 ppm (AIHA, 1999)

Water Solubility:  <0.1 mg/mL at 72¦ F (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN:  IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop.  IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION:  DO NOT INDUCE VOMITING.  Corrosive chemicals will destroy the membranes of the mouth, throat, and esophagus and, in addition, have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems.  If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.  IMMEDIATELY transport the victim to a hospital.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the Headache lower than the body.  DO NOT INDUCE VOMITING.  Transport the victim IMMEDIATELY to a hospital. OTHER: Since this chemical is a known or suspected carcinogen you should contact a physician for advice regarding the possible long term health effects and potential recommendation for medical monitoring.  Recommendations from the physician will depend upon the specific compound, its chemical, physical and toxicity properties, the exposure level, length of exposure, and the route of exposure. (NTP, 1992)

Reactivity:
STABILITY:  This chemical is stable for 2 weeks at temperatures up to 140 F when protected from light.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical rapidly decomposes rubber on contact.  It can react vigorously with oxidizing materials and it reacts to form an explosive product with bromine perchlorate. (NTP, 1992)

Symptoms:
in animals: irritation eyes, skin, respiratory system; kidney damage; potential occupational carcinogen

Physical Description:
Clear, colorless liquid with a mild, turpentine-like odor.

Exposure Symptoms:
In animals: irrit eyes, skin, resp sys; kidney damage; [carc]


General Desc:
PHYSICAL DESCRIPTION:  Yellow solid or powder. (NTP, 1992)

Properties:
Melting Point:  227.3-230.9¦ F (NTP, 1992)

Vapor Pressure:  Very low (NIOSH, 1997)

Specific Gravity:  1.06 (NIOSH, 1997)

Boiling Point:  Decomposes (NIOSH, 1997)

Molecular Weight:  230.27 (NTP, 1992)

IDLH:  100 mg/m3 (NIOSH, 1997)

TLV TWA:  0.1 mg/m3 (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 72¦ F (NTP, 1992)

Reactivity:
STABILITY:  This material is stable under normal laboratory conditions. (NTP, 1992)

Symptoms:
epistaxis, excess bleeding from minor cuts, bruises; smokey urine, black tarry stools; abdominal, back pain

Health Effects:
cumulative anticoagulant effect (warfarin analogy)

Synonyms:
tert-Butyl valone; 1,3-Dioxo-2-pivaloy-lindane; Pival®; Pivalyl; 2-Pivalyl-1,3-indandione

Physical Description:
Bright-yellow powder with almost no odor.

Exposure Symptoms:
Epis, excess bleeding from minor cuts, bruises; smoky urine, black tarry stools; abdom, back pain


General Desc:
Physical State Shipped: Liquid

Odor: Skunk-like odor

Color: Yellow to dark brown

Characteristics in Water: Sinks in water.  Freezing point is 37ºF. (USCG, 1999)

Properties:
Flash Point:  >325¦ F (NTP, 1992)

Melting Point:  37.13¦ F (NTP, 1992)

Vapor Pressure:  0.00004 mm Hg at 86¦ F (NTP, 1992)

Specific Gravity:  1.23 at 77¦ F (NTP, 1992)

Boiling Point:  313-315¦ F at 0.7 mm Hg (decomposes) (NTP, 1992)

Molecular Weight:  330.36 (NTP, 1992)

IDLH:  250 mg/m3 (NIOSH, 1997)

TLV TWA:  10 mg/m3  Skin. (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 70.7¦ F (NTP, 1992)

First Aid:
EYES:  First check the victim for contact lenses and remove if present.  Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.  Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.  IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.  Gently wash all affected skin areas thoroughly with soap and water.  IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop.  IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. INHALATION:  IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.  IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of Breathing, or burning in the mouth, throat, or chest) develop.  Provide proper respiratory protection to rescuers entering an unknown atmosphere.  Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING.  If the victim is conscious and not convulsing, administer a slurry of activated charcoal in water and simultaneously call a hospital or poison control center.  IMMEDIATELY transport the victim to a hospital.  If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the Headache lower than the body.  DO NOT INDUCE VOMITING.  IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Nonfire Spill Response:
Neutralizing Agents for Acids and Caustics: Liquid bleach solution for decontamination. (USCG, 1999)

Firefighting:
Fire Extinguishing Agents: Dry chemical, carbon dioxide, water spray, foam (USCG, 1999)

Reactivity:
CHEMICAL PROFILE:  Yellow to brown liquid, it turn solid at 2.9C, moderately toxic. Organic phosphate insecticide, acts as an inhibitor of cholinesterase. When heated to decomposition it emits toxic fumes of oxides of sulfur and phosphorus [Lewis, 3rd ed., 1993, p. 789]. (REACTIVITY, 1999)

Symptoms:
miosis, aching eyes, blurred vision, lacrimation;  eye, skin irritation; rhinorrhea; headaches; tightness of chest, wheezing, laryngeal spasms; salivation; anorexia, nausea, vomiting, abdominal cramping, diarrhea; giddiness, confusion, ataxia

Target Organ:
eyes, skin, respiratory system, liver, blood cholinesterase, central nervous system, cardiovascular system, gastrointestinal tract

Synonyms:
S-[1,2-bis(ethoxycarbonyl) ethyl]O,O-dimethyl-phosphorodithioate; Diethyl (dimethoxyphosphinothioylthio) succinate

Physical Description:
Deep-brown to yellow liquid with a garlic-like odor.

Notes 2:
[insecticide] [Note: A solid below 37ºF.]

Exposure Symptoms:
Irrit eyes, skin; miosis, aching eyes, blurred vision, lac; salv; anor, nau, vomit, abdom cramps, diarr, gidd, conf, ataxia; rhin, head; chest tight, wheez, lar spasm


General Desc:
Cyclotrimethylene trinitramine is an explosive.  The explosion can be initiated by a sudden shock, high temperature or a combination of the two.  The primary hazard is from blast effect and not from flying projectiles and fragments.  Under prolonged exposure to heat or fire they can explode. (¬ AAR, 1999)

Properties:
Melting Point:  401¦ F (NIOSH, 1997)

Vapor Pressure:  0.0004 mm at 230¦F (NIOSH, 1997)

Specific Gravity:  1.82 (NIOSH, 1997)

Boiling Point:  None reported (NIOSH, 1997)

Molecular Weight:  222.2 (NIOSH, 1997)

TLV TWA:  1.5 mg/m3  Skin. (¬ACGIH, 1999)

TLV STEL:  3 mg/m3  Skin. (¬ACGIH, 1999)

Water Solubility:  Insoluble (NIOSH, 1997)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material wet.  Wet spilled material before picking it up.  Do not attempt to sweep up dry material. ( AAR, 1999)

Firefighting:
Dangerously explosive.  Do not fight fires in a cargo of explosives.  Evacuate area and let burn. ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Danger of explosion when dry (REACTIVITY, 1999)

Symptoms:
irritation eyes, skin; headache, irritability, fatigue, weakness, tremor, nausea, dizziness, vomiting, insomnia, convulsions

Health Effects:
chronic central nervous system effects (nausea, convulsions)

Synonyms:
Cyclonite, Cyclotrimethylenetrinitramine; Hexahydro-1,3,5-trinitro-s-triazine; RDX; Trimethylenetrinitramine; 1,3,5-Trinitro-1,3,5-triazacyclohexane

Exposure Symptoms:
Irrit eyes, skin; head, irrity, ftg, weak, tremor, nau, dizz, vomit, insom, convuls


General Desc:
Methylcyclopentadienyl manganese tricarbonyl is a orange colored liquid with a pleasant odor.  It is slightly soluble in water and heavier than water.  It may be toxic by inhalation, ingestion and/or skin absorption. (¬ AAR, 1999)

Properties:
Flash Point:  230¦ F (cc) (EPA, 1998)

Melting Point:  34¦ F (EPA, 1998)

Vapor Pressure:  7.3 mm at 212¦ F (EPA, 1998)

Vapor Density:  0.00064 g/L at 70.0¦ F (NTP, 1992)

Specific Gravity:  1.39 at 68¦ F (NTP, 1992)

Boiling Point:  449¦ F at 760 mm (EPA, 1998)

Molecular Weight:  218.1 (EPA, 1998)

TLV TWA:  0.2 mg/m3  Skin. (¬ACGIH, 1999)

Water Solubility:  Insoluble (NTP, 1992)

First Aid:
Note: Emesis may be contraindicated if victim has ingested a mixture of mangenese, tricarbonyl methylcyclopentadienyl and a hydrocarbon solvent or fuel. Signs and Symptoms of Manganese, Tricarbonyl Methylcyclopentadienyl Exposure: Acute exposure to manganese, tricarbonyl methylcyclopentadienyl may produce eye irritation, headache, slurred speech, sensation of having a thick tongue, giddiness, nausea, and loss of appetite.  Respiratory signs may include slow and labored breathing after acute exposure and chronic bronchitis and interstitial pneumonia after chronic exposure.  Excitability, hyperactivity, muscle spasms, tremors, convulsions, and coma may also be noted.  Emergency Life-Support Procedures: Acute exposure to manganese, tricarbonyl methylcyclopentadienyl may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination. Inhalation Exposure: 1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to manganese, tricarbonyl methylcyclopentadienyl.  2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.  3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  4.  Rush to a health care facility.  Dermal/Eye Exposure: 1.  Remove victims from exposure.  Emergency personnel should avoid self-exposure to manganese, tricarbonyl methylcyclo-pentadienyl. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.  3.  Remove and isolate contaminated clothing as soon as possible.  4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes.  5.  Wash exposed skin areas thoroughly with soap and water. 6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  7.  Rush to a health care facility. Ingestion Exposure: 1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.  2.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  3.  Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of manganese, tricarbonyl methylcyclo-pentadienyl is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.  Ipecac should not be administered to children under 6 months of age.  Warning: Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4.  The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal.  4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water.  5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults.  6.  Rush to a health care facility. (EPA, 1998)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Attempt to stop leak if without undue personnel hazard.    Apply water spray or mist to knock down vapors.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.    Water spill:  Use natural barriers or oil spill control booms to limit spill travel.  Remove trapped material with suction hoses. ( AAR, 1999)

Firefighting:
Extinguish with water, dry chemicals, foam, or carbon dioxide. Wear goggles and self-contained breathing apparatus. (EPA, 1998)

Reactivity:
STABILITY:  This chemical decomposes when exposed to light.  It is stable in water. (NTP, 1992)

Symptoms:
irritation eyes; giddiness, nausea, headache; in animals: tremor, severe clonic spasms, weakness, slow respiration; liver, kidney injury

Health Effects:
acute central nervous system effects; cumulative liver and kidney damage; irritation-eye---moderate

Synonyms:
CI-2, Combustion Improver-2, Manganese tricarbonylmethylcyclopentadienyl, 2-Methylcyclopentadienyl manganese tricarbonyl, MMT

Physical Description:
Yellow to dark-orange liquid with a faint, pleasant odor.

Exposure Symptoms:
Irrit eyes; gidd, nau, head; in animals: tremor, severe clonic spasms, weak, slow respiration; liver, kidney inj


General Desc:
PHYSICAL DESCRIPTION:  White crystals or crystalline powder.

PHYSICAL DATA:  Odorless.  Slightly bitter taste.  Solution in water is acid to methyl red. (NTP, 1992)

Properties:
Flash Point:  482¦ F (NTP, 1992)

Melting Point:  275¦ F (NTP, 1992)

Specific Gravity:  1.40 (NTP, 1992)

Boiling Point:  284¦ F (decomposes) (NTP, 1992)

Molecular Weight:  180.16 (NTP, 1992)

Water Solubility:  <1 mg/mL at 73¦ F (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container.  Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material.  Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal.  Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should store this material under ambient temperatures and protect it from moisture. (NTP, 1992)

Reactivity:
STABILITY:  This compound slowly hydrolyzes in moist air.  Solutions of this chemical in acetone should be stable for 24 hours under normal lab conditions.REACTIVITY:  This chemical is incompatible with oxidizers and strong acids.  It is also incompatible with strong bases.  It may react with water or nucleophiles (e.g.  amines and hydroxy groups).  It may also react with acetanilide, amidopyrine, phenazone, hexamine, iron salts, phenobarbitone sodium, quinine salts, potassium and sodium iodides, alkali hydroxides, carbonates, stearates and paracetanol. (NTP, 1992)

Symptoms:
irritation eyes, skin, upper respiratory system; increased blood clotting time; nausea, vomiting; liver, kidney injury

Synonyms:
Acetal, o-Acetoxybenzoic acid, 2-Acetoxybenzoic acid, Aspirin

Physical Description:
Odorless, colorless to white, crystal-line powder.

Notes 2:
[aspirin] [Note: Develops the vinegar-like odor of acetic acid on contact with moisture.]

Exposure Symptoms:
Irrit eyes, skin, upper resp sys; incr blood clotting time; nau, vomit; liver, kidney inj


General Desc:
PHYSICAL DESCRIPTION:  White powder or crystals; light brown solid. (NTP, 1992)

Properties:
Flash Point:  198¦ F (NTP, 1992)

Melting Point:  138-140¦ F (NTP, 1992)

Vapor Pressure:  0.8 mm at 77¦F (NIOSH, 1997)

Boiling Point:  399-410¦ F (NTP, 1992)

Molecular Weight:  94.12 (NTP, 1992)

IDLH:  5 ppm (NIOSH, 1997)

Water Solubility:  10-50 mg/mL at 66¦ F (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you spill this chemical, you should dampen the solid spill material with water, then transfer the dampened material to a suitable container.  Use absorbent paper dampened with water to pick up any remaining material.  Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal.  Wash all contaminated surfaces with a strong soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should protect this chemical from contact with air.  Store it in a refrigerator with the container tightly closed under an inert atmosphere. (NTP, 1992)

Reactivity:
STABILITY:  This compound is unstable in the presence of air.REACTIVITY:  This compound forms salts with acids and reacts with oxidizing agents. (NTP, 1992)

Symptoms:
headaches, dizziness; excitement; nausea; high blood pressure; respiratory distress; weakness; convulsions; stupor

Health Effects:
headache, increased blood pressure; central nervous system stimulation

Physical Description:
White powder, leaflets, or crystals with a characteristic odor.

Exposure Symptoms:
Irrit eyes, nose, throat; head, dizz; excitement; nau; high BP; resp distress; weak; convuls; stupor


General Desc:
Cyanogen chloride is a colorless liquid boiling at 60 deg. F.  with a strong odor.  In very low concentrations it is irritating to the eyes and mucous membranes while in higher concentrations it is toxic by inhalation.  Its vapor is heavier than air.  Prolonged exposure of the container to fire or intense heat may cause violent rupturing and rocketing.  It weighs 10.0 lbs./gal. (¬ AAR, 1999)

Properties:
Flash Point:  Not Applicable.  Not flammable. (USCG, 1999)

Lower Exp Limit:  Not Applicable.  Not flammable. (USCG, 1999)

Upper Exp Limit:  Not Applicable.  Not flammable. (USCG, 1999)

Auto Igtn Temp:  Not Applicable.  Not flammable. (USCG, 1999)

Melting Point:  20¦ F (USCG, 1999)

Vapor Pressure:  704.36 mm at 50¦ F (USCG, 1999)

Vapor Density (air = 1):  2.1 (USCG, 1999)

Specific Gravity:  1.2 (¬ AAR, 1999)

Boiling Point:  55.6¦ F at 760 mm (USCG, 1999)

Molecular Weight:  61.48 (USCG, 1999)

TLV TWA:  0.3 ppm  Ceiling limit. (¬ACGIH, 1999)

ERPG-1:  not appropriate (AIHA, 1999)

ERPG-2:  0.4 ppm (AIHA, 1999)

ERPG-3:  4 ppm (AIHA, 1999)

Water Solubility:  7% (NIOSH, 1997)

First Aid:
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical. Skin: If this chemical in liquid form contacts the skin, immediately wash the contaminated skin with water. If this chemical penetrates the clothing, immediately remove the clothing and wash the skin with water. If symptoms occur after washing, get medical attention immediately. Breathing: If a person breathes large amounts of this chemical, move the exposed  person to fresh air at once. If breathing has stopped, perform mouth-to-mouth  resuscitation. Keep the affected person warm and at rest. Get medical  attention as soon as possible. Swallow: If this chemical in liquid form has been swallowed, get medical attention immediately. (NIOSH, 1997)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Attempt to stop leak if without undue personnel hazard.  Use water spray to knock-down vapors.    Vapor knockdown water is corrosive or toxic and should be diked for containment.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash or cement powder.    Water spill:  Add dilute caustic soda (NaOH).  Add calcium hypochlorite (Ca(ClO)2).  Adjust pH to neutral (pH=7). ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Very slow reaction with water to form hydrogen cyanide. (REACTIVITY, 1999)

Symptoms:
irritation eyes, upper respiratory system; cough, delayed pulmonary edema; weakness, headache, giddiness, dizziness, confusion, nausea, vomiting; irregular/irregularities heartbeat; irritation skin (liquid)

Synonyms:
Chlorcyan, Chlorine cyanide, Chlorocyanide, Chlorocyanogen, Cyanogen chloride, inhibited

Physical Description:
Colorless gas or liquid (below 55ºF) with an irritating odor.

Notes 2:
[Note: Shipped as a liquefied gas. A solid below 20ºF. Forms cyanide in the body.]

Exposure Symptoms:
Irrit eyes, upper resp sys; cough, delayed pulm edema; weak, head, gidd, dizz, conf, nau, vomit; irreg heartbeat; irrit skin (liquid)


General Desc:
Tetranitromethane is a pale yellow liquid.  It is a skin and respiratory irritant.  It is very toxic by inhalation.  The material is somewhat difficult to ignite and once ignited it burns at a steady rate.  If contaminated with combustible material, tetranitromethane may decompose explosively.  Prolonged exposure of tetranitromethane and/or its containers to fire or heat may cause an explosion.  Toxic oxides of nitrogen are produced during combustion of this material. (¬ AAR, 1999)

Properties:
Flash Point:  >235¦ F (NTP, 1992)

Lower Exp Limit:  Non-combustible. (EPA, 1998)

Upper Exp Limit:  Non-combustible. (EPA, 1998)

Melting Point:  57.6¦ F (EPA, 1998)

Vapor Pressure:  13 mm at 77¦ F (EPA, 1998)

Vapor Density:  6.8 (EPA, 1998)

Specific Gravity:  1.6229 at 77¦ F (NTP, 1992)

Boiling Point:  259¦ F at 760 mm (EPA, 1998)

Molecular Weight:  196.04 (EPA, 1998)

IDLH:  4 ppm (NIOSH, 1997)

TLV TWA:  0.005 ppm, Suspected human carcinogen (¬ACGIH, 1999)

Water Solubility:  <1 mg/mL at 68¦ F (NTP, 1992)

First Aid:
Warning: Contact with eyes may result in severe damage to the cornea, conjunctiva, and blood vessels.  Caution is advised; Signs and Symptoms of Tetranitromethane Exposure: Acute exposure to tetranitromethane may result in irritation and burning of the skin, eye, and mucous membranes.  Headache, light-headedness, drowsiness, slurred speech, pupillary dilation, increased salivation, dysphagia (difficulty swallowing), abdominal pain, and spontaneous vomiting may occur.  Chest pain, stridor, (high-pitched, noisy respirations), dyspnea (shortness breath), and pulmonary edema are also common.  Apathy and mental confusion may develop, with progression to coma and death.  Emergency Life-Support Procedures: Acute exposure to tetranitromethane may require decontamination and life support for the victims.  Emergency personnel should wear protective clothing appropriate to the type and degree of contamination.  Air-purifying or supplied-air respiratory equipment should also be worn, as necessary.  Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.  Inhalation Exposure:  1.  Move victims to fresh air.  Emergency personnel should avoid self-exposure to tetranitromethane.  2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.   3.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures. 4.  Transport to a health care facility.   Dermal/Eye Exposure:  1.  Remove victims from exposure.  Emergency personnel should avoid self-exposure to tetranitromethane. 2.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.  3.  Remove contaminated clothing as soon as possible. 4.  If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 30 minutes.  5.  Wash exposed skin areas twice with soap and water.  6.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  7.  Transport to a health care facility.   Ingestion Exposure:  1.  Evaluate vital signs including pulse and respiratory rate, and note any trauma.  If no pulse is detected, provide CPR.  If not breathing, provide artificial respiration.  If breathing is labored, administer oxygen or other respiratory support.  2.  Obtain authorization and/or further instructions from the Localized hospital for administration of an antidote or performance of other invasive procedures.  3.  Vomiting may be induced with syrup of Ipecac.  If elapsed time since ingestion of tetranitromethane is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4.  Ipecac should not be administered to children under 6 months of age.  Warning: Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma.  If ANY uncertainty exists, proceed to Step 4.  The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz).  Ambulate (walk) the victims and give large quantities of water.  If vomiting has not occurred after 15 minutes, Ipecac may be readministered.  Continue to ambulate and give water to the victims.  If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal.  4.  Activated charcoal may be administered if victims are conscious and alert.  Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water.  5.  Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims.  Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults. 6.  Transport to a health care facility. (EPA, 1998)

Firefighting:
Do not move cargo or vehicle if cargo has been exposed to heat. Cool containers that are exposed to flames with water from the side until well after fire is out. For massive fire, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn.Extinguish small fires with water only, no dry chemicals or carbon dioxide. For large fires, flood the fire area with water. (EPA, 1998)

Reactivity:
CHEMICAL PROFILE:  Self-reactive. This material is a weak, but highly sensitive explosive (Van Dolah 1967). Propellant; ignites upon contact with alcohols, amines, ammonia, beryllium alkyls, boranes, dicyanogen, hydrazines, hydrocarbons, hydrogen, nitroalkanes, powdered metals, silanes, or thiols (Bretherick 1979 p.174). (REACTIVITY, 1999)

Symptoms:
eye, nose, throat irritation; dizziness; headaches; chest pain, dyspnea; methemoglobinuria; cyanosis; skin burns

Health Effects:
irritation-eye, nose, throat, skin---marked; acute central nervous system and lung effects; cumulative systemic damage; methemoglobinemia;

Physical Description:
Colorless to pale-yellow liquid or solid (below 57ºF) with a pungent odor.

Exposure Symptoms:
Irrit eyes, skin, nose, throat; dizz, head; chest pain, dysp; methemo, cyan; skin burns


General Desc:
Perchloryl fluoride is a colorless, non corrosive gas with a characteristic sweet odor.  Contact with the material may cause irritation to skin, eyes, and mucous membranes.  It is very toxic by inhalation and skin absorption.  Under prolonged exposure to fire or intense heat the containers may violently rupture and rocket. (¬ AAR, 1999)

Properties:
Melting Point:  -234¦ F (NIOSH, 1997)

Vapor Pressure:  10.5 atm (NIOSH, 1997)

Boiling Point:  -52¦F (NIOSH, 1997)

Molecular Weight:  102.5 (NIOSH, 1997)

IDLH:  100 ppm (NIOSH, 1997)

TLV TWA:  3 ppm (¬ACGIH, 1999)

TLV STEL:  6 ppm (¬ACGIH, 1999)

Water Solubility:  0.06% (NIOSH, 1997)

Reactivity:
CHEMICAL PROFILE:  Propellant; ignites upon contact with alcohols, amines, ammonia, beryllium alkyls, boranes, dicyanogen, hydrazines, hydrocarbons, hydrogen, nitroalkanes, powdered metals, silanes, or thiols (Bretherick 1979. p.174). (REACTIVITY, 1999)

Symptoms:
respiratory irritation; skin burns; in animals:  methemoglobinemia, anoxia, cyanosis; weakness, dizziness, headaches; pulmonary edema, pneumonitis

Health Effects:
methemoglobinemia; irritation-eyes, nose, throat, skin---moderate

Synonyms:
Chlorine fluoride oxide, Chlorine oxyfluoride, Trioxychlorofluoride

Physical Description:
Colorless gas with a characteristic, sweet odor.

Exposure Symptoms:
Irrit resp sys; liquid: frostbite; in animals: methemo; cyan; weak, dizz, head; pulm edema; pneuitis; anoxia


General Desc:
Sodium bisulfite is a white crystalline solid with a faint odor of burning sulfur.  It is soluble in water.  It is non-combustible when wet.  It is corrosive to aluminum.  It is used in the manufacture of other chemicals, in food processing, in photography, and for many other uses. (¬ AAR, 1999)

Properties:
Melting Point:  <32¦ F (USCG, 1999)

Specific Gravity:  1.48 (NIOSH, 1997)

Boiling Point:  >212¦ F at 760 mm (USCG, 1999)

Molecular Weight:  104.06 (USCG, 1999)

Water Solubility:  29% (NIOSH, 1997)

Nonfire Spill Response:
Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Cover solids with a plastic sheet to prevent dissolving in rain or fire fighting water.    Water spill:  Add dilute caustic soda (NaOH).  Add calcium hypochlorite (Ca(ClO)2).  Adjust pH to neutral (pH=7). ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  When heated to decomposition or on contact with mineral acids it emits highly toxic fumes of sulfur dioxide gas [ Sax, 9th ed., 1996, p. 2949]. (REACTIVITY, 1999)

Synonyms:
Monosodium salt of sulfurous acid, Sodium acid bisulfite, Sodium bisulphite, Sodium hydrogen sulfite

Physical Description:
White crystals or powder with a slight odor of sulfur dioxide.


General Desc:
PHYSICAL DESCRIPTION:  Pale yellowish-bronze, metallic, lustrous crystals; shiny gold-green (metallic) crystalline powder. (NTP, 1992)

Properties:
Melting Point:  1454¦ F (NTP, 1992)

Specific Gravity:  5.82 (NTP, 1992)

Molecular Weight:  240.25 (NTP, 1992)

Water Solubility:  <1 mg/mL at 70.7¦ F (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you spill this chemical, you should dampen the solid spill material with 5% acetic acid, then transfer the dampened material to a suitable container.  Use absorbent paper dampened with 5% acetic acid to pick up any remaining material.  Your contaminated clothing and the absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal.  Wash all contaminated surfaces with 5% acetic acid followed by washing with a soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should keep this material in a tightly closed container under an inert atmosphere, and store it at refrigerated temperatures. (NTP, 1992)

Reactivity:
STABILITY:  This chemical is sensitive to prolonged exposure to air.  Solutions of this chemical in water, DMSO, 95% ethanol or acetone should be stable for 24 hours under normal lab conditions. (NTP, 1992)

TLV NOTES:
Measured as inhalable fraction and vapor as Ni


General Desc:
Triethylamine is a clear colorless liquid with a strong ammonia to fish-like odor.  It has a flash point of 20 deg. F.  Its vapors are irritating to the eyes and mucous membranes.  It is lighter than water and soluble in water.  Its vapors are heavier than air.  Toxic oxides of nitrogen are produced during combustion of this material.  It weighs 6.1 lbs./gal. (¬ AAR, 1999)

Properties:
Flash Point:  20¦ F (NTP, 1992)

Lower Exp Limit:  1.2 % (USCG, 1999)

Upper Exp Limit:  8.0 % (USCG, 1999)

Auto Igtn Temp:  842¦ F (USCG, 1999)

Melting Point:  -174.5¦ F (NTP, 1992)

Vapor Pressure:  53.5 mm Hg (NTP, 1992)

Vapor Density:  3.48 (NTP, 1992)

Specific Gravity:  0.7275 at 68¦ F (NTP, 1992)

Boiling Point:  192.7¦ F (NTP, 1992)

Molecular Weight:  101.22 (NTP, 1992)

IDLH:  200 ppm (NIOSH, 1997)

TLV TWA:  1 ppm  Skin. (¬ACGIH, 1999)

TLV STEL:  5 ppm  Skin. (¬ACGIH, 1999)

Water Solubility:  Soluble (NTP, 1992)

Nonfire Spill Response:
Keep sparks, flames, and other sources of ignition away.  Keep material out of water sources and sewers.  Build dikes to contain flow as necessary.  Attempt to stop leak if without undue personnel hazard.  Use water spray to disperse vapors and dilute standing pools of liquid.    Apply water spray or mist to knock down vapors.  Vapor knockdown water is corrosive or toxic and should be diked for containment.    Land spill:  Dig a pit, pond, lagoon, holding area to contain liquid or solid material.  Dike surface flow using soil, sand bags, foamed polyurethane, or foamed concrete.  Absorb bulk liquid with fly ash, cement powder, or commercial sorbents.  Apply "universal" gelling agent to immobilize spill.  Neutralize with sodium bisulfate (NaHSO4).    Water spill:  Add sodium bisulfate (NaHSO4).  If dissolved, in region of 10 ppm or greater concentration, apply activated carbon at ten times the spilled amount.  Use mechanical dredges or lifts to remove immobilized masses of pollutants and precipitates. ( AAR, 1999)

Reactivity:
CHEMICAL PROFILE:  Reacts with Al and Zn; reacts violently with oxidants. see reaction hazard statement for amines (REACTIVITY, 1999)

Symptoms:
eye, respiratory system, skin irritation

Health Effects:
irritation-eye, nose, throat, skin---marked; lung edema; corneal damage

Target Organ:
eyes, skin, respiratory system, cardiovascular system, liver, kidneys

Physical Description:
Colorless liquid with a strong, ammonia-like odor.

Exposure Symptoms:
Irrit eyes, skin, resp sys; in animals: myocardial, kidney, liver damage


General Desc:
Trimethyl phosphite is a clear colorless liquid with a strong foul odor.  It has a flash point of 99 deg. F.  It is heavier than water and insoluble in water.  The vapors are heavier than air.  It is used to make other chemicals. (¬ AAR, 1999)

Properties:
Flash Point:  82¦ F (cc)
130¦ F (oc) (USCG, 1999)

Melting Point:  -108¦ F (USCG, 1999)

Vapor Pressure:  24 mm at 77¦F (NIOSH, 1997)

Specific Gravity:  1.05 (NIOSH, 1997)

Boiling Point:  232¦ F at 760 mm (USCG, 1999)

Molecular Weight:  124.08 (USCG, 1999)

TLV TWA:  2 ppm (¬ACGIH, 1999)

Water Solubility:  Reacts (NIOSH, 1997)

Reactivity:
AIR AND WATER REACTIONS:  Slowly reacts with water to form phosphoric acid and corresponding organic alcoholCHEMICAL PROFILE:  As soon as trimethyl phosphite contacted a small amount of magnesium perchlorate in a flask, there was a flash and an explosion that shattered the flask (Allison 1968). (REACTIVITY, 1999)

Symptoms:
irritation eyes, skin, upper respiratory system; dermatitis; in animals: teratogenic effects

Synonyms:
Methyl phosphite, Trimethoxyphosphine, Trimethyl ester of phosphorous acid

Physical Description:
Colorless liquid with a distinctive, pungent odor.

Exposure Symptoms:
Irrit eyes, skin, upper resp sys; derm; in animals: terato effects


General Desc:
Dipropylketone is a colorless liquid with a pleasant odor.  It is insoluble in water and lighter than water.  It has a flash point of 120 deg. F.  It is toxic by inhalation and a skin irritant.  It is used to make flavorings and as a solvent. (¬ AAR, 1999)

Properties:
Flash Point:  120¦ F (cc) (NIOSH, 1997)

Melting Point:  -27¦ F (NIOSH, 1997)

Vapor Pressure:  5 mm (NIOSH, 1997)

Specific Gravity:  0.82 (NIOSH, 1997)

Boiling Point:  291¦F (NIOSH, 1997)

Molecular Weight:  114.2 (NIOSH, 1997)

TLV TWA:  50 ppm (¬ACGIH, 1999)

Water Solubility:  Insoluble (NIOSH, 1997)

First Aid:
Eye: If this chemical contacts the eyes, immediately wash the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Contact lenses should not be worn when working with this chemical.  Skin: If this chemical contacts the skin, wash the contaminated skin with soap and water. Breathing: If a person breathes large amounts of this chemical, move the exposed  person to fresh air at once. If breathing has stopped, perform mouth-to-mouth  resuscitation. Keep the affected person warm and at rest. Get medical  attention as soon as possible.  Swallow: If this chemical has been swallowed, get medical attention immediately. (NIOSH, 1997)

Symptoms:
irritation eyes, skin; central nervous system depressant/depression, dizziness, somnolence (sleepiness, unnatural drowsiness), decreased breathing; in animals: liver injury; narcosis

Synonyms:
Butyrone, DPK, 4-Heptanone, Heptan-4-one, Propyl ketone

Exposure Symptoms:
Irrit eyes, skin; CNS depres, dizz, som, decr breath; in animals: liver inj; narco


General Desc:
Physical State Shipped: Liquid

Odor: Sweet, ether-like odor

Color: Colorless

Characteristics in Water: Sinks in water. (USCG, 1999)

Properties:
Auto Igtn Temp:  1256¦ F (NTP, 1992)

Melting Point:  -33.5¦ F (NTP, 1992)

Vapor Pressure:  284 mm Hg  at 77¦ F (NTP, 1992)

Specific Gravity:  1.5635 at 77¦ F (NTP, 1992)

Boiling Point:  117.9¦ F (NTP, 1992)

Molecular Weight:  187.38 (NTP, 1992)

IDLH:  2000 ppm (NIOSH, 1997)

Water Solubility:  Insoluble (NTP, 1992)

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE:  If you spill this chemical, use absorbent paper to pick up all liquid spill material.  Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal.  Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution.  Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS:  You should store this chemical under freezer conditions, and keep it away from all oxidizing materials. (NTP, 1992)

Firefighting:
Fire Extinguishing Agents: Extinguish fires with material appropriate to the surrounding materials. (USCG, 1999)

Reactivity:
REACTIVITY:  Violent reactions with Al, Ba, Li, Sm, NaK alloy and Ti. (NTP, 1992)

Symptoms:
throat irritation; drowsiness; dermatitis;  in animals:  cardiac arrhythmia

Target Organ:
skin, heart, central nervous system, cardiovascular system

Synonyms:
Chlorofluorocarbon-113, CFC-113, Freon®113, Genetron®113, Halocarbon 113, Refrigerant 113, TTE

Physical Description:
Colorless to water-white liquid with an odor like carbon tetrachloride at high concentrations.

Exposure Symptoms:
Irrit skin, throat, drow, derm; CNS depres; in animals: card arrhy, narco


